煤炭脱固硫技术现状及实验探讨

从当前环境状况入手,分析了目前脱固硫技术的现状、方法,并针对铜川高硫煤进行了物理洗选脱硫实验,提出了进一步固硫技术研究的设想。     

关于煤粉工业锅炉的技术分析与政策思考

在技术进步和政策的推动下,煤粉工业锅炉的应用正在形成高潮,但存在技术上的不实宣传和推广政策偏向问题。为使该技术能健康和可持续地发展,本文针对该锅炉的效率、污染物排放、制粉配送、风险和经济效益以及推广政策等方面,做了较深入的研究。研究认为该锅炉有高效节煤、SO2和NOx排放总量下降、集中配送煤粉和锅炉房干净等优点,值得推广;但因粉尘排放总量和浓度上升,综合环保效果处于劣势,同时存在电耗较大、煤源要求苛刻、煤粉储运和使用有风险,及经济效益不确定等问题,因此必须根据全面的技术、环境和经济评价,因地制宜地推广。建议政府采取具体措施,如资助布局优质煤粉供应点,以节能减排实效为资助的依据,鼓励专业锅炉制造厂参与研发和竞争,制定地方和国家有关煤粉工业锅炉的制造、用煤和污染物排放等标准,使该技术不断完善,可持续地发展。     

浅析同程化技术在含悬浮物矿井水净化处理中的应用

开发研究工艺简单、技术可靠、管理方便、经济合理的新工艺、新设备和新药剂,是矿井废水处理和利用的重要课题。文章阐述了同程化技术处理含悬浮物矿井水的工艺、技术、流程以及处理装置的运行管理,同程化技术在达到较好运行效果的同时,实现多级净化、高度集成,具有系统简单、工艺合理、运行维护方便的特点。     

Characteristics and anthropogenic sources of carbonyl sulfide in Beijing

Atmosphericmixing ratios of carbonyl sulfide (COS) in Beijingwere intensivelymeasured from March 2011 to June 2013. COS mixing ratios exhibited distinct seasonal variation, with a maximumaverage value of 849 ± 477 pptv in winter and a minimal value of 372 ± 115 pptv in summer. The seasonal variation of COS was mainly ascribed to the combined effects of vegetation uptake and anthropogenic emissions. Two types of significant linear correlations (R² > 0.66) were found between COS and CO during the periods from May to June and from October to March, with slopes (ΔCOS/ΔCO) of 0.72 and 0.14 pptv/ppbv, respectively. Based on the emission ratios of COS/CO from various sources, the dominant anthropogenic sources of COS in Beijing were found to be vehicle tire wear in summer and coal burning in winter. The total anthropogenic emission of COS in Beijing was roughly estimated as 0.53 ± 0.02 Gg/year based on the local CO emission inventory and the ΔCOS/ΔCO ratios.     

Numerical modelling of the effects of vessel length-to-diameter ratio (L/D) on pressure piling

Pressure piling presents a major explosion hazard in interconnected process vessels. Pressure enhancement in the secondary vessel due to the acceleration of the flame through the connecting pipe can generate a disproportionately more violent explosion than would have been expected based on the concentration of dust in the secondary vessel. Pressure piling is a very complex phenomenon that is difficult to investigate through experimentation. Advanced computational fluid dynamics (CFD) modelling is a promising route to accurately account for all the complexities associated with pressure piling.In this paper, the current state of knowledge concerning pressure piling is presented. Further, the effects of varying the length-to-diameter ratio (L/D) of the primary vessel (Vessel 1) on pressure piling was investigated using numerical modelling. The volumes and volume ratio of the interconnected vessels were kept constant while the L/D of Vessel 1 was varied from 0.5 to 15. The simulations of coal dust explosion were performed using the coalChemistryFoam solver from OpenFOAM version 5.0.1. It is hoped that the findings from this study provide insight into the effects of the geometrical design of interconnected vessels, particularly L/D, on pressure piling. Additionally, this work has implications for the optimal placement of explosion isolation devices intended to actuate before the flame front and pressure escape to downstream vessels.     

庞庄煤矿煤矸石淋溶液对周边水体影响分析

为研究庞庄煤矿张小楼煤矸石堆场淋溶液对其场地和周边地表水、地下水水质影响情况,围绕煤矸石堆场及周边采集13组水样做分析比对。结果表明,煤矸石堆场淋溶液对周边地表水体形成普遍污染,且污染物浓度随着污染距离增加逐步降低,一般化学污染指标主要包括溶解性总固体、硫酸盐、铁、锰、氨氮等,毒理学污染指标包括亚硝酸盐、氟化物、砷,超标倍率约为0.02~5.36。受距离及成井深度等因素影响,地下水体未遭受淋溶液明显的污染和影响。     

利用粉煤灰输送与贮存系统处置粘胶纤维污水场污泥的研究

通过对粘胶纤维污水场的中和脱锌污泥、二沉池剩余污泥和煤灰水混合体的沉降性能实验,证实其固液分离性能良好;吸附与渗透实验取得了粉煤灰、亚粘土对锌、汞的吸附等温线和地下水影响预测所需的参数;并分析了灰泥混合流体对电厂原输灰系统和环境的影响。研究结果表明：利用粉煤灰输送与贮存系统处置粘胶纤维污水场污泥的处理工艺在技术上可行,操作简单、运行可靠、投资少,每年可节省污泥处理费用40.5万元。外排污染物达到国家排放标准。     

采煤工作面瓦斯涌出量预测的神经网络模型

正确预测瓦斯涌出量,对于指导矿井设计和安全生产有重要意义。为此,应用神经网络理论,建立了采煤工作面瓦斯涌出量的预测模型,对其影响因素进行了权重排序,并确定了关键因素。实际应用表明,预测模型可信,精度能满足要求。     

山西煤炭基地矿井水的环境影响及利用研究

本文研究了山西矿井水水质特征及其环境影响.结果表明,矿井水中50％为高硬度、高矿化度水,42％为中性淡水,8％为酸性水,其污染特征为SS占第一位,依次为COD、硫化物、BOD_5、As等.文章还对山西矿井水的涌水量、利用现状与利用潜力进行了调查研究,指出山西矿井水应主要回用煤矿本身,实行清污分流和分质供水.     

改进高氯酸消化HG/AAS测定煤和环境及生物样品中砷和硒

由于硫酸往往含有微量硒杂质,本文改用硫酸钠作扶助剂提高高氯酸（硝酸）常压湿消化的允许消化温度,实现煤和环境及生物样品中有机砷和有机硒的全消化。建立了一个容易操作、重现性好的消化程序。用液氮低温捕集技术提高分析灵敏度。硝酸分解残留物对砷化氢和硒化氢生成过程的干扰,以及盐酸中微量氧化物对Ｓｅ（Ⅵ）还原处理的影响均用盐酸羟氨消除。ＥＤＴＡ可用于消除过渡金属离子对硒化氢生物过程的干扰。测定了多种标准参考物中微量砷和硒,得到与检定值相符合的结果。