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51.
胡敏酸对铜的鱼鳃生物有效性影响的计算机模拟 总被引:1,自引:1,他引:1
以彩虹方头鱼为模拟对象,用鱼鳃微环境测定装置和化学平衡计算方法(MINTEQA2),计算了含和不含胡敏酸的人工河水及暴露于其中的鱼鳃微环境中,不同pH条件下,铜的形态分布.研究了胡敏酸对鱼鳃内外的铜的形态分布及其生物有效性的影响,并讨论了pH对此的影响.计算结果表明,当胡敏酸存在时,胡敏酸络合态铜成为鱼鳃内外铜形态分布体系中的优势态,并引起铜生物有效性的降低.鱼鳃粘液和胡敏酸的共同作用使鱼鳃微环境中的生物有效铜含量低于外部水相.pH对铜形态分布及生物有效性的影响主要发生在碱性环境下. 相似文献
52.
Zhou Zai zhi 《环境科学学报(英文版)》1999,11(2):174-180
1IntroductionHighlyproductivelanduseresultsinacontinuouschangeoflandscapesinruralareas.Undertheimpactofcropproductmarkets,lan... 相似文献
53.
湖泊暴雨径流水质模拟研究 总被引:12,自引:1,他引:12
根据暴雨径流污染物浓度变化特点,采用最小二乘法对暴雨期间污染源各监测数据进行回归分析处理,对湖底糙率采用自动调整处理,建立了湖泊暴雨径流水质模型.对滇池湖泊某次暴雨过程的总磷和总氮进行了模拟研究,计算结果表明,该模型应用于滇池湖泊是成功的. 相似文献
54.
55.
Long‐Term Trends of Nutrients and Sediment from the Nontidal Chesapeake Watershed: An Assessment of Progress by River and Season 下载免费PDF全文
Qian Zhang Damian C. Brady Walter R. Boynton William P. Ball 《Journal of the American Water Resources Association》2015,51(6):1534-1555
To assess historical loads of nitrogen (N), phosphorus (P), and suspended sediment (SS) from the nontidal Chesapeake Bay watershed (NTCBW), we analyzed decadal seasonal trends of flow‐normalized loads at the fall‐line of nine major rivers that account for >90% of NTCBW flow. Evaluations of loads by season revealed N, P, and SS load magnitudes have been highest in January‐March and lowest in July‐September, but the temporal trends have followed similar decadal‐scale patterns in all seasons, with notable exceptions. Generally, total N (TN) load has dropped since the late 1980s, but particulate nutrients and SS have risen since the mid‐1990s. The majority of these rises were from Susquehanna River and relate to diminished net trapping at the Conowingo Reservoir. Substantial rises in SS were also observed, however, in other rivers. Moreover, the summed rise in particulate P load from other rivers is of similar magnitude as from Susquehanna. Dissolved nutrient loads have dropped in the upland (Piedmont and above) rivers, but risen in two small rivers in the Coastal Plain affected by lagged groundwater input. In addition, analysis of fractional contributions revealed consistent N trends across the upland watersheds. Finally, total N:total P ratios have declined in most rivers, suggesting the potential for changes in nutrient limitation. Overall, this integrated study of historical data highlights the value of maintaining long‐term monitoring at multiple watershed locations. 相似文献
56.
Development of the Spatial Rainfall Generator (SRGEN) for the Agricultural Policy/Environmental Extender Model 下载免费PDF全文
Jaehak Jeong Jimmy R. Williams Colleen G. Rossi Robin A. Taylor Xiuying Wang William E. Fox 《Journal of the American Water Resources Association》2015,51(1):154-167
Accurate spatial representation of climatic patterns is often a challenge in modeling biophysical processes at the watershed scale, especially where the representation of a spatial gradient in rainfall is not sufficiently captured by the number of weather stations. The spatial rainfall generator (SRGEN) is developed as an extension of the “weather generator” (WXGEN), a component of the Agricultural Policy/Environmental eXtender (APEX) model. SRGEN generates spatially distributed daily rainfall using monthly weather statistics available at multiple locations in a watershed. The spatial rainfall generator as incorporated in APEX is tested on the Cowhouse watershed (1,178 km2) in central Texas. The watershed presented a significant spatial rainfall gradient of 2.9 mm/km in the lateral (north‐south) directions based on four rainfall gages. A comparative analysis between SRGEN and WXGEN indicates that SRGEN performs well (PBIAS = 2.40%). Good results were obtained from APEX for streamflow (NSE = 0.99, PBIAS = 8.34%) and NO3‐N and soluble P loads (PBIAS ≈ 6.00% for each, respectively). However, APEX underpredicted sediment yield and organic N and P loads (PBIAS: 24.75‐27.90%) with SRGEN, although its uncertainty in output was lower than WXGEN results (PBIAS: ?13.02 to ?46.13%). The overall improvement achieved in rainfall generation by SRGEN is demonstrated to be effective in the improving model performance on flow and water quality output. 相似文献
57.
A Modeling System to Assess Land Cover Land Use Change Effects on SAV Habitat in the Mobile Bay Estuary 下载免费PDF全文
Maurice G. Estes Jr. Mohammad Z. Al‐Hamdan Jean T. Ellis Chaeli Judd Dana Woodruff Ronald M. Thom Dale Quattrochi Brian Watson Hugo Rodriguez Hoyt Johnson III Tom Herder 《Journal of the American Water Resources Association》2015,51(2):513-536
Estuarine ecosystems are largely influenced by watersheds directly connected to them. In the Mobile Bay, Alabama watersheds we examined the effect of land cover and land use (LCLU) changes on discharge rate, water properties, and submerged aquatic vegetation, including freshwater macrophytes and seagrasses, throughout the estuary. LCLU scenarios from 1948, 1992, 2001, and 2030 were used to influence watershed and hydrodynamic models and evaluate the impact of LCLU change on shallow aquatic ecosystems. Overall, our modeling results found that LCLU changes increased freshwater flows into Mobile Bay altering temperature, salinity, and total suspended sediments (TSS). Increased urban land uses coupled with decreased agricultural/pasture lands reduced TSS in the water column. However, increased urbanization or agricultural/pasture land coupled with decreased forest land resulted in higher TSS concentrations. Higher sediment loads were usually strongly correlated with higher TSS levels, except in areas where a large extent of wetlands retained sediment discharged during rainfall events. The modeling results indicated improved water clarity in the shallow aquatic regions of Mississippi Sound and degraded water clarity in the Wolf Bay estuary. This integrated modeling approach will provide new knowledge and tools for coastal resource managers to manage shallow aquatic habitats that provide critical ecosystem services. 相似文献
58.
David J. Rosa John C. Clausen Michael E. Dietz 《Journal of the American Water Resources Association》2015,51(3):746-757
The Storm Water Management Model was used to simulate runoff and nutrient export from a low impact development (LID) watershed and a watershed using traditional runoff controls. Predictions were compared to observed values. Uncalibrated simulations underpredicted weekly runoff volume and average peak flow rates from the multiple subcatchment LID watershed by over 80%; the single subcatchment traditional watershed had better predictions. Saturated hydraulic conductivity, Manning's n for swales, and initial soil moisture deficit were sensitive parameters. After calibration, prediction of total weekly runoff volume for the LID and traditional watersheds improved to within 12 and 5% of observed values, respectively. For the validation period, predicted total weekly runoff volumes for the LID and traditional watersheds were within 6 and 2% of observed values, respectively. Water quality simulation was less successful, Nash–Sutcliffe coefficients >0.5 for both calibration and validation periods were only achieved for prediction of total nitrogen export from the LID watershed. Simulation of a 100‐year, 24‐h storm resulted in a runoff coefficient of 0.46 for the LID watershed and 0.59 for the traditional watershed. Results suggest either calibration is needed to improve predictions for LID watersheds or expanded look‐up tables for Green–Ampt infiltration parameter values that account for compaction of urban soil and antecedent conditions are needed. 相似文献
59.
A Simulation of Temporal and Spatial Variations in Carbon at Landscape Level: A Case Study for Lake Abitibi Model Forest in Ontario,Canada 总被引:2,自引:0,他引:2
Xiaolu Zhou Changhui Peng Qing-Lai Dang Jiaxin Chen Sue Parton 《Mitigation and Adaptation Strategies for Global Change》2007,12(4):525-543
Using a case study of the Lake Abitibi Model Forest (LAMF), this study aims to assess the temporal and spatial variability
in carbon storage during 1990–2000, and to present a comprehensive estimation of the carbon budget for LAMF's ecosystems.
As well, it provided the information needed by local forest managers to develop ecological and carbon-based indicators and
monitor the sustainability of forest ecosystems. Temporal and spatial carbon dynamics were simulated at the landscape level
using ecosystem model TRIPLEX1.0 and Geographical Information System (GIS). The simulated net primary productivity (NPP) and
carbon storage in forest biomass and soil were compared with field data and results from other studies for Canada's boreal
forests. The results show that simulated NPP ranged from 3.26 to 3.34 tC ha−1 yr−1 in the 1990s and was consistent with the range measured during the Boreal Ecosystem-Atmosphere Studies (BOREAS) in central
Canada. Modeled NPP was also compared with the estimation from remote sensing data. The density of total above-and belowground
biomass was 125.3, 111.8, and 106.5 tC ha−1 for black spruce, trembling aspen, and jack pine in the LAMF ecosystem, respectively. The total carbon density of forested
land was estimated at 154.4 tC ha−1 with the proportion of 4:6 for total biomass and soil. The analysis of net carbon balance of ecosystem suggested that the
LAMF forest ecosystem was acting as a carbon sink with an allowable harvest in the 1990s. 相似文献
60.
Rodríguez-Maroto JM García-Delgado RA Gómez-Lahoz C Vereda-Alonso C García-Herruzo F Muñoz MP 《Environmental monitoring and assessment》2003,89(2):165-177
Lead and cadmium contamination of an agricultural soil has been studied using batch and column experiments. Thermodynamics of theretention phenomena may be represented by a Langmuir isotherm foran aqueous metal concentration up to 100 mg L-1. First order kinetics with respect to the solid phase yield good predictabilityfor both batch and column experiments. Kinetics and thermodynamics of lead retention predominate over those ofcadmium. As a consequence, lead is preferentially retainedand can even displace sorbed cadmium. In the event of anspill involving both metals, cadmium would move further inthe soil and its aqueous concentration downstream could beeven higher than that of the influent solution, increasingpotential risks. A two-region model has been used to fit all the experimental results. Satisfactory predictions for column experiments are obtained with parameters which are consistent with those obtained for the batch experiments, for which sorption is described by a Langmuir isotherm including competitive retention. 相似文献