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排序方式: 共有234条查询结果,搜索用时 46 毫秒
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水中阴离子表面活性剂的测定 总被引:13,自引:1,他引:12
偶氮红两相滴定法在pH=7.5的条件下,能测定水和废水中的各种阴离子表面活性剂的摩尔浓度。本文通过对硫酸盐、磺酸盐、苯磺酸盐、肥皂和磷酸盐等各类阴离子表面活性剂的测定,以及干扰试验和实际水样测定,表明此法优于亚甲基蓝分光光度法。方法的变异系数为1.0%(n=11),最小检出浓度0.052mg/L(n=21),加标回收率92.1%-110.2%,平均100.6%(n=14)。建议水中阴离子表面活性剂 相似文献
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Dissimilatory reduction of FeIII (EDTA) with microorganisms in the system of nitric oxide removal from the flue gas by metal chelate absorption 总被引:2,自引:0,他引:2
In the system of nitric oxide removal from the flue gas by metal chelate absorption, it is an obstacle that ferrous absorbents are easily oxidized by oxygen in the flue gas to ferric counterparts, which are not capable of binding NO. By adding iron metal or electrochemical method, Fe^Ⅲ (EDTA) can be reduced to Fe^Ⅱ(EDTA).However, there are various drawbacks associated with these techniques. The dissimilatory reduction of Fe^Ⅲ(EDTA) with microorganisms in the system of nitric oxide removal by metal chelate absorption was investigated. Ammonium salt instead of nitrate was used as the nitrogen source, as nitrates inhibited the reduction of Fe^Ⅲ due to the competition between the two electron acceptors. Supplemental glucose and lactate stimulated the formation of Fe^Ⅱ more than ethanol as the carbon sources. The microorganisms cultured at 50~C were not very sensitive to the other experimental temperature, the reduction percentage of Fe^Ⅲ varied little with the temperature range of 30-50℃.Concentrated Na2 CO3 solution was added to adjust the solution pH to an optimal pH range of 6-7. The overall results revealed that the dissimilatory ferric reducing microorganisms present in the mix-culture are probably neutrophilic, moderately thermophiUc Fe^Ⅲ reducers. 相似文献
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络合滴定法测定工业废水中的硫酸根离子 总被引:5,自引:0,他引:5
通过对乙二胺四乙酸(EDTA)滴定检测硫酸根离子法的改进,实现了可以同时消除钙、镁及其他重金属离子、碳酸根离子、磷酸根离子干扰的目的。该方法简单、快捷、准确度高,加标回收率为96.38%-99.69%,变异系数为1.2%-1.49%,尤其适用于污染较为严重水体的分析。 相似文献
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E. T. Romero-Guzmán L. R. Reyes-Gutiérrez M. J. Marín-Allende Z. I. González-Acevedo M. T. Olguín-Gutiérrez 《Chemistry and Ecology》2013,29(5):459-475
Eichhornia crassipes (Ec) and Lemna minor (Lm) are aquatic plants. They are considered as weeds of the water and approach being a scourge in many parts of the world, choking waterways and hindering transport upon them. At the same time they are known to readily remove heavy metal ions from water. This paper considers the use of non-living plants as novel and inexpensive biosorbent for the removal of As(V) from watersheds. In the first place they were conditioned and characterised to determine their physicochemical and surface properties and in the second place their adsorption properties for As(V) from aqueous solution were evaluated considering the toxicity of this metalloid in the environment. It describes the methodology to prepare the non-living biomasses; the physicochemical characterisation by SEM, XRD, FTIR, TGA analyses and surface characterisation of Ec and Lm by specific surface, hydration kinetic, point of zero charge determination by mass titration, active site density and XPS analysis are described. Both studied biomasses were found to be potential bio-sorbents for arsenic ions from aqueous solution. According to their efficiency to remove arsenic, they can be used in a very low cost metalloid ions removal system. 相似文献
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将EDTA转化成具有缓释性能的微胶囊EDTA(Cap-EDTA)作为螯合剂,采用大宝山矿区周边重金属复合污染农田土壤进行重金属连续批浸提及盆栽试验,比较研究Cap-EDTA和未微胶囊化EDTA(Ncap-EDTA)对土壤铅铜活化的动态变化及其对玉米吸收提取铅铜的影响。结果表明:Cap-EDTA处理土壤溶液中初始增溶的铅铜质量分数显著低于Ncap-EDTA处理,且使土壤溶液中的铅铜质量分数长时间持续保持在适度范围内。添加Cap-EDTA的处理显著提高玉米吸收提取铅铜的效率,如实施3 mmol·kg-1的Cap-EDTA使玉米地上部Pb的积累高达1.26 mg·pot-1,是对照处理的1.9倍,是等量Ncap-EDTA处理的1.4倍。因此,在进行污染土壤植物修复的EDTA调控时,采用微胶囊化EDTA,能降低因直接实施EDTA而带来的污染地下水风险,且显著提高玉米修复效率。 相似文献
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