试论火山-斑岩型锡矿床中的氟异常分布及其成因机理- -以岩背锡矿为例

本文以岩背锡矿为例，对火山—斑岩型锡矿床中的氟地球化学异常分布特征作了扼要总结；指出在锡矿床中Sn与F的地球化学异常有“形影关系”，并对其形成的地球化学原因作了分析，揭示了氟异常与锡矿化的内在联系。论证了氟的地球化学异常在火山—斑岩型锡矿床普查过程中具有良好的指示意义。     

The effect of oils on PAH, PCDD, PCDF, and PCB emissions from a spark engine fueled with leaded gasoline

The effect of synthetic and mineral oils on the formation of polyaromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and biphenyls (PCBs) in emissions from a spark ignition engine was studied on a Skoda Favorit engine fueled with leaded gasoline. The test cycle simulated urban traffic conditions on a chassis dynamometer, in accordance with the ECC 83.00 test. The data for selected PAHs as well as PCDDs, PCDFs, and PCBs congener profiles are presented. PCDD/Fs emissions for an unused oil and the oil after 10000-km operation varied from 300 to 2000 fmol/m3, PCBs emissions from 75 to 178 pmol/m3, and PAHs emissions from 150 to 420 microg/m3. The content of PCBs in oils varied from 2 to 920 mg/kg.     

Copper-catalyzed chlorination and condensation of acetylene and dichloroacetylene

The chlorination and condensation of acetylene at low temperatures is demonstrated using copper chlorides as chlorinated agents coated to model borosilicate surfaces. Experiments with and without both a chlorine source and borosilicate surfaces indicate the absence of gas-phase and gas-surface reactions. Chlorination and condensation occur only in the presence of the copper catalyst. C₂ through C₈ organic products were observed in the effluent; PCDD/F were only observed from extraction of the borosilicate surfaces. A global reaction model is proposed that is consistent with the observed product distributions. Similar experiments with dichloroacetylene indicate greater reactivity in the absence of the copper catalyst. Reaction is observed in the gas-phase and in the presence of borosilicate surfaces at low temperatures. The formation of hexachlorobenzene is only observed in the presence of a copper catalyst. PCDD/F were only observed from extraction of the borosilicate surfaces. A global reaction model is proposed for the formation of hexachlorobenzene from dichloroacetylene.     

Simple relationships between the ionization energies of one-, two- and three-electron ions of consecutive elements

The ionization energy of one-electron ions can be calculated from a well-known equation that is based on quantum mechanics and on the Bohr model, but no theoretically justified equation is available for the calculation of the ionization energies of multi-electron ions. I report here simple empirical relationships between the ionization energies of one-, two- and three-electron ions of elements whose atomic numbers are Z, Z + 1 and Z + 2. On the basis of these relationships, an equation was constructed for the calculation of the ionization energies of two- and three-electron ions (IE(2el)(Z) and IE(3el)(Z), respectively) as a function of Z only: [equation: see text] where N = the number of electrons, i.e. 2 or 3. For N = 3, this equation is only valid when Z > N, being inaccurate for the neutral Li atom. Graphs of the difference between calculated and experimental values of the ionization energies as a function of Z reveal inaccurate experimental results that are impossible to detect by inspection of the ionization energy itself. On the basis of the present results, more accurate values can be predicted for these ionization energies. A striking example is the inaccuracy of the traditional handbook value of IE(3el)(Fe).     

颜料红23对锦鲤的毒性及对部分组织中磷酸酶活性的影响

为了研究偶氮染料颜料红23对水生生物的毒性作用,将锦鲤(Cyprinus carpio)分别暴露于5个质量浓度的颜料红23溶液中,设1个对照组,进行96 h-LC_(50)急性毒性试验,测得其半致死质量浓度(96h-LC_(50))为255.38 mg/L。测定了颜料红23对锦鲤鳃、肝脏及肌肉组织中碱性磷酸酶(AKP)和酸性磷酸酶(ACP)活性的影响。结果表明:颜料红23对锦鲤鳃中AKP和ACP活性的影响趋势相反,AKP活性表现为诱导—抑制—诱导效应,ACP则表现为抑制—诱导—抑制效应;颜料红23对锦鲤肝脏组织中AKP、ACP活性的影响趋势相同,均表现为抑制效应;在锦鲤肌肉组织中,AKP活性表现为诱导—抑制效应,ACP表现为抑制—诱导—抑制效应。AKP和ACP在鱼体抵御偶氮染料毒性方面有着重要作用。     

Managing Birds and Controlling Aircraft in the Kennedy Airport–Jamaica Bay Wildlife Refuge Complex: The Need for Hard Data and Soft Opinions

During the 1980s, the exponential growth of laughing gull (Larus atricilla) colonies, from 15 to about 7600 nests in 1990, in the Jamaica Bay Wildlife Refuge and a correlated increase in the bird-strike rate at nearby John F. Kennedy International Airport (New York City) led to a controversy between wildlife and airport managers over the elimination of the colonies. In this paper, we review data to evaluate if: (1) the colonies have increased the level of risk to the flying public; (2) on-colony population control would reduce the presence of gulls, and subsequently bird strikes, at the airport; and (3) all on-airport management alternatives have been adequately implemented. Since 1979, most (2987, 87%) of the 3444 bird strikes (number of aircraft struck) were actually bird carcasses found near runways (cause of death unknown but assumed to be bird strikes by definition). Of the 457 pilot-reported strikes (mean = 23 ± 6 aircraft/yr, N= 20 years), 78 (17%) involved laughing gulls. Since a gull-shooting program was initiated on airport property in 1991, over 50,000 adult laughing gulls have been killed and the number of reported bird strikes involving laughing gulls has declined from 6.9 ± 2.9 (1983–1990) to 2.6 ± 1.3 (1991–1998) aircraft/yr; nongull reported bird strikes, however, have more than doubled (6.4 ± 2.6, 1983–1990; 14.9 ± 5.1, 1991–1998). We found no evidence to indicate that on-colony management would yield a reduction of bird strikes at Kennedy Airport. Dietary and mark–recapture studies suggest that 60%–90% of the laughing gulls collected on-airport were either failed breeders and/or nonbreeding birds. We argue that the Jamaica Bay laughing gull colonies, the only ones in New York State, should not be managed at least until all on-airport management alternatives have been properly implemented and demonstrated to be ineffective at reducing bird strikes, including habitat alterations and increasing the capability of the bird control unit to eliminate bird flocks on-airport using nonlethal bird dispersal techniques. Because the gull-shooting program may be resulting in a nonsustainable regional population of laughing gulls (>30% decline), we also recommend that attempts be made to initiate an experimental colony elsewhere on Long Island to determine if colony relocation is a feasible management option.     

Determinants of foreign direct investment in the mining sector in Asia: A comparison between China and India

The aim of this paper is to assess the conditions that influence foreign direct investment in the mineral industries of China and India. The paper first surveys literature on the determinants of foreign direct investment to identify key conditions, under which host countries attract mining FDI. It then builds an evaluative framework which allows for comparative analysis. The paper then comparatively evaluates the performance of foreign investment regimes that govern mineral industries in China and India. Its findings show that the overall conditions for foreign mining investment in China and India are not favourable and that substantial policy, regulatory and other changes in both countries need to be made if more investment is to flow.     

造纸法再造烟叶废水COD的快速预测

针对造纸法再造烟叶生产废水COD波动大、废水处理系统运行不稳定等问题,对造纸法再造烟叶的生产废水排放及不同种类废水的水质特点进行了分析。在废水处理系统运行检测数据的基础上,采用数理统计方法研究了废水COD与pH的关系。结果表明:COD与pH呈高度显著的线性关系;用得到的回归方程COD=-2 913pH+22 059对废水COD进行验证和预测,相对偏差在15%以内。本研究为造纸法再造烟叶废水处理系统的运行提供了一种快捷的COD预测方法,有助于提高废水处理系统的处理效率和运行稳定性。     

添加剂F127对CPVC超滤膜性能的影响研究

文章探讨了添加剂F127的质量百分含量(5%、7%、10%和13%)对CPVC超滤膜微观结构及其性能(包括水通量、截留率、机械性能、亲水性和耐污染性能)的影响.结果表明:随着F127含量的增加,铸膜液剪切粘度增加,截留率上升,亲水性和耐污染性能大幅度提高,纯水通量和机械性能有所下降.综合比较添加剂F127含量为10%时,CPVC超滤膜性能较好.     

Neighborhood effects in the Brazilian Amazônia: Protected areas and deforestation

This article investigates whether protected areas are efficient instruments against deforestation in the Brazilian Amazônia. A Dynamic Spatial Durbin Model taking into account both the location bias and the spatial spillover effects between municipalities allows to assess the impact of the different types of protected areas (integral protected areas, sustainable protected areas and indigenous lands) on deforestation. We show that deforestation decisions are strategic complements. The econometric results differ according to the type of protected area. It is shown that: i) integral protected areas and indigenous lands allow for reducing deforestation; ii) sustainable use areas do not help to reduce deforestation; and iii) the spillover effects generated by integral protected areas and indigenous lands lead a reduction in deforestation in their vicinity. A 10% increase in the surface area of integral protected areas (indigenous lands) allows an estimated 9.32 sq. km (10.08 sq. km) of avoided deforestation.