中空柱状生物膜载体在处理工业废水工程中的应用

本文介绍新开发的一种在污水处理中的高科技产品一高效生物膜载体,通过对其在与其他处理方式各方面择比研究过程中的高找到其特点,推广新科技。     

水膜预湿行为对典型保温材料燃烧抑制实验研究

为探索喷淋形成水膜的预湿行为对外立面典型保温材料燃烧抑制机理,采用自建水膜预湿抑制保温材料燃烧实验装置,研究外加辐射作用下,水膜流率对聚苯乙烯(PS)保温材料表面出现干斑、变形和熔融的影响规律.结果表明:实验结束时PS材料表面水膜出现干斑、材料发生变形和熔融面积占比均与无量纲辐射强度呈正相关;PS材料表面水膜出现干斑、...     

玻璃纤维-砂浆管试件动态拉伸破坏特性试验研究

为了探究动载作用下GFRP（玻璃纤维）-砂浆管的动态拉伸破坏特性,采用分离式SHPB试验装置对2种空心率的水泥砂浆管和GFRP-砂浆管进行动态拉伸试验。结果表明:空心率越小、冲击气压和壁厚越大,试件峰值抗拉强度越大;GFRP-砂浆管的峰值抗拉强度随GFRP管壁厚的增大而不断增大,在空心率为0.292时,峰值抗拉强度随GFRP管壁厚增大呈对数函数递增,而在空心率0.187时,峰值抗拉强度随GFRP管壁厚增大呈指数函数递增;无GFRP管时水泥砂浆管呈对称四块破碎,GFRP-砂浆管在0.5~0.7 MPa冲击气压下仅有细小裂纹产生,在0.8 MPa冲击气压下,与入射杆接触部分产生“楔形”破坏,但总体保持为管状、破坏程度仍低于水泥砂浆管,表明GFRP管对水泥砂浆管具有较好的保护作用,可有效提高其动态抗拉强度。     

Quantification of pesticide residues on plastic mulching films in typical farmlands of the North China

• Pesticide residuals on mulching film of Shandong, Tianjin and Hebei. • Detected 29 pesticides in soil and 30 in mulching film. • Pesticides on plastic films: 86.4‒22213.2 ng/g and in soil: 9.3‒535.3 ng/g. • Pesticides on plastic films 20 times higher than in soil. Plastic debris as new pollutants attracts much attention in the recent years. The plastic mulching films is one of the most important plastic debirs source in the environment. The aim of this work was to investigate the current status of pesticide residues on the plastic mulching films. Based on the QuEChERS method, multi-residue methods for detection of pesticide residues with gas chromatography tandem mass spectrum (GC-MS) and high performance liquid chromatography tandem mass spectrum (HPLC-MS) were developed for the analysis of the pesticides residues in plastic film and soil samples from Tianjin, Hebei and Shandong. The total concentrations of pesticide residues were in the range of 86.4‒22213.2 ng/g in plastic film debris, which was about 20 times higher than that in soil (9.3‒535.3 ng/g). Residual level of pesticides varied greatly in different samples. The historical usage and recent application of pesticides were the main sources for pesticide residues on plastic films and soil. In short, plastic mulching films could act as a sink for pesticides in farmland and the ubiquitous pesticide residues on plastic films should draw more attention.     

“限塑令”政策实施效应与对策研究

分析了"限塑令"的政策安排、实施效果,以及"限塑令"的实行对塑料袋生产、销售、使用相关各方的影响,讨论了政策执行中存在的政策实施目的偏差、缺乏配套政策、回收利用产业发展缓慢、垃圾袋和替代品不环保等问题,提出了保证"限塑令"政策有效实施的对策建议,即应依照少用、回收、替代、降解的原则对待塑料袋的使用。     

Comparison of surface emissions and subsurface distribution of cis- and trans-1,3-dichloropropne and chloropicrin in sandy field beds covered with four different plastic films

The purpose of this study was to conduct a field study at a Florida field site on surface emissions and subsurface distribution of cis-and trans-1,3-dichloropropene (1,3-D) and chloropicrin (CP) in raised beds injected with Telone C35 with four replications. A total of 16 beds were applied with Telone C35 by chisel injection and covered with four different plastic films, 4 beds for each film. Each bed was installed with five 20-cm long soil pore air probes and a surface air collection pan at arbitrarily locations along the length of each bed for sampling soil pore air and surface air, respectively, for analysis of the three biologically active compounds, cis- and trans-1,3-D and CP. We found that average concentrations of the three compounds at 20-cm depth among the beds covered with four different plastic films generally were not statistically different. Among the four beds covered with the same plastic film, average concentrations of the three compounds were statistically different only in the four metallic PE covered beds at 5 and 24 hours after injection. Volatilization rates of the three compounds among the beds covered with four different plastic films, with the exception of CP at 48 hours after injection, were not statistically different. It appeared that initial upward diffusion and volatilization flux were influenced by solar radiation. Initial subsurface concentrations of the three compounds and volatilization flux, especially cis-1,3-D, were greater in the beds on the east side of the field than that in the beds on the west side of the field. Whether or not difference in initial subsurface concentrations of the compounds between east side beds and west side beds may influence fumigant efficacy remains to be determined.     

转盘液膜光电催化法处理罗丹明B的反应动力学

采用幂指数方程法建立了转盘液膜光电催化法降解罗丹明B(RhB)废水的动力学方程.结果表明,该反应动力学符合表观一级动力学.在考察的影响因素中,外加偏压对反应速率的影响最大,催化剂用量次之,其次是RhB初始浓度,转盘转速和光强度的影响相对较小.     

Contamination Characteristics and Degradation Behavior of Low-Density Polyethylene Film Residues in Typical Farmland Soils of China

Low-density polyethylene (LDPE) film residues left in farmlands due to agricultural activities were extensively investigated to evaluate the present pollution situation by selecting the typical areas with LDPE film application, including Harbin, Baoding, and Handan of China. The survey results demonstrated that the film residues were ubiquitous within the investigaed areas and the amount reached 2400–8200 g ha^?1. Breakage rates of the film residues were almost at the same level in the studied fields. There were relatively small amounts of film residues remaining in neighboring farmland fields without application of LDPE film. The studies showed that the sheets of LDPE residues had the same oxidative deterioration, which was probably due to photodegradation instead of biodegradation. The higher molecular weight components of the LDPE film gradually decreased, which were reflected by the appearance of some small flakes detached from the film bodies. LDPE films in the investigated fields gradually deteriorated and the decomposing levels developed with their left time increasing. The degradation behaviors of LDPE films were confirmed by using Fourier transform infrared (FTIR), scanning electron microscopic (SEM), and gel permeation chromatography analyses.     

南通平原河网地区典型农田系统地下水硝态氮污染调查

针对平原河网地区典型农田系统灌溉施肥带来的地下水环境污染问题,采集南通地区蔬菜地、水稻-小麦轮作地、水稻-油菜轮作地和桑地地下水样品,分析了不同农田种植体系下的地下水污染程度。结果表明,蔬菜、桑地、水稻-油菜轮作、水稻-小麦轮作地地下水的硝态氮(N)平均值分别为12.2,9.53,7.95和6.12 mg/L,与氮肥用量呈显著的正相关关系;研究区域地下水硝态氮超Ⅲ类标准率(20 mg/L)的为4.8%,表明地下水已部分受到硝态氮污染。     

基于重金属有效态的农田土壤重金属污染评价研究

目前农田土壤重金属污染评价以重金属全量为依据,而评价农田土壤重金属污染影响时主要考虑农产品安全从而保障人体健康,农作物对重金属的吸收积累量则取决于土壤中有效态重金属含量。在阐述土壤重金属有效态定义的基础上,综合分析了土壤重金属有效态的影响因素及其与土壤中重金属全量和农作物中重金属含量的相关性,概括了土壤重金属有效态在土壤重金属污染评价中的应用,以期提出建立以土壤重金属有效态含量为基础、结合土壤重金属全量及作物中吸收的重金属含量的土壤重金属污染评价体系。