利用胱氨酸生产废水开发氨基酸复合（混）固体肥料的研究

针对目前胱氨酸生产的处理和资源化所存有的问题，通过现场调查，室内模拟，生物试验，车间试生产等手段，探讨了利用胱氨酸生产废水开发氨基酸复合（混）固体肥料的原理和技术及其肥效和效益特点。     

多元生物有机复合肥的推广应用

介绍了多元生物有机复合肥的主要功能、特点、推广应用状况、应用效果、社会经济效益．     

Response of antioxidant enzymes in Nicotiana tabacum clones during phytoextraction of heavy metals

Background, aim, and scope  Tobacco, Nicotiana tabacum, is a widely used model plant for growth on heavy-metal-contaminated sites. Its high biomass and deep rooting system make it interesting for phytoextraction. In the present study, we investigated the antioxidative activities and glutathione-dependent enzymes of different tobacco clones optimized for better Cd and Zn accumulation in order to characterize their performance in the field. Main features  The improved heavy metal resistance also makes the investigated tobacco clones interesting for understanding the plant defense enzyme system in general. Freshly harvested plant material (N. tabacum leaves) was used to investigate the antioxidative cascade in plants grown on heavy metal contaminated sites with and without amendments of different ammonium nitrate and ammonium sulfate fertilizers. Materials and methods  Plants were grown on heavily polluted soils in north-east Switzerland. Leaves were harvested at the field site and directly deep frozen in liquid N₂. Studies were concentrated on the antioxidative enzymes of the Halliwell–Asada cycle, and spectrophotometric measurements of catalase (CAT, EC 1.11.1.6), ascorbate peroxidase (APX, EC 1.11.1.11), superoxide dismutase (SOD, EC 1.15.1.1), glutathione peroxidase (GPX, EC 1.11.1.9), glutathione reductase (GR, EC 1.6.4.2), glutathione S-transferase (GST, EC 2.5.1.18) were performed. Results and discussion  We tried to explain the relationship between fertilizer amendments and the activity of the enzymatic defense systems. When tobacco (N. tabacum) plants originating from different mutants were grown under field conditions with varying fertilizer application, the uptake of cadmium and zinc from soil increased with increasing biomass. Depending on Cd and Zn uptake, several antioxidant enzymes showed significantly different activities. Whereas SOD and CAT were usually elevated, several other enzymes, and isoforms of GST were strongly inhibited. Conclusions  Heavy metal uptake represents severe stress to plants, and specific antioxidative enzymes are induced at the cost of more general reactions of the Halliwell–Asada cycle. In well-supplied plants, the glutathione level remains more or less unchanged. The lack of certain glutathione S-transferases upon exposure to heavy metals might be problematic in cases when organic pollutants coincide with heavy metal pollution. When planning phytoremediation of sites, mixed pollution scenarios have to be foreseen and plants should be selected according to both, their stress resistance and hyperaccumulative capacity.     

Practices,perceptions, and implications of fertilizer use in East-Central China

Face-to-face interviews (n = 553) were conducted in five counties in East-Central China to study farmers’ fertilizer application behaviors, decision-making processes, attitudes towards adopting better fertilizer application technologies, and environmental consciousness. The survey results revealed widespread fertilizer misapplication and highly variable application behaviors in the study regions. The lack of scientific knowledge on fertilizers and the absence of guidance from agricultural extension services have forced the farmers to rely on personal judgment and advice from fertilizer dealers and friends to make decisions in fertilizer application. Overall, farmers have been idiosyncratic in fertilizer application with limited adoption of better fertilizer application technologies. There are great potentials for reducing pollutant load from agricultural runoff through promoting scientific fertilizer application in the regions. However, farmers’ diverse preferences over agricultural extension programs necessitate an integrated approach emphasizing farmer involvement throughout the development of such programs for promoting better fertilizer application practices.     

Concentrations of heavy metals in fly ash from a coal-fired power plant with respect to the new Finnish limit values

In Finland, the new limit values for heavy metals in fertilizers used in agriculture and in forestry came into force in March 2007, and for materials used as earth construction agents, in June 2006. From the utilization point of view, it was notable that the total heavy metal concentrations (Cd, Cu, Pb, Cr, Mo, Zn, As, Ni, Ba, and Hg) in fly ash from a coal-fired power plant were lower than those limit values. The concentrations of the easily soluble elements Ca, Mg, Na, P, and Zn in the fly ash were between 3.5 and 35 times higher than those found in the coarse mineral soils of Finland. Fly ash is a potential agent for soil remediation and for improving soil fertility. If inorganic materials and by-products are utilized in earthworks, the content of harmful compounds must be low and the harmful components must be tightly bound to the matrix. Therefore, a five-stage sequential extraction procedure was used to evaluate the extractability of different elements in fly ash into the following fractions: (1) the water-soluble fraction, (2) the exchangeable fraction (CH₃COOH), (3) the easily reduced fraction (NH₂OH-HCl), (4) the oxidizable fraction (H₂O₂ + CH₃COONH₄), and (5) the residual fraction (HF + HNO₃ + HCl).     

淮北市叶菜类蔬菜中硝酸盐含量的调查

通过对淮北市近郊几个大的蔬菜生产基地叶菜类蔬菜中硝酸盐含量的分析,发现淮北市叶菜类蔬菜中硝酸盐含量普遍很高,且有超标状况存在。究其因,主要是化肥的过量使用,使蔬菜中的硝态氮不能及时还原,累积于体内。     

化肥废水零排放工程实践

采用吹脱-A/O一体生化工艺对化肥废水进行处理,设计水量1800m3／d。进水NH3-N质量浓度为762mg／L,处理后的出水水质达到GB13458—2001《合成氨工业水污染排放标准》（中型一级）,全部回用车间作为循环冷却水,污水零排放。     

Human urine as a source of alternative natural fertilizer in agriculture: A flight of fancy or an achievable reality

Organically agricultural products are gaining popularities through out the world as it gives the consumer satisfaction with a basket of safer and better trusted foods. It is also well established that intensive conventional agricultural practices can introduce contaminants into the food chain with adverse affect on environment. However, organic agricultural practices give an alternative environmental friendly sustainable agriculture among the farmers. Beside this fact, organic crops contain fewer nitrates, nitrites, pesticide residues and trace elements than conventional crops. Even though, in organic systems generally have 20% lower yields than conventionally produced crops. One of the major constrains of organic farming is decrease of raw organic matters to prepare compost. Therefore, scientists are looking forward for different organic sources which are plenty in nature and available at little-to-no cost. Human urine is one of them, and has been gaining popularities as a raw material for organic cultivation. However, several important merits and demerits of application of human urine are needed to be addressed in agriculture.     

Effects of field-applied composted cattle manure and chemical fertilizer on ammonia and particulate ammonium exchanges at an upland field

The present study aimed to investigate the NH₃ volatilization loss from field-applied compost and chemical fertilizer and evaluate the atmosphere–land exchange of NH₃ and particulate NH₄⁺ (pNH₄) at an upland field with volcanic ash soil (Andosol) in Hokkaido, northern Japan. Two-step basal fertilization was conducted on the bare soil surface. First, a moderately fermented compost of cattle manure was applied by surface incorporation (mixing depth, 0–15 cm) at a rate of 117 kg N ha⁻¹ as total nitrogen (T-N) corresponding to 9.9 kg N ha⁻¹ as ammoniacal nitrogen (NH₄–N). Twelve days later, a chemical fertilizer containing 10% (w/w) of NH₄–N as a mixture of ammonium sulfate and ammonium phosphates was applied by row placement (cover depth, 3 cm) at a rate of 100 kg N ha⁻¹ as NH₄–N. The study period was divided into the first-half, beginning after the compost application (CCM period), and the second-half, beginning after the chemical fertilizer application (CF period). The mean air concentrations of NH₃ and pNH₄ (1.5 m height) were 7.6 and 3.0 μg N m⁻³, respectively, in the CCM period; the values were 3.7 and 3.9 μg N m⁻³, respectively, in the CF period. The composition ratios of NH₃ to the sum of NH₃ and pNH₄ (1.5 m height) were 72% and 49% in the CCM and CF periods, respectively. The NH₃ volatilization loss from the compost was 0.8% of the applied T-N (or 9.3% of the applied NH₄–N) and that from the chemical fertilizer was near zero. Excluding the period immediately after the compost application, the upland field acted as a net sink for NH₃ and pNH₄.     

实现秸秆资源化利用的主要途径

随着我国农村经济的发展和能源供应的改善，部分经济较发达地区出现了秸秆过剩的现象，田间直接燃烧秸秆造成了严重的环境问题。文章认为秸秆作为农业的副产品，是一种有用的资源。介绍了4种秸秆资源化利用的途径，包括能源利用技术、肥料利用技术、饲料利用技术以及用于工业原料的技术。