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391.
392.
合成并表征了石墨烯,然后通过溶剂法制备石墨烯/环氧树脂复合材料,研究了石墨烯对环氧树脂复合材料的热稳定性和燃烧性能的影响。热重分析数据显示,石墨烯可以显著提高环氧树脂的热稳定性。锥形量热仪测试结果表明,石墨烯降低了环氧复合材料热和烟气的释放。炭渣的扫描电镜(SEM)图揭示了石墨烯减少了环氧树脂炭层孔洞的生成,提高了炭层的致密度,从而增强了炭层的阻隔作用。 相似文献
393.
利用混合菌群活性污泥法实现生物可降解塑料PHA的合成 总被引:4,自引:0,他引:4
PHA是一种生物可降解塑料,可从污水有机物中合成。文章在简要说明现阶段工业生产PHA情况的基础上,总结了利用混合菌种活性污泥法从污水有机物中合成PHA的优点。重点对两种从污水中生产PHA工艺——厌氧-好氧活性污泥工艺和好氧瞬时供料工艺进行了介绍,并给出了相应工艺流程。通过使用廉价的有机底物可以使PHA的生产价格降低到原来的一半,大约为每公斤4欧元左右。文章还讨论了控制工艺运行条件对PHA合成的重要性,并说明了不同底物组成对合成PHA性质的影响。 相似文献
394.
The floatability of seven plastics (POM, PVC, PET, PMMA, PC, PS and ABS) in the presence of methyl cellulose (MC) and separation of plastics mixtures were investigated in this paper. It was found that the seven plastics can be separated into three groups by using the wetting agent MC. Group one includes POM and PVC. They are depressed at very low MC concentrations. Group two, including PET, PMMA and PC, has an intermediate floatability. Group three (ABS and PS) has a high floatability. They are almost not depressed within the given MC concentration range. In order to understand the mechanism of selective flotation of plastics and the chemical conditioning process, surface chemical factors, such as wettability of plastics and surface tension of flotation medium, and gravity factors, such as particle density and shape, were studied. It was found that the depressing effect of MC on plastics is ascribed mainly to its adsorption on the plastics surfaces. The MC molecules absorbed on plastics expose some of their polar groups oriented towards the aqueous phase, hence making the plastics surfaces hydrophilic. In addition, flotation selectivity for the plastics is dominated not only by wettability of plastics, but also by particle size, density and shape. 相似文献
395.
396.
Akio Kamimura Eisuke Konno Shigehiro Yamamoto Takeru Watanabe Kazuo Yamada Fumiaki Tomonaga 《Journal of Material Cycles and Waste Management》2009,11(1):38-41
To develop a new method for the chemical recycling of plastics, we examined the formation of recycled polymers from the recovered
monomeric materials of solubilized waste fiber-reinforced plastics (FRP) under supercritical alcoholic conditions. Treatment
of waste FRP with supercritical MeOH resulted in the formation of monomeric organic compounds that mainly contained dimethyl
phthalate (DMP) and propylene glycol. The presence of these materials was confirmed by gas chromatography and nuclear magnetic
resonance analyses and they were mixed with new DMP and glycols in various ratios to form unsaturated polyesters. The polymerization
progressed successfully for all mixing ratios of the recovered and new DMP. Hardness tests on these recycled polymers indicated
that the polymer made from a 1:1 mixture of recovered and new dimethyl phthalate had almost the same level of hardness as
the polymers made from new materials. We also examined the formation of recycled FRP by using glass fibers and monomeric materials
recovered through the present depolymerization method.
Chemical Feedstock Recycling & Other Innovative Recycling Techniques 6 相似文献
397.
Todd A. Anderson Devin M. Scherubel Rong Tsao Alan W. Schwabacher Joel R. Coats 《Journal of Polymers and the Environment》1997,5(2):119-124
Determining the fate of xenobiotic materials in the environment can be aided by the use of radioactive isotope technology.
Previous research on the degradation of polymers such as polyethylene (PE) was aided by the utilization of radiotracers. In
order to study the environmental fate of degradable (PE/starch) plastics, we synthesized3H-labeled PE. Results of soil incubation studies indicate that only minimal degradation of the PE component, as indicated
by the production of water-soluble metabolites, occurred during 2 years of incubation in soil. Despite the minimal degradation,
the3H label did not allow for detection of the degradation products. In addition, the3H-PE was particularly useful for tracing the fate of degradable plastics after consumption by terrestrial isopods. The detection
of aqueous-soluble radioactivity in isopod frass was used to indicate degradation of the plastic film. 相似文献
398.
沉淀法回收聚苯乙烯泡沫塑料的工艺研究 总被引:7,自引:0,他引:7
研究沉淀法回收聚苯乙烯泡沫塑料(EPS)的工艺,利用石油裂解副产物为溶剂回收废旧聚苯乙烯泡沫塑料,以废治废,回收利用。溶剂低毒,对聚苯乙烯泡沫塑料溶解速度快,溶解量大,价廉易得。采用转式间歇投料并附加溶剂挥发分z收装置的工艺,溶剂回收率高,无二次污染,可循环使用。聚苯乙烯塑料(PS)回收率可达99%。 相似文献
399.
400.