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81.
试验了用非全量消解—悬浮液直接进样火焰原子吸收光谱法测定煤灰中的铜和铅,结果表明:铜和铅的方法检出限(3σ)分别为0.038mg/L和0.23mg/L,测定吸光度与其浓度的线性范围均为0.5mg/L—5.0mg/L,样品加标回收率在87%—97%之间,相对标准差(n=4)小于7%。 相似文献
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83.
To investigate the effect of Al2O3 particle size on an aluminum explosion, the overpressure and flame velocity in a vertical duct were evaluated. The results show that the inhibitory effect of submicron Al2O3 is best, while the inhibitory effect increases with increasing inerting ratio. However, the inhibitory effect of micron Al2O3 does not increase significantly after the inerting ratio exceeds 40%. For high-concentration aluminum powder, 0.8 μm Al2O3 with an inerting ratio less than 20% promotes aluminum explosion. As the inerting ratio increases beyond 20%, however, the overpressure decreases. Furthermore, Al2O3 inhibits the formation of the intermediate product AlO and decreases the flame brightness. As the inerting ratio of 0.8 μm Al2O3 reaches 50%, the white patches in the flame image disappear. The results of scanning electron microscopy showed that the explosion products agglomerate and some dot-like protrusions appear on the surface of the unburned aluminum particles. The inhibition mechanism was qualitatively investigated. Physical heat absorption is proven to play a limited role. Thermal radiation and chemical inhibition play a key role. The chemical effect mainly influences the surface reaction energy source. 相似文献
84.
Although the effects of jet fires are often limited to rather short distances, if their flames impinge on a pipe or a vessel collapse can occur in very short times. In such cases, the heat flux on the affected equipment is very high and wall temperature can increase very rapidly. This can happen in parallel pipelines, if a release occurs and impinges on another one. Nevertheless, jet fire impingement has been scarcely studied. In this communication the results obtained from an experimental set-up are presented. Sonic jet fires impinged on a pipe containing stagnant air or water. The temperatures of the flames impinging on it were measured for the worst case (flame front-bright zone), as well as the evolution with time of the pipe wall temperature at different locations. Initial temperature increases up to around twenty °C/s were registered for the air inside, with maximum values of up to 600 °C reached in 2.5 min, and 800 °C in approximately 9 min. In the case of pipe containing water, in the zone of the wall in contact with the liquid the heating rates were much lower, the maximum temperature reached being up to approximately 150 °C. From the temperatures of the jet flames and of the pipe, the heat fluxes reaching the pipe and the corresponding heat transfer coefficients were obtained. The results obtained emphasized that safe distances are essential in pipelines, together with fire proofing and other safety measures. 相似文献
85.
The hybrid mixture of combustible dusts and flammable gases/vapours widely exist in various industries, including mining, petrochemical, metallurgical, textile and pharmaceutical. It may pose a higher explosion risk than gas/vapor or dust/mist explosions since the hybrid explosions can still be initiated even though both the gas and the dust concentration are lower than their lower explosion limit (LEL) values. Understanding the explosion threat of hybrid mixtures not only contributes to the inherent safety and sustainability of industrial process design, but promotes the efficiency of loss prevention and mitigation. To date, however, there is no test standard with reliable explosion criteria available to determine the safety parameters of all types of hybrid mixture explosions, nor the flame propagation and quenching mechanism or theoretical explanation behind these parameters. This review presents a state-of-the-art overview of the comprehensive understanding of hybrid mixture explosions mainly in an experimental study level; thereby, the main limitations and challenges to be faced are explored. The discussed main contents include the experimental measurement for the safety parameters of hybrid mixtures (i.e., explosion sensitivity and severity parameters) via typical test apparatuses, explosion regime and criterion of hybrid mixtures, the detailed flame propagation/quenching characteristics behind the explosion severities/sensitivities of hybrid mixtures. This work aims to summarize the essential basics of experimental studies, and to provide the perspectives based on the current research gaps to understand the explosion hazards of hybrid mixtures in-depth. 相似文献
86.
Low-concentration gas transported in pipelines may lead to explosion accidents because gas with a concentration of less than 30% is prone to explode. To reduce the incidence of gas explosions, water sealing of fire barriers is implemented, and explosion venting devices are installed along the pipeline. To investigate their suppression effect on low-concentration gas explosion, experiments using methane–air premixed gas under different conditions were implemented on a DN500 pipeline test system. The effects of three types of explosion venting forms (rupture disc, asbestos board, and plastic film) on explosion overpressure and flame were compared and analysed. Results show that the rupture disc, asbestos board, and plastic film can achieve adequate explosion venting, causing the peak decay rates of explosion overpressure to reach 82.37%, 81.72%, and 90.79%, respectively. The foregoing indicates that the greater the static activation pressure of the explosion venting form, the higher the peak explosion overpressure at each measurement point. Moreover, the shorter the explosion flame duration, the greater the flame propagation velocity. The research results provide an essential theoretical foundation for the effective suppression of gas explosion accidents in the process of low-concentration gas transportation. 相似文献
87.
In this paper flame microstructures and propagation characteristic of methane explosion are studied by high speed schlieren photography technique. By experiment it shows that flame front surface and inner flow field of methane explosion has distinctly fractal characteristic, the effect of the wrinkle of flame front surface and inner reactants on flame propagation can be directly reflect by fractal dimensions. Fractal dimension has a direct relation to flame structure and flame propagation characteristics, and it is the important parameter to scale the flame propagation velocity and flame temperature. 相似文献
88.
89.
使用聚苯胺(PANI)与氮化硼(BN)作为阻燃体系,采用一步法对棉布进行阻燃改性,研究了PANI与BN的配比对Cotton-PANI-covered BN复合材料形貌的变化以及对阻燃性能、热稳定性的影响。由扫描电镜(SEM)和全反射傅里叶红外(ATR-FTIR)测试结果可知,PANI成功生长在棉布纤维表面。另外由于PANI的粘附性,BN能被粘附在棉织物表面,从而形成更为致密的包覆结构。研究发现,PANI和BN的存在,能大大提高棉布的热稳定性和成炭性。当PANI的浓度为2.7 wt%,BN的浓度为5.9 wt%时,改性棉布的残炭量能达到8.9%,比纯棉布(0.6%)增加了约14倍。同样,垂直燃烧实时图像能看出PANI/BN改性的棉布的残炭量更高,炭层也更完整,表明PANI和BN具有优良的阻燃效果。 相似文献
90.
Current liquid flammability classification mainly relies on flash point and its risk is largely dependent on consequence and probability. However, combustions of liquefied marine fuels have their uniqueness, leading to a less consistent with the common classification. This work aims at classifying flammable liquids in compression ignition engines for further safety evaluation. Besides liquid flammability characteristics, flame propagation and aerosol formulation are considered. Two unsupervised machine learning clustering algorithms, k-means and spectral clustering, are applied to the collected liquid compounds database. To consider both cluster cohesion and separation, the global mean silhouette value is used to find the optimal number of clusters and to evaluate the clustering performance. The results show that the spectral clustering outperforms k-means on classifying the risk ratings for all proposed models, while the clustering accuracy of the optimal model has been doubled by employing spectral clustering algorithm. Moreover, principal component analysis and star coordinate diagrams are presented to visualize high dimensional data to 2-D graphs. Finally, the overall liquid safety performance is evaluated by a novel combustion risk index via the weight values determined by the information entropy approach. This index can be used to explore inherently safer fuels in the process industries. 相似文献