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881.
Numerical simulation tools have been used to study the dominating processes during transport of aromatic hydrocarbons in the unsaturated soil zone. Simulations were based on field observations at an experimental site located on a glacial delta plain with pronounced layered sedimentary structures. A numerical model for transport in the unsaturated zone, SWMS-3D, has been extended to incorporate coupled multispecies transport, microbial degradation following Monod kinetics and gas diffusive transport of oxygen and hydrocarbons. The flow field parameters were derived from previous work using nonreactive tracers. Breakthrough curves (BTC) from the hydrocarbon field experiment were used to determine sorption parameters and Monod kinetic parameters using a fitting procedure. The numerical simulations revealed that the assumption of homogeneous layers resulted in deviations from the field observations. The deviations were more pronounced with incorporation of reactive transport, compared with earlier work on nonreactive transport. To be able to model reasonable BTC, sorption had to be reduced compared to laboratory experiments. The initial biomass and the maximum utilisation rate could be adjusted to capture both the initial lag phase and the overall degradation rate. Nevertheless, local oxygen limitation is predicted by the model, which was not observed in the field experiment. Incorporation of evaporation and diffusive gas transport of the hydrocarbons did not significantly change the local oxygen demand. The main cause of the observed discrepancies between model and field are attributed to channelling as a result of small-scale heterogeneities such as biopores. 相似文献
882.
Qianfeng Li Di Hu Sirakarn Leungsakul Richard M. Kamens 《Atmospheric environment (Oxford, England : 1994)》2007,41(40):9341-9352
This work merges kinetic models for α-pinene and d-limonene which were individually developed to predict secondary organic aerosol (SOA) formation from these compounds. Three major changes in the d-limonene and α-pinene combined mechanism were made. First, radical–radical reactions were integrated so that radicals formed from both individual mechanisms all reacted with each other. Second, all SOA model species from both compounds were used to calculate semi-volatile partitioning for new semi-volatiles formed in the gas phase. Third particle phase reactions for particle phase α-pinene and d-limonene aldehydes, carboxylic acids, etc. were integrated. Experiments with mixtures of α-pinene and d-limonene, nitric oxide (NO), nitrogen dioxide (NO2), and diurnal natural sunlight were carried out in a dual 270 m3 outdoor Teflon film chamber located in Pittsboro, NC. The model closely simulated the behavior and timing for α-pinene, d-limonene, NO, NO2, O3 and SOA. Model sensitivities were tested with respect to effects of d-limonene/α-pinene ratios, initial hydrocarbon to NOx (HC0/NOx) ratios, temperature, and light intensity. The results showed that SOA yield (YSOA) was very sensitive to initial d-limonene/α-pinene ratio and temperature. The model was also used to simulate remote atmospheric SOA conditions that hypothetically could result from diurnal emissions of α-pinene, d-limonene and NOx. We observed that the volatility of the simulated SOA material on the aging aerosol decreased with time, and this was consistent with chamber observations. Of additional importance was that our simulation did not show a loss of SOA during the daytime and this was consistent with observed measurements. 相似文献
883.
Fuster G Schuhmacher M Domingo JL 《Environmental science and pollution research international》2001,8(2):91-94
The present study was intended to establish an inventory of PCDD/F emissions in Tarragona Province (Catalonia, NE Spain), as a preliminary phase in the development of a flow analysis of PCDD/Fs in this Province. In 1999, global PCDD/F emissions reached a value of 2.24 g I-TEQ/y, which means a density of 3.8 micrograms I-TEQ/inhabitant/y. The low amount of PCDD/Fs emitted to air by the only municipal solid waste incinerator in the Province (approximately 0.04% of the total) has been one of the most notable results. As a reflection of uncertainties in the estimates for individual sources, the 90th percentiles of PCDD/F releases for 1999 ranged up to 4.1 g I-TEQ/y. 相似文献
884.
Abstract: We developed a simple model of Pinus strobus L. stand dynamics to compare the impacts of different temporal arrangements of surface fires designed to reflect the application of fire as both an essential ecosystem process (natural fire) and as an efficient means of producing specific habitat features or other values (optimal fire). We used a stochastic simulation model of fire processes to estimate the mean fire-return interval that would maximize stand structural diversity. We investigated trade-offs between structural diversity and temporal population stability associated with changes in the fire interval and used a deterministic version of the model to explore the effects of scheduling fires at fixed intervals. In stochastic simulations, maximum structural diversity occurred at intermediate levels of disturbance (40-year mean fire interval). When fires were scheduled at fixed intervals, a longer, 100-year return interval maximized diversity. Mean fire-return interval was a mitigating factor in the diversity-stability relationship, which changed from positive to negative as the fire interval was reduced progressively from 250 to 5 years. As an alternative to scheduling fires at specified mean intervals, we developed a goal-programming model (a form of linear programming model) and used it to identify an optimal fire schedule for achieving habitat and visual-quality objectives. In comparison with the 40-year stochastic mean fire interval, which maximized structural diversity, the optimal schedule produced comparable levels of both diversity and fire frequency. Our results show how simulation and goal-programming models can be used to evaluate prescribed fire-scheduling alternatives and to explore the comparative advantages of natural and optimal fire-management approaches. 相似文献
885.
Wind Tunnel Experiments and Numerical Simulation of Snow Drifting around an Avalanche Protecting Dam
To learn about wind flow and snow drifting around avalanche dams, experiments were done in the Jules Verne Climatic Wind Tunnel. The paper reports the results from numerical wind flow simulations that were done to support the findings from the wind tunnel. Satisfying the model similitude criteria for the wind tunnel configuration was difficult due to the inevitable small geometric scale of the model, while on the contrary the snow drifting conditions in the facilities were full scale. By comparing numerical wind flow results of full scale and model scale dams with the snow pattern observed in the wind tunnel, it was possible to conclude that albeit poor model similitude, the snowdrifts on the windward side of the wind tunnel model are likely to indicate the full scale natural situation. 相似文献
886.
蔬菜地土壤磷提取及模拟径流中磷素潜在流失的影响 总被引:1,自引:1,他引:1
蔬菜地磷素流失是一种典型农业非点源污染类型。通过观测地表径流中溶解态反应磷(DRP)、生物可利用磷(BAP)可以监测土壤磷素流失程度。受到各种客观条件的限制,这两个指标比较难于获取,而土壤中的总磷(TP)、Olsen(OP)、Mehlich-1(M-1P)和水溶性磷(Pw)可以通过常规分析手段获取。本文选取27个典型蔬菜样地,分析测定各样地土壤中的总磷(TP)、Olsen(OP)、Mehlich-1(M-1P)和水溶性磷(Pw)四个磷提取变量,采用了经典方法计算土壤磷流失潜能指标——磷吸持饱和度(DPS)。同时采用模拟径流实验得出典型蔬菜样地地表径流样中溶解态反应磷(DRP)、生物可利用磷(BAP)。结果表明:M-1P、Pw与DPS呈极显著正相关,相关系数分别达到了0.85和0.74(p<0.01);而M-1P、Pw与DRP浓度相关系数(r2=0.843和0.786,p<0.01)大于TP、OP与DRP浓度的相关系数(r2=0.554和0.722,p<0.01)。结论认为,通过测定M-1P、Pw和计算DPS能比较准确、便捷地预测土壤径流磷素流失风险程度。 相似文献
887.
Simulation of Ekman Boundary Layers by Large Eddy Model with Dynamic Mixed Subfilter Closure 总被引:2,自引:0,他引:2
I. Esau 《Environmental Fluid Mechanics》2004,4(3):273-303
Theoretical analysis of boundary layer turbulence has suggested a feasibility of sufficiently accurate turbulence resolving
simulations at relatively coarse meshes. However, large eddy simulation (LES) codes, which employ traditional eddy-viscosity
turbulence closures, fail to provide adequate turbulence statistics at coarse meshes especially within a surface layer. Manual
tuning of parameters in these turbulence closures may correct low order turbulence statistics but severely harms spectra of
turbulence kinetic energy (TKE). For more than decade, engineering LES codes successfully employ dynamic turbulence closures.
A dynamic Smagorinsky turbulence closure (DSM) has been already tried in environmental LES. The DSM is able to provide adequate
turbulence statistics at coarse meshes but it is not completely consistent with the LES equations. This paper investigates
applicability of an advanced dynamic mixed turbulence closure (DMM) to simulations of Ekman boundary layers of high Reynolds
number flows. The DMM differs from the DSM by explicit calculation of the Leonard term in the turbulence stress tensor. The
Horizontal Array Turbulence Study (HATS) field program has revealed that the Leonard term is indeed an important component
of the real turbulence stress tensor.
This paper presents validation of a new LES code LESNIC. The study shows that the LES code with the DMM provides rather accurate
low order turbulence statistics and the TKE spectra at very coarse meshes. These coarse LES maintain more energetic small
scale fluctuations of velocity especially within the surface layer. This is critically important for success of simulations.
Accurate representation of higher order turbulence statistics, however, requires essentially better LES resolution. The study
also shows that LES of the Ekman boundary layer cannot be directly compared with conventionally neutral atmospheric boundary
layers. The depth of the boundary layer is an important scaling parameter for turbulence statistics. 相似文献
888.
In many environmental studies measuring the amount of a contaminant in a sampling unit is expensive. In such cases, composite sampling is often used to reduce data collection cost. However, composite sampling is known to be beneficial for estimating the mean of a population, but not necessarily for estimating the variance or other parameters. As some applications, for example, Monte Carlo risk assessment, require an estimate of the entire distribution, and as the lognormal model is commonly used in environmental risk assessment, in this paper we investigate efficiency of composite sampling for estimating a lognormal distribution. In particular, we examine the magnitude of savings in the number of measurements over simple random sampling, and the nature of its dependence on composite size and the parameters of the distribution utilizing simulation and asymptotic calculations. 相似文献
889.
We review the fundamentals of a new numerical modeling technique called Renormalized Numerical Simulation (RNS). The goal
of RNS is to model the drag force produced by high Reynolds-number turbulent flow over objects that display scale-invariant
properties, objects such as tree-like fractals. The hallmark of RNS in this application is that the drag of the unresolved
tree branches is modeled using drag coefficients measured from the resolved branches and unresolved branches (as modeled in
previous iterations of the procedure). In the present paper, RNS is used to study the effects of branch orientation on the
drag force generated by highly idealized trees in which trunk and branches have square cross-section, and the branches all
lie in a plane perpendicular to the incoming flow. Then, the procedure is generalized to the more general case of non-planar
branch arrangements. Results illustrate that RNS may enable numerical modeling of environmental flow processes associated
with fractal geometries using affordable computational resolution. 相似文献
890.
Haolan Lu Cavan S. Reilly Sudipto Banerjee Bradley P. Carlin 《Environmental and Ecological Statistics》2007,14(4):433-452
Recently, public health professionals and other geostatistical researchers have shown increasing interest in boundary analysis, the detection or testing of zones or boundaries that reveal sharp changes in the values of spatially oriented variables.
For areal data (i.e., data which consist only of sums or averages over geopolitical regions), Lu and Carlin (Geogr Anal 37: 265–285,
2005) suggested a fully model-based framework for areal wombling using Bayesian hierarchical models with posterior summaries
computed using Markov chain Monte Carlo (MCMC) methods, and showed the approach to have advantages over existing non-stochastic
alternatives. In this paper, we develop Bayesian areal boundary analysis methods that estimate the spatial neighborhood structure
using the value of the process in each region and other variables that indicate how similar two regions are. Boundaries may then be determined by the posterior distribution
of either this estimated neighborhood structure or the regional mean response differences themselves. Our methods do require
several assumptions (including an appropriate prior distribution, a normal spatial random effect distribution, and a Bernoulli
distribution for a set of spatial weights), but also deliver more in terms of full posterior inference for the boundary segments
(e.g., direct probability statements regarding the probability that a particular border segment is part of the boundary).
We illustrate three different remedies for the computing difficulties encountered in implementing our method. We use simulation
to compare among existing purely algorithmic approaches, the Lu and Carlin (2005) method, and our new adjacency modeling methods.
We also illustrate more practical modeling issues (e.g., covariate selection) in the context of a breast cancer late detection
data set collected at the county level in the state of Minnesota. 相似文献