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231.
232.
废FCC催化剂对水中铅离子的连续吸附及脱附 总被引:1,自引:0,他引:1
通过测定吸附等温线,考察了Pb2+在废FCC(流化催化裂化)催化剂上的吸附性能及规律,结果表明,Pb2+在废FCC催化剂上的吸附规律可用Langmuir和Frundlich模式描述,吸附呈单分子层形式且容易进行。又通过填充床吸附试验,对Pb2+的连续吸附及脱附情形作了考察。结果表明,在温度为15℃、pH为5.13、过柱速率为3.0mL/min、径高比为2.25.0条件下,吸附柱具备适宜的生产周期,连续吸附操作可行,柱效率可达75.9%;在温度为15℃、采用2mol/L稀盐酸作脱附剂,过柱速率为5.0mL/min的条件下,吸附剂易于脱附再生,脱附效率可达78.1% 相似文献
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通过改变内循环生物流化床的启动水质,提高N/C组成以强化流化床后期的硝化作用.结果表明,高N/C和低进水COD强化启动后处理生活污水,在HRT为2h时,可以同时高效去除COD和氨氮,氨氮的平均去除率为74%.耗氧速率试验表明,强化启动后,流化床中生物膜的异养菌活性大幅度降低,氨氧化细菌活性明显提高,硝化细菌活性变化不大.对反应系统微生物醌进行的跟踪分析表明,强化启动后,生物膜中的硝化细菌数量明显增加,微生物种群的分布均匀性变化较小,以革兰氏阴性菌为主.扫描电镜观察显示,低N/C启动条件下,生物膜厚且致密,异养菌所占比例高;高N/C启动条件有利于硝化细菌的生长,生物膜相对稀薄. 相似文献
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236.
XIE Jian-jun YANG Xue-min ZHANG Lei DING Tong-li SONG Wen-li LIN Wei-gang 《环境科学学报(英文版)》2007,19(1):109-116
This paper presents the experimental investigations of the emissions of SO2, NO and N2O in a bench scale circulating fluidized bed combustor for coal combustion and co-firing coal and biomass. The thermal capacity of the combustor is 30 kW. The setup is electrically heated during startup. The influence of the excess air, the degree of the air staging, the biomass share and the feeding position of the fuels on the emissions of SO2, NO and N2O were studied. The results showed that an increase in the biomass shares resulted in an increase of the CO concentration in the flue gas, probably due to the high volatile content of the biomass. In co-firing, the emission of SO2 increased with increasing biomass share slightly, however, non-linear increase relationship between SO2 emission and fuel sulfur content was observed. Air staging significantly decreased the NO emission without raising the SO2 level. Although the change of the fuel feeding position from riser to downer resulted in a decrease in the NO emission level, no obvious change was observed for the SO2 level. Taking the coal feeding position R as a reference, the relative NO emission could significantly decrease during co-firing coal and biomass when feeding fuel at position D and keeping the first stage stoichiometry greater than 0.95. The possible mechanisms of the sulfur and nitrogen chemistry at these conditions were discussed and the ways of simultaneous reduction of SO2, NO and N2O were proposed. 相似文献
237.
循环流化床半干法烟气脱硫技术是目前世界上主流脱硫工艺技术之一,主要适用于大中型燃煤电厂的烟气脱硫,在国内外拥有大量成功运行的工程案例。本文章基于本公司实践论述Turbosorp湍流吸收循环流化床脱硫技术的技术特点、关键工艺控制要点以及在机组改造工程中的技术优势,为同类型机组改造工程中的方案选择提供参考。 相似文献
238.
Awoke Guadie Siqing Xi Wei Jiang Lijie Zhou Zhiqiang Zhang Slawomir W. Hermanowicz Xiaoyin Xu Shuang Shen 《环境科学学报(英文版)》2014,26(4):765-774
The feasibility of struvite recovery at low (12.5 mg/L) and high (120 mg[L) phosphorus concentrations was studied by constructing a novel fluidized bed reactor with cones (FBRwc) and without cones (FBRwoc). The crystallization process was continuously operated for 133 days under different hydraulic retention times (HRT = 1-10 hr), pH (7.5-10), and molar ratios of Mg/P (0.75-1.75), N/P (1-10) and Ca/Mg (0-2). The optimum operating conditions of HRT, pH, Mg/P and N/P molar ratios were found to be 2 hr, 9, 1.25, and 7.5, respectively. Under these optimum conditions, the phosphorus precipitation efficiencies of FBRwc were 93% for low and 98% for high phosphorus influent; however, the efficiencies were 78% and 81% for FBRwoc, respectively. Due to crystal losses at each junction (17%-31%), the crystal recovery efficiency of FBRwoc was relatively low (47%-65%) for both influent concentrations. However, the losses were minimal in FBRwc, which showed 75% and 92% crystal recovery for low and high phosphorus concentrations, respectively. At low calcium concentration, crystal chemical analysis showed the product to be pure struvite (〉 99%). The scanning electron microscope and X-ray diffraction results further confirmed that the crystal recovered from FBRwc contained pure struvite, which could be considered a high quality fertilizer. Except HRT, all parameters (pH, Mg/P, N/P and Ca/Mg) were found to be influencing factors for FBRwc performance. Overall, inserting cones in each part of the reactor played a significant role in enhancing struvite recovery from a wide range of phosphorus-containing wastewater. 相似文献
239.
240.
全程自养脱氨氮悬浮填料床反应器性能的研究 总被引:8,自引:0,他引:8
以NH+4-N溶液为基质建立和启运了全程自养脱氨氮悬浮填料床反应器,反应器连续运行的实验结果表明在pH为8.0~8.5、溶解氧为0.7~1.0mg/L和温度为28℃的条件下.当氨氮表面负荷为2~2.5g/(m2@d)时,其表面去除速率为1.1~1.3/(m2@d),全程自养脱氮率基本稳定在55%左右;全程自养脱氮的最适pH范围为7.5~8,5,其中最佳pH为8.0左右;最适溶解氧范围为0.5~1.5mg/L,其中尤以0.8~1.0ms/L左右为最佳. 相似文献