Regeneration performance and carbon consumption of semi-coke and activated coke for SO2 and NO removal

To decrease the operating cost of flue gas purification technologies based on carbon-based materials, the adsorption and regeneration performance of low-price semi-coke and activated coke were compared for SO₂ and NO removal in a simulated flue gas. The functional groups of the two adsorbents before and after regeneration were characterized by a Fourier transform infrared (FTIR) spectrometer, and were quantitatively assessed using temperature programmed desorption (TPD) coupled with FTIR and acid–base titration. The results show that semi-coke had higher adsorption capacity (16.2% for SO₂ and 38.6% for NO) than activated coke because of its higher content of basic functional groups and lactones. After regeneration, the adsorption performance of semi-coke decreased because the number of active functional groups decreased and the micropores increased. Semi-coke had better regeneration performance than activated coke. Semi-coke had a larger SO₂ recovery of 7.2% and smaller carbon consumption of 12% compared to activated coke. The semi-coke carbon-based adsorbent could be regenerated at lower temperatures to depress the carbon consumption, because the SO₂ recovery was only reduced a small amount.     

Preparation and evaluation of aminopropyl-functionalized manganese-loaded SBA-15 for copper removal from aqueous solution

A novel material, aminopropyl-functionalized manganese-loaded SBA-15 (NH₂-Mn-SBA- 15), was synthesized by bonding 3-aminopropyl trimethoxysilane (APTMS) onto manganeseloaded SBA-15 (Mn-SBA-15) and used as a Cu²⁺ adsorbent in aqueous solution. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction spectra (XRD), N₂ adsorption/ desorption isotherms, high resolution field emission scanning electron microscopy (FESEM) and X-ray photoelectron spectroscopy (XPS) were used to characterize the NH₂-Mn-SBA-15. The orderedmesoporous structure of SBA-15 was remained aftermodification. The manganese oxides were mainly loaded on the internal surface of the pore channels while the aminopropyl groups were mainly anchored on the external surface of SBA-15. The adsorption of Cu²⁺ on NH₂-Mn-SBA-15 was fitted well by the Langmuir equation and the maximum adsorption capacity of NH₂-Mn-SBA-15 for Cu²⁺ was over two times higher than that of Mn-SBA-15 under the same conditions. The Elovich equation gave a good fit for the adsorption process of Cu²⁺ by NH₂-Mn-SBA-15 and Mn-SBA-15. Both the loaded manganese oxides and the anchored aminopropyl groups were found to contribute to the uptake of Cu²⁺. The NH₂-Mn-SBA-15 showed high selectivity for copper ions. Consecutive adsorption-desorption experiments showed that the NH₂-Mn-SBA-15 could be regenerated by acid treatment without altering its properties.     

香溪河附石性大型底栖动物功能摄食类群研究

利用1∶50 000地形图对香溪河进行划分,显示香溪河为一条6级河流。分析包括捕食者(PR)、撕食者(SH)、刮食者(SC)、直接收集者（GC）和过滤收集者(FC)在内的5个主要功能摄食类群的组成,发现香溪河主要摄食类群以直接收集者和刮食者为主。各功能摄食类群的密度和生物量随着河流级别的变化而发生变化,基本趋势为：直接收集者和滤食者的密度和生物量都随着河流级别的增加而增大;撕食者和刮食者的密度和生物量的密度随着河流级别的增加而减小;而捕食者在整个流域内的密度上游小于下游,生物量却是上游大于下游。研究结果表明香溪河在夏季其上游物质来源以附石性藻类生产为主,下游则以异源性细有机颗粒输入为主。此外,功能摄食类群的密度与部分环境因子具有显著的相关性：过滤收集者与Ca2+和河宽相关,收集者与SiO2相关显著,刮食者与海拔和氨氮相关性较高,撕食者与电导和PO4 P相关性较高.     

Welfare Balance of Different Interest Groups During Rural-urban Land Conversion

Rural-urban land conversion is currently a common social economic phenomenon during the process of economic development and rural urbanization in China. Rural-urban land conversion is positively effective as far as social and economic benefits are concerned （Yang, 2002）, but its negative effect is also evident, resulting in such problems as low efficiency of rural land configuration and loss of social welfare. Consequently, farmers should also have an equal chance to enjoy the social welfare enhanced by land conversion. Based on the theories of welfare economy, this paper puts forward policy suggestions by discussing the welfare changes of various interest groups, builds the model of welfare distribution, and analyzes the conditions of maximizing social welfare. The absolute and opposite value of social welfare is closely related with the speed of rural-urban land conversion, and governments should give farmers and collectives fair compensation to make up for the utility loss caused by land expropriation, which are conclusions drawn from this paper. This study aims to provide a theoretical basis for regulating targets and evaluation criteria, realizing the mechanism and implementation of public polices during rural-urban land conversion.     

旅游交通弱势群体景区偏好与可达度研究——以大学生秦岭景区旅游为例

针对交通弱势群体的旅游可达问题,通过RBF插值法对秦岭景区大学生的偏好度与公共交通可达度(PTA)之间的关系进行研究.研究发现:①现实偏好度(AP)和潜在偏好度(PP)的高聚集区和低分散区吻合,而其他区域的差异较大,AP呈阶梯状变化而PP分布均衡；②可达性较高区域中的AP与PP吻合,而在较低区域中差异较大；③邻近中心城镇区域中PP与PTA呈正相关,而远离中心城镇区域中两者的影响不大.因此,提高公共交通可达度有助于实现旅游的民生功能.     

汶川8.0级地震灾后响应研究——以灾后学生响应为例

基于网络信息,以学生群体对汶川8.0级地震响应为研究对象,通过对搜集到的复杂网络信息的分类和分级,刻画出非灾区学生群体的灾害响应能力,探讨了学生灾后响应主要类型、强度的空间分异及灾后响应的驱动力。结果表明：①学生灾后响应的主要类型是学生自发捐款、中小学异地复课等;②造成学生灾后响应空间差异的主要因素不是交通条件,而是空间距离导致心理疏离;③学生灾后响应的驱动力随时间的变化特征不同,其中满足自我强化需要的响应速度快但持续性较低,而满足灾源地的需要的响应速度慢但持续性高。     

活性炭脱除烟气中SO2的研究进展

活性炭是一种高效吸附剂,在烟气脱硫领域有广阔的应用前景。在分析国内外试验结果的基础上,综述了活性炭孔隙结构及表面化学性质对其脱硫性能的影响,阐述了活性炭脱硫的反应机理,指出了未来研究方向。     

The influence of different surface-modification treatments on biomass-based carbons and their effects on adsorption of carbon dioxide

Surface modification of biomass-based carbon with nitrogen-containing functional groups is performed by the different modification method, including the thermal and chemical methods. We also investigate the effect of the different reaction parameters on their pore structure using the Brunauer–Emmett–Teller surface area and adsorption performance based on methylene blue value. Fourier transforms infrared spectroscopy methods are performed to confirm the presence of N-containing groups. Based on above results, the comparison effect of different modification methods on physico-chemical propriety and adsorption properties of biomass-based carbon materials are carried out. In conclusion, all modification methods could enhance CO₂ adsorption capability. However, the carbon materials treated with ammonia using thermal method show the best performance.     

氮改性活性碳纤维的脱硫作用

为了提高活性碳纤维的脱硫性能,使用三聚氰胺、氯化铵、尿素作为改性剂对活性碳纤维进行改性,得到一系列含氮活性碳纤维(N-ACFs).通过XPS研究了改性活性碳纤维的表面化学结构的变化,并测定了其脱硫性能.实验发现:三聚氰胺改性ACF的最大累积硫容为38.26 mg/g,氯化铵改性ACF的最大累积硫容33.69 mg/g,...