Predictions for isomer distributions of toxic dioxins and furans in selected industrial combustion processes

Three thermodynamic databases of polychlorinated dibenzo-p-dioxins and dibenzo-furans (PCDD/Fs) have been used to simulate the PCDD/F isomer distribution in industrial combustion processes. The three databases had been derived using the Group Additivity approach and two computational molecular modelling methods, Modified Neglect of Diatomic Overlap (MNDO) and Parametrized Model 3 (PM3), respectively. The predictions of the toxic PCDD/F isomer distributions using the three different databases have been compared with measured values from industrial processes. An excellent agreement between the predictions using the MNDO method and the measured data has been obtained. It is concluded that the PCDD/F isomer distributions within each group observed in these combustion processes may be thermodynamically controlled.     

三明化工厂开展班组危险预防分析活动几点经验

介绍了班组开展危险预防分析活动的几种方法与经验。     

企、事业单位专职安技员队伍建设探讨

本文对专职安技员及队伍现状进行了分析,根据专职安技员的职业生涯三阶段客观规律,偿试将个人和组织的需要进行合理匹配,探讨提高专职安技员业务素质和安技队伍专业水平的对策.     

器材类武警装备环境适应性评估模型研究

目的研究器材类武警装备环境适应性评估模型。方法通过分析武警装备环境适应性要求类型及特点,提出器材类武警装备环境适应性评价因素集,分析环境因素的影响特征,基于历史数据和问卷调查确定各环境因素影响的隶属函数。结果建立了考虑时间的器材类武警装备环境适应性模糊综合评估模型。结论通过实例验证了该模型合理,方法可行。     

Prediction models for the flash point of pure components

The flash point for a liquid is defined as the lowest temperature at which its vapor forms a spontaneously ignitable mixture when brought in contact with air. Having a good estimation of the flash point temperature at normal conditions is relevant because it is one of the main properties used to characterize fire and explosion hazards for liquids. Most of predictive correlations in the literature include a physical effect by including the normal boiling temperature in their formulation. To achieve combustion, sufficient evaporation is required and then a part of the liberated energy from the combustion is used to support the evaporation. Thus the evaporation energy and a chemical effect given by the heat of reaction are incorporated in this work. It is firstly verified that the relation between the flash point temperature and the normal boiling temperature tends to be a constant. Thus a heuristic approach based on 611 chemical species of diverse families indicates that this relation is around 0.75. The dispersion of the error has been reduced by using two proposed correlations where both physical and chemical properties are included in the model. In particular, the second equation is based on the group contributions method, which has been developed for alkanes. This method is in fact a combination of the group contributions method and the first model to overcome the difficulties in predicting isomeric differences.     

荷兰生态（有机）农业对上海农业发展的借鉴

安全高效、资源节约、环境友好型的生态农业生产技术,已成为国际农业领域研究和关注的热点;发展高效生态（有机）农业,以新的强度和效能为长三角和我国现代化农业发展作贡献,是上海社会主义新农村建设的重大战略,是上海现代农业发展的必由之路。荷兰生态（有机）农业发展提供了以下成功经验：以生态学原理指导农业生产,实现生产生态共荣;在农产品生产中应用HACCP理论,加强农业生产的过程控制和质量管理;通过制定良好农业技术规范（Eurep-GAP）,保障农业的可持续发展,保护生态环境。上海发展高效生态（有机）农业的对策建议：加强政策扶持,深化有机农业理论和技术研究,建立和规范与国际接轨的认证体系,以生态学的原理和原则指导农业生产和技术的发展。     

Costs of switching social groups for dominant and subordinate dark-eyed juncos (Junco hyemalis)

I quantified the costs of switching from a familiar to an unfamiliar flock for captive dark-eyed juncos (Junco h. hyemalis) by measuring several physiological and behavioral variables before and after flock switching. Birds that were initially dominant dropped in status in unfamiliar flocks, and experienced increased metabolic rates, while subordinate birds appeared to undergo less physiological change when switching flocks. This difference occurred despite a lack of any rank-related differences in the effects of joining a new flock on rates of aggression, weight change, access to food, or plasma corticosterone levels. These results suggest that for dominant, but not subordinate, individuals there is a measurable metabolic cost to joining a new social group, even in the absence of adverse factors such as food limitation. Dominant individuals may be less likely than subordinates to leave familiar flocks because of their higher metabolic costs when joining a new social group.     

长株潭城市群PM2.5中二次无机离子特征及生成机制

二次无机离子是大气PM_2.5的主要组分,其对城市霾污染的驱动作用愈发明显.目前长株潭城市群秋冬季PM_2.5污染形势依旧严峻,但该区域的二次转化对冬季霾污染过程以及秋冬季SNA差异特征的影响尚不明晰.2020年11月和2021年1月在长株潭城市群4个典型站点进行PM_2.5连续采样,并定量分析了SO₄^2-、 NO^-₃和NH⁺₄等组分.结果显示,秋季和冬季PM_2.5中ρ(SO₄^2-)、ρ(NO^-₃)、ρ(NH⁺₄)平均值(μg·m^-3)分别为(5.2±2.5)、(7.9±4.8)、(4.1±2.2)和(7.2±4.2)、(17.1±10.5)、(7.8±5.2).在冬季霾污染过程中,ρ(SO₄^...     

结构物损伤预测模型及其在隧道施工中的应用

基于结构物风险评估理论,构建结构物损伤预测模型,并将其应用于隧道施工的研究中,以解决在地下工程施工中引起地上建筑损伤预测的技术难题。将数值模拟与模糊数学隶属度相结合,形成对结构物在隧道工程施工状态下的损伤预测模式,并以西安地铁某区间盾构下穿高铁涵洞为算例,提取相应的智能监测数据对该预测模式的可行性进行验证。结果表明,数值模拟与模糊数学隶属度相结合的结构物损伤预测模型计算效率高,便于操作,适用于隧道工程施工时对地上建筑物的安全评估,能有效解决在地下工程施工中引起地上建筑损伤预测的技术难题。     

多目标模糊决策模型对水环境质量的评价

水质环境质量评价宜采用多项控制指标进行综合评价。在模糊理论和考虑优先隶属度的基础上,通过实例推导出水环境质量多目标模糊决策评价图,用以说明两组或两组以上的数据或变量的相互联系,以非常直观地分析概念,讨论水质变化趋势。模型可客观地评价水域单元的各类水质指标。