油田废污泥治理研究

冀东油田废水池地处环境敏感区域，对其废污泥采用固化法进行处理。在大量实验的基础上优选出了三种固化剂体系并通过多次浸泡实验、淋洗实验和静态浸出实验对固化效果进行了分析。     

东部油田采出污水处理的长远对策

从综合治理，合理利用采出污水的长远利益出发，针对东部油田高含水阶段的新特点，提出地面高效处理，地下控水稳油相结合的治理策略，探讨了相关的技术和方法，并讨论了采出污水回注利用中应加强研究的几个问题。     

Distribution of pesticides and heavy metals in trophic chain

Determination of triazines herbicides (atrazine and simazine) by high performance liquid chromatography (HPLC) in samples of trophic chain were worked out. Determination limits of 0.5 μg g⁻¹ for atrazine, 0.8 μg g⁻¹ for simazine with pesticides recovery of 70–77% in trophic chain samples were obtained. The content of simazine in soils was in range 1.72–57.89 μg g⁻¹, in grass 5–88 μg g⁻¹, in milk 2.32–15.29 μg g⁻¹, in cereals 10.98–387 μg g⁻¹, in eggs 30.14–59.48 μg g⁻¹, for fruits: 2.45–6.19 μg g⁻¹. The content of atrazine in soils was in range 0.69–19.59 μg g⁻¹, in grass 7.85–23.85 μg g⁻¹, in cereals 1.88–43.08 μg g⁻¹. Cadmium, lead and zinc were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) in the same samples as atrazine and simazine. Determination limits for cadmium 5 × 10⁻³ μg g⁻¹, for lead 1 × 10⁻² μg g⁻¹, and for zinc 0.2 × 10⁻³ μg g⁻¹, were obtained. The content of cadmium in soil was in range 0.13–5.89 μg g⁻¹, in grass 114–627.72 × 10⁻³ μg g⁻¹, in milk 8.88–61.88 × 10⁻³ μg g⁻¹, in cereals 0.20–0.31 μg g⁻¹, in eggs 0.11–0.15 μg g⁻¹, in fruits 0.23–0.59 μg g⁻¹. The content of lead in soils was in range 0.57–151.50 μg g⁻¹, in grass 0.16–136.57 μg g⁻¹, in milk 1.16–3.74 μg g⁻¹, in cereals 1.05–5.47 μg g⁻¹, in eggs 5.79–55.87 μg g⁻¹, in fruits 21.00–87.36 μg g⁻¹. Zinc content in soil was in range 9.15–424.5 μg g⁻¹, in grass 35.20–55.87 μg g⁻¹, in milk 20.00–34.38 μg g⁻¹, in cereals 14.94–28.78 μg g⁻¹, in eggs 15.67–32.01 μg g⁻¹, in fruits 14.94–18.88 μg g⁻¹.

Described below extraction and mineralization methods for particular trophic chains allowed to determine of atrazine, simazine, cadmium, lead and zinc with good repeatability and precision. Emphasis was focused on liquid–liquid extraction and solid-phase extraction of atrazine and simazine from analysed materials, as well as, on monitoring the content of herbicides and metals in soil and along trophic chain. Higher concentration of pesticides in samples from west region of Poland in comparison to that of east region is likely related to common applying them in Western Europe in relation to East Europe. The content of metals strongly depends on samples origin (industry area, vicinity of motorways).     

常压立式储油罐地震应力的有限元计算

采用有限元方法 ,考虑在静载和动载共同作用下 ,对常压立式拱顶储油罐的地震应力进行了计算分析 ,给出了轴向应力的分布状态 ;并与相关抗震设计规范中的验算公式得出的结果进行了比较。结果表明 :由于地震的动力作用 ,储油罐的受力状态不是均匀分布 ,出现了峰值和谷值 ,而这些应力峰值大于工业设备抗震鉴定标准和石油化工设备抗震鉴定标准中公式的计算应力值 ,这应引起足够的注意。     

海面浮油的生物处理技术

文章就海面浮油的产生、危害、发展趋势以及防治技术进行了论述,在海面浮油处理的物理、化学、生物技术中,生物技术具有高效、低费用、无二次污染等优点。特别是处理较薄油膜或化学药品使用受限时,更有其无可替代的优点。同时还指出了生物技术的局限性。     

污水集中处理厂污水中金属(重金属)的分布

系统地建立集中污水处理装置是环境管理和污染治理的发展方向之一，在工业发达国家已相当普及，本文分析了美国和加拿大污水集中处理厂原污水和常用治理流程各工序中金属（重金属）的分布情况。结果表明，由于地理，气候，人口，特别是工业分布的影响，原污水中金属含量会有较大变化，因为变化范围大且超过排放标准2－10倍（按均值计），在设计和评价时应予化重点考虑的几种金属为：Cd,Cu,Cr,Pb,Ni和Zn，经典型的沉淀－活性污泥工艺处理后，金属除去率大于80％，可以满足排放要求。     

热水洗辅助微生物修复高含油落地油泥

为解决油田落地油泥含油率高但不能直接进行生物无害化处置的问题,探索一种热水洗辅助微生物修复工艺。利用热水洗实验考察了清洗配方和水温对降低含油率的影响;从落地油泥中分离出石油烃降解菌,以用于含油残砂的微生物降解过程,同时探究填料和烃降解微生物对残砂中石油烃降解效果的影响。结果表明,鼠李糖脂清洗剂在总用量为0.5%、水洗时间30 min和50 ℃条件下,可将油泥含油率由107.1 mg·g⁻¹降至为39.3 mg·g⁻¹;水洗后残砂中的土著菌群数量出现了明显下降。分离获得了2株烃降解菌,并优选出具有增加油泥溶氧和保水的沼渣。将烃降解微生物和优选沼渣加入残砂后,石油烃生物降解效率得到显著提升,200 d后含油率降为4.62 mg·g⁻¹。在此过程中,微生物优先降解分子量小的饱和烃和芳香烃组分,对胶质和沥青质等组分降解程度偏低。该研究结果可为油田高含油落地油泥的环保处置提供参考。     

Characteristics of large cooking oil pool fires and their extinguishment by water mist

Large cooking oil pool fires, occurring in industrial oil cookers, present a severe hazard to food processing plants due to their size and the large amount of hot oil involved. This paper reports a series of full-scale fire experiments conducted in a large industrial oil cooker mock-up. The characteristics of large cooking oil pool fires and the effect of oil depth and hood position in the oil cooker on fire growth were studied. The use of water mist for extinguishing large oil pool fires and their extinguishing performance under different discharge pressure and with different types of water mist systems were investigated. Experimental results showed that the cooking oil underwent a substantial expansion in volume during heating. The fires developed quickly once the oil auto-ignited. The fire growth rate was affected by the oil depth in the pan and the hood position in the oil cooker. The water mist fire suppression systems effectively extinguished large cooking oil fires and prevented them from re-igniting. Their extinguishing performance was determined by the type of water mist system, discharge pressure and hood position in the oil cooker.     

扬沸火灾发生时间预测模型的建立与应用分析

原油储罐扬沸火灾由池火灾发展而成,是一种危害性极大的事故.准确预测扬沸事故发生的时间,是扬沸机理研究中的难题之一.现有扬沸时间计算的通用模型由于没有考虑油品的粘性作用,计算结果误差较大.把扬沸火灾简化为无内热源的非稳态传热问题,在此基础上进行传热分析,进而推导出扬沸事故时间计算模型.设定了6组不同尺寸和不同充装水平的原油储罐池火灾,利用推导模型计算出了相应的扬沸事故发生时间.将计算结果与通用模型计算结果以及实验结果进行对比:该模型的准确性由于通用模型,计算结果与实验值误差较小,较为合理.研究结果对于扬沸火灾事故下消防人员的灭火救援的安全保障具有重要意义.     

基于三维GIS的油罐区应急管理平台研究与实现

分析油罐区危险特性和事故模式,将三维GIS系统、日常管理、监控预警、应急指挥与辅助决策等功能进行集成,建立基于三维GIS的油罐区一体化应急管理平台。该平台利用数据融合技术,将液位、可燃气体、温度等多参数进行了融合,提高了报警可靠性。同时构建了DEA-BP应急资源配置模型,结合罐区事故类型,实现了罐区重大事故应急资源的优化配置。平台还提供数字化预案和三维应急演练,为油罐区员工提高应急安全技能提供了培训环境。