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961.
Objective This study was done to estimate whether heavy metals in the air may affect endometrial chemical composition.
Materials and Methods A total of 30 albino Wistar rats were employed and randomly divided into three groups. The rats of Group 1 and 2 were acutely
and sub-chronically exposed to the gas form of heavy metals, respectively. Group 3 was used as a control group. Endometrial
tissue worth of heavy metals of the groups was measured in through using scanning electron microscope.
Results A statistically no significant difference was found for endometrial chemical composition of all of the heavy metals (chrome,
manganese, iron, cobalt, nickel, zinc and lead) between group 1 and 2 (p > 0.05). On the other hand, there was statistically significant difference for all of the heavy metals between group 1 and
group 3 (p < 0.05), while there was statistically significant difference for chrome, manganese, iron, cobalt and nickel (p < 0.05), but zinc and lead (p > 0.05) between group 2 and 3.
Conclusion Air pollutants of Pb and Zn resulting mostly from combustion of fossil fuels and certain special industrial process in Kirikkale
may be a risk factor for the high pregnancy loses by changing endometrial homeostasis. 相似文献
962.
Surface sediment samples (n = 18) were collected from the Algerian Mediterranean coasts and analyzed for seven metals using inductively coupled plasma-optical
emission spectrometry in order to asses the distribution and bioavailability of metals and to study the anthropogenic factors
affecting their concentrations. Sediment samples were size-fractionated into three sizes: 1,080–500 (coarse), 500–250 (medium),
and <250 mm (fine). Bulk sediments were subjected to both sequential extraction and total digestion to evaluate the reliability
of the sequential extraction procedure (SEP), while the fractions have been only sequentially extracted for metals speciation.
The metals were sequentially extracted into five phases namely exchangeable (P1), carbonates (P2), Fe–Mn oxides (P3), organic
(P4) and residual (P5). Metal recoveries in sequential extractions were ±20% of the independently measured total metal concentrations;
the high recovery rates indicate the good reliability of the SEP used in this study. Correlation coefficients indicated that
the grain size has an effect on the distribution of metals in the investigated samples. The order of metal levels in the fractions
was medium > fine > coarse for all the metals. The average total extractable metal concentrations for Cd, Cr, Cu, Fe, Ni,
Pb, and Zn were 1.1, 8.8, 4.7, 1,291.3, 13.9, 5.7 and 20.4 μg/g, respectively. The northeastern shelf had the lowest metal
levels while the highest were in northwestern part mainly due to the significant tourism activities in the northwestern part.
Comparison of our results to Earth’s crust values and to previous studies points out that our samples were relatively unpolluted
with respect to the heavy metals investigated; most of the metals are not from anthropogenic sources. Enrichment factors as
the criteria for examining the impact of the anthropogenic sources of heavy metals were calculated, and it was observed that
the investigated samples were not contaminated with Cr, Cu, and Fe, moderately contaminated with Ni, Pb, and Cd, and contaminated
with Cd in some sites. The P5 phase had the highest percents of Cr, Cu, Fe, Ni, and Zn. Cadmium and lead were predominant
in the P4 phase, while Cu, Fe and Zn were distributed in the order P5 > P3 > P4 > P2 > P1. The following order of bioavailability
was found with the heavy metals Pb > Cr > Cd > Ni > Zn > Cu > Fe. 相似文献
963.
Soylak M Divrikli U Saracoglu S Elci L 《Environmental monitoring and assessment》2007,127(1-3):169-176
Cellulose nitrate membrane filter was used for the preconcentration-separation of Cu, Co, Cd, Pb and Cr ions. The analyte
ions were collected on the membrane filter by the aid of carmine. Then membrane filter was dissolved by using nitric acid.
The levels of the analytes in the final solutions were determined by flame atomic absorption spectrometry (FAAS). The analytical
parameters including pH, amounts of carmine, sample volumes etc. have been optimized. No influences have been observed from
the matrix ions. The detection limits for analytes were in the range of 0.08 μg/l-0.93 μg/l. The validation of the procedure
was checked by the analysis of standard reference sediment (GBW 07309). The present method has been successfully applied for
the FAAS determinations of analyte ions in real samples including black tea and magnesium salts. 相似文献
964.
Panichayapichet P Nitisoravut S Simachaya W 《Environmental monitoring and assessment》2007,135(1-3):181-193
The aim of this study was to investigate the spatial distribution of heavy metal in soil and evaluate the dissolution of metal
from soil to ponded-surface water, leaching through soil profiles and metal uptake in grass as related to different land-use
practices. The data provided a scientific basis for best-management practices for land use in Khli Ti watershed. The watershed
has a Pb-contamination problem from the previous operation of a Pb-ore concentrator and abandoned Zn–Pb mine. Sampling sites
were selected from a land-use map, with land-use types falling into the following four categories: forest, agricultural land,
residential area and road. Soil, ponded-surface water, grass samples and soil profiles were collected. The study related soil
characteristics from different land-use practices and locations with observed metal concentrations in ponded-surface water
and soil. High enrichment factors of Pb and As in soil were found. Partitioning coefficient, Kd values were in the order: Cr > Pb > Ni > Cu > Cd > Zn. Soil disturbance from land-use activities including tillage and traffic
increased leaching of trace metal from soils. Pb in soil was significantly taken up by grass even though the Transfer Factor,
TF values were rather low. Agricultural activities in the watershed must be limited. Moreover, land encroachments in the upper
and middle part of the watershed which have high potential of Pb must be strictly controlled in order to reduce the Pb contamination
from non-point sources. 相似文献
965.
Jordão CP Ribeiro PR Matos AT Bastos RK Fernandes RB Fontes RL 《Environmental monitoring and assessment》2007,127(1-3):315-326
A study was performed to evaluate the environmental contamination in the Turvo Limpo River basin which receives effluent discharges from domestic (residential and commercial) activities. The watercourses examined were the São Bartolomeu Stream, Turvo Sujo River, and Turvo Limpo River, located in the Minas Gerais State, Brazil. Water samples were collected at the river-side and analyzed for evaluation of pollutant inputs. The pH, temperature, electrical conductivity, redox potential (Eh), dissolved oxygen (DO), total and settleable solids, visual color, hardness, chemical oxygen demand (COD), biochemical oxygen demand (BOD), chloride, total phosphate, total nitrogen, ammonia nitrogen, nitrate, total coliforms and E. coli, as well as the Cd, Pb, Cu, and Zn speciation were determined in the watercourses. The data obtained were compared with those of the Brazilian Environmental Standards and with data from non-contaminated areas. River water characteristics in some sites were far from the limit values established for superficial waters with satisfactory quality. For instance, the BOD values reached 411 mg L?1 for a maximum limit of 10.0 mg L?1, while the ammonia nitrogen concentration reached 28 mg L?1 for a maximum limit of 13.3 mg L?1. Some sites showed E. coli values above those of non-contaminated regions. Besides the effects of sewage discharges into the water-courses, agriculture activities and the use of the area for cattle husbandry influenced the quality of the river waters, for instance, the pH of a spring-water sample reached the value of 4.3. The São Bartolomeu Stream has been contributing to the deterioration of the water quality of the Turvo Sujo River, while the Turvo Limpo River has also been affected by anthropogenic discharges in the Turvo Sujo River. The speciation of Cd, Cu and Pb showed that these metals were mainly found in the particulate fraction (i. e., associated with the suspended material). Fifty five percent of the water samples showed labile Zn concentrations greater than that of the nonlabile Zn. 相似文献
966.
Quality parameters from 17 sampling stations from Lake Koronia and 18 from Lake Volvi were determined during sampling period
of one year. Physicochemical parameters (pH, conductivity, DO) did not show remarkable differences neither between sampling
sites nor between sampling periods. Nutrient concentrations (nitrogen and phosphorus compounds) were higher in lake Koronia
than in Volvi showing relatively small temporal and spatial variations. As far as heavy metals in sediments, lake Koronia
is considerably more polluted than Volvi lake especially with the metals Fe, Mn, Zn, Pb and Cd. The mean total concentrations
of metals in lake Koronia decrease in the order Mn > Zn > Cr > Pb > Cu > Fe > Cd. The mean total concentrations of metals
in lake Volvi decrease in the order Mn > Zn > Cr > Cu > Pb > Fe $>$ Cd. 相似文献
967.
Park GS 《Environmental monitoring and assessment》2007,135(1-3):153-162
Spatial and temporal distribution patterns of total suspended solids (TSS) in the shallow and macrotidal regions of the Korean
peninsula indicated there were significant changes in TSS concentrations. These were seasonally influenced by the wind, river
input and tidal cycle. There were high TSS values at estuarine and river mouth stations and during low tide due to the re-suspension
of bottom sediment by strong wind action during winter months, in addition the land input through rivers and strong tidal
current during ebbing. Monthly mean values of TSS significantly correlated with wind speed and nitrate concentration (p < 0.01). This indicated that the resuspension of surface sediment was a more important source of TSS than the river input,
and that nitrate was introduced into the water column during the resuspension process. TSS were seven times higher at low
tide than in high tide. Light penetration was significantly inhibited by TSS; as >98% of incident light was absorbed within
2 m and zero photosynthetically active radiation (PAR) under 2 m in the estuarine stations during winter. Removal of heavy
metals and nutrients by TSS in the water column was evident. Over 80% of the initial concentration of nutrients was removed
within 10 min under various concentrations of TSS and also TSS contained significantly higher concentration of heavy metals
than surface sediment. The concentration levels of nutrients and chemical oxygen demand in the west coast were comparable
with the East and South Sea, even the major rivers in the Korean peninsula flow into the West Sea with major pollutant loadings
into the coastal areas. High concentration of TSS is likely to contribute to the removal process of these pollutants, resulting
in relatively lower levels of nutrients and organic materials in these coastal waters. 相似文献
968.
海洋石油开发过程中重金属锌对海洋的影响日益受到关注。依据曹妃甸油田群海域2010—2018年长期海洋环境监测数据,采用克里金插值法和Hakanson生态风险指数法,分析了海域重金属锌的变化趋势、时空分布特征和潜在生态风险,探讨了可能来源并提出减缓措施。结果表明:研究海域海水水质锌呈现先降低后升高的趋势,平均含量2010年5月最高。2010年5月沉积物锌含量为(44.9±14.3)×10-6低于渤海表层沉积物锌含量背景值(67.6±17.0)×10-6。各期监测结果显示,油田区域未形成明显锌高值区。陆源排污、河流入海携带、航运、大气湿沉降等是研究海域重金属锌的重要来源。 相似文献
969.
钼矿区土壤中重金属污染状况的分析与评价 总被引:11,自引:0,他引:11
对葫芦岛钼矿区土壤重金属污染的情况进行了详细研究。选择土壤样本80个,采用HNO3-HF-HClO4混酸对土壤样品进行处理,运用等离子体发射光谱仪(ICP-OES)测定土壤样品中Pb、As、Hg、Cr、Cd、Zn、Cu、Ni、Mo的含量,全面系统地评价土壤重金属污染现状。结果表明,该矿区土壤重金属As、Cd和Hg污染较为严重,平均含量分别达154.13mg/kg,74.92mg/kg和3.06mg/kg。不同片区间存在明显差别,污染强度以矿山山沿污染最高,其次是运输区、选矿厂及矿区附近山地,内梅罗综合指数分别为78.34、74.34、71.42、68.55。 相似文献
970.
辽宁省大气可吸入颗粒物中重金属及多环芳烃污染特征研究 总被引:4,自引:0,他引:4
为全面了解辽宁省大气可吸入颗粒物污染状况,2004年在省内选取了5个城市进行分季节采样,并对颗粒物中重金属元素含量和美国优先控制的16种多环芳烃(PAHs)进行了定量研究。结果表明,大气PM10和PM2.5中重金属元素和PAHs污染较重,且冬季高于其它季节,重金属元素和PAHs主要富集在PM2.5及以下细小颗粒物中。 相似文献