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51.
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Thermodynamics and kinetics of cadmium adsorption onto
oxidized granular activated carbon 总被引:3,自引:0,他引:3
Cadmium sorption behavior of granular activated carbon oxidized with nitric acid was systematically studied by sets of the equilibrium and time-based experiments under various conditions.The cadmium adsorption capacity of oxidized granular activated carbon enlarged with an increase in pH,and reduced with an increase in ionic strength.Experimental data were evaluated to find out kinetic characteristics.Adsorption processes were found to follow pseudo-second order rate equation.Adsorption isotherms correlate well with the Langmuir isotherm model and the maximum sorption capacity of cadmium evaluated is 51.02μmol/g.Thermodynamic parameters were calculated based on Van't Hoff equation.Equilibrium constant Kd was evaluated from Freundlich isotherm model constants,Langmnir isotherm model constants,and isotherms,respectively.The average change of standard adsorption heatΔH~0 was -25.29 kJ/mol.NegativeΔH~0 andΔG~0 values indicate the adsorption process for cadmium onto the studied activated carbon is exothermic and spontaneous.The standard entropyΔS~0 was also negative,which suggests a decrease in the freedom of the system. 相似文献
53.
吴季松 《中国人口.资源与环境》1997,7(4):65-67
资源的有效保护和永续利用在我国可持续发展战略中占有十分重要的地位。本文分析了我国资源法制建设中存在的问题,阐述了综合资源立法在资源法制建设体系中的意义。 相似文献
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The effects of turbulence intensity (velocity gradient, G (s−1)), Henry's law constant (H), and molecular weight (M) on the volatilization rates of organic compounds are examined using changes in the mass transfer coefficients (KOL (cm/min)) under specific liquid-mixing intensities. The selected compounds were divided into three groups according to their H values (mole in gas/mole in liquid, dimensionless), which ranged from 102 to 10−5. The relationship of the KOL relative to G, H and M was obtained via multiple regression. The obtained values of these parameters indicate that the primary factor affecting the KOL values of the high H compounds is their M values. The effects of the H values on the KOL values of the high H compounds can be neglected. On the other hand, the H value is the major factor determining the KOL values of the low H compounds. The changes in the KOL values of the different H compounds exhibit different profiles as the liquid-mixing intensity increases. The M and H values of middle H compounds possibly affect their KOL values. The effects of the liquid-mixing intensity on the KOL values of the organic compounds increase with increasing H values. The variation in the KOL values might be a result of the concentration of the organic compounds at the interface between the liquid and gas films. The empirical relationship between KOL and some selected parameters, G, H and M, is examined in this study. The obtained results can help to estimate volatilization loss of organic solutes in wastewater treatment facilities. 相似文献
57.
关于植物中氟化物测定结果的计算 总被引:1,自引:0,他引:1
针对植物中氟化物测定时由于绘制校准曲线的标准溶液体积与分析样品的定容体积不一样而引出的结果计算时的某些问题,提出了正确的计算方法和建议。 相似文献
58.
单靠道德自律及经济、行政性处罚等手段 不可能从根本上解决环境问题,唯有加强法律作为硬性强制性手段,才能加大环保工作的有效性。 相似文献
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A new and simple equation has been presented here for calculation of adsorption and desorption rate constants of Langmuir-Freundlich kinetic equation. The derivation of new equation is on the basis of extension and correction to the geometric method which has been presented by Kuan et al. [Kuan, W.-H., Lo, S.-L., Chang, C.M., Wang, M.K., 2000. A geometric approach to determine adsorption and desorption kinetic constants. Chemosphere 41, 1741-1747] for the kinetics of adsorption/desorption in aqueous solutions. The correction is to consider that the concentration of solute is not constant and changes as adsorption proceeds. The extension is that we applied Langmuir-Freundlich kinetic model instead of Langmuir kinetic model to consider the heterogeneity and therefore it is more applicable to the real systems. For solving Langmuir-Freundlich kinetic model, some geometric methods and also Taylor expansion were used and finally a simple and novel equation was derived (Eq. (20)) for calculation of adsorption rate constant. This new method was named "extended geometric method". The input data of the obtained equation can be simply derived from initial data of adsorption kinetics. Finally the adsorption of methyl orange onto granular activated carbon was carried out at dynamic and equilibrium conditions and the capabilities of extended geometric method were examined by the experimental data. 相似文献
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