湿式氧化处理剩余污泥反应动力学研究

针对剩余污泥湿式氧化处理过程。以污泥中挥发分的去除为目标污染物，进行了化工废水剩余污泥．炼油废水剩余污泥湿式氧化过程动力学研究，并对湿式氧化两阶段一级动力学模型和广义动力学模型的动力学进行求解。两阶段一级动力学模型说明化工污泥．炼油污泥湿式氧化过程均属于快速反应期接慢速反应期。但不同污泥其活化能和指前因子相差较大：而用广义动力学模型可以建立通用的剩余污泥湿式氧化反应速率方程，该模型应用于城市废水剩余污泥湿式氧化过程，计算值与试验值有很好的相关性（P^2≥0．98）。     

基于对应分析法的吉林西部地下水化学特征时空演化研究

运用对应分析方法,分析了吉林西部地下水化学特征随时间、空间的变化.对研究区进行了分区,分别确定了各区的主要影响因子,并分析了各区的主要因子随时间的变化趋势.最后,结合吉林西部的水文地质条件与人类活动,分析了地下水化学成分的来源及成因.结果显示,吉林西部地下水按照其水质特征可分为3个区:Ⅰ区,位于山前平原的通榆北部、长岭南部等地及盐碱区,阴离子主要为HCO-3,总碱度大,动态变化平稳;Ⅱ区,位于西部山前平原与中部低平原区间过渡带的洮南中部、通榆东北部等地,Ca2+、Mg2+含量高,硬度大,NO-3-N含量较高,且有增大趋势;Ⅲ区,位于低平原区的乾安、前郭、大安地区,主要为高矿化度水,阴离子主要为SO2-4、Cl-,阳离子为Na+,矿化度有增大趋势.上述分析结果符合当地实际.研究表明,地下水化学特征时空演化研究可为地下水污染的防治、生态环境的改善提供重要依据.     

石化企业燃煤电厂二氧化硫控制对策研究

通过对国内外燃煤电厂二氧化硫控制现状、政策及技术的对比分析，提出了石化企业燃煤电厂二氧化硫控制的战略性对策。     

中国“十一五”石化行业发展规划的环境制约因素及规划环评应起的作用

结合目前中国石化行业发展存在的问题,通过对中国"十一五"石化行业发展规划分析后可知,规划的实施将受到资源短缺、环境恶化、人居安全等环境因素的制约,为实现可持续发展,应全面规划环评,最终实现和谐社会的目标。     

我国石化企业建立环境管理体系的意义及建议

介绍了ＩＳＯ１４０００环境管理体系的内容。通过分析我国石化企业的现状和建立ＩＳＯ１４０００环境管理体系的意义，提出了建立ＩＳＯ１４０００环境管理体系是提高企业管理水平的有效途径的观点。最后，探讨了现阶段石化企业建立ＩＳＯ１４０００环境管理体系的步骤。     

Identification of managerial shaping factors in a petrochemical plant by resilience engineering and data envelopment analysis

Resilience engineering (RE) is a novel approach that is capable of controlling and limiting incidents and accidents. This study identifies managerial shaping factors in a petrochemical plant by RE and data envelopment analysis (DEA). To do this, a standard questionnaire containing resilient factors is completed by managers of a petrochemical plant. Then, the best DEA model is selected based on average efficiency and statistical test. In addition, sensitivity analysis are performed to identify the most important shaping factors. Reporting culture, management commitment, and preparedness are identified as the most important factors in this paper, respectively. Finally, the proposed model is validated and verified through statistical experiment. The proposed approach would help managers to have a comprehensive understanding of the plant with respect to the RE. To the best of our knowledge this is the first paper that examines resilient shaping factors in a petrochemical plant with respect to management and organization by DEA.     

吉林省“十三五”期间污染物减排对策及建议

通过分析吉林省"十二五"期间总量减排取得的成效及存在的问题,提出吉林省"十三五"污染物总量控制政策及对策措施。此项研究是吉林省"十三五"规划前期研究的重要内容,对于吉林省今后的环境管理和总量控制规划的工作思路、发展方向的调整和转变,提高总量控制规划的可操作水平,促进新时期全省环境保护工作的开展方面都有借鉴意义。     

Biodegradation of pentyl amine and aniline from petrochemical wastewater

The objectives of the project were to isolate a bacterial strain capable of degrading pentyl amine and aniline and to define the optimal pentyl amine and aniline degradation conditions for this bacterial strain. The bacterial strain was isolated from activated sludge obtained from a Northeastern China treatment facility for petrochemical wastewater rich in pentyl amine and aniline. Once the strain was isolated, five triplicate (5) batch tests were used to establish the conditions for maximum pentyl amine and aniline degradation, by varying one at a time the following five factors: temperature, pH, reaction time, pollutant concentrations and aeration rate. In a final test, oil refinery sludge was inoculated with the strain and tested for the degradation of pentyl amine and aniline under optimal conditions, while observing the degradation pathway of pentyl amine and aniline. The isolated strain, PN1001, is a member of the Pseudomonas species and it was capable of degrading pentyl amine and aniline. The optimal reactor conditions for the degradation of a mixture of pentyl amine and aniline, at a concentration ranging between 150 and 200mg/L, were found to be 30 degrees C at a pH of 7.0, under a reaction time of 24h and a maximum solution dissolved oxygen level of 6 mgO(2)/L. Under such conditions, the strain PN1001 degraded 93% and 89% of the pentyl amine and aniline, respectively, aniline being more toxic and demonstrating a more complex degradation pathway. The strain PN1001 degraded more contaminants when both were present because of the pi and sigma electron cloud coordination functions of aniline and pentyl amine, respectively, presumed to reduce the toxic effect of aniline. Once inoculated with the strain, oil refinery sludge degraded 93% and 88% of the pentyl amine and aniline, compared to the strain alone which degraded 72% and 82%, likely because of the sludge's buffering effect against the toxic environment.     

我国企业信息化建设中的三类角色

本文着重阐述了我国企业信息化建设中的三类角色，它们分别是企业、管理咨询公司和信息化产品开发商。企业信息化是企业、管理咨询公司、信息化产品开发商三方参与，并且互相影响、互相制约、互相促进的全员工程，缺少了三类角色中的任何一方，企业信息化的项目就无法顺利的进行下去。如何处理三者之间的关系，更显得尤为重要。     

Comparative lifecycle greenhouse gas emissions and their reduction potential for typical petrochemical enterprises in China

Petrochemical enterprises have become a major source of global greenhouse gas (GHG) emissions. Yet, due to the unavailability of basic data, there is still a lack of case studies to quantify GHG emissions and provide petrochemical enterprises with guidelines for implementing energy conservation and emission reduction strategies. Therefore, this study conducted a life cycle assessment (LCA) analysis to estimate the GHG emissions of four typical petrochemical enterprises in China, using first-hand data, to determine possible emission reduction measures. The analytical data revealed that Dushanzi Petrochemical (DSP) has the highest GHG emission intensity (1.17 tons CO₂e/ton), followed by Urumqi Petrochemical (UP) (1.08 tons CO₂e/ton), Dalian Petrochemical (DLP) (average 0.58 tons CO₂e/ton) and Karamay Petrochemical (KP) (average 0.50 tons CO₂e/ton) over the whole life cycle. At the same time, GHG emissions during fossil fuel combustion were the largest contributor to the whole life cycle, accounting for about 77.31%–94.27% of the total emissions. In the fossil-fuel combustion phase, DSP had the highest unit GHG emissions (1.20 tons CO₂e), followed by UP (0.89 tons CO₂e). In the industrial production phase, DLP had the highest unit GHG emissions (average 0.13 tons CO₂e/ton), followed by UP (0.10 tons CO₂e/ton). During the torch burning phase, torch burning under accident conditions was the main source of GHG emissions. It is worth noting that the CO₂ recovery stage has "negative value," indicating that it will bring some environmental benefits. Further scenario analysis shows that effective policies and advanced technologies can further reduce GHG emissions.