员工行为安全管理系统的初步构建

现有的企业安全管理主要依靠管理人员监督管理,对员工行为的规范化管理效果有限。针对常见的员工不安全行为,提出建立员工行为安全管理系统促使员工行为规范化,并将其分为4个部分:违规提示系统,危险警报系统,辅助提示系统,紧急制动系统,辅以"自我观察法"作为配套管理措施,将员工意识由"要我安全"向"我要安全"转变,以期能够减少由不安全行为引发的事故,促进企业安全文化的逐步形成。     

燃煤飞灰中汞在渗滤过程中的迁移规律研究

燃煤飞灰在堆放、填埋过程中,固定于灰中的汞可能被再次释放,而带来二次污染。为研究飞灰中汞对环境的影响,本研究参照国标规定的渗滤方法和美国毒性特征浸出程序,对飞灰中汞的渗滤特性进行研究,即研究不同类型酸浸取液、浸取液pH值以及液固比对汞渗滤特性的影响。不同酸的浸取试验结果表明：硝酸的汞渗出浓度最大,硫酸最小,经化学动力学分析是由于不同类型酸对于玻璃体中各种氧化物溶解能力的差异性所致。采用硫酸渗滤时,出现反常的渗滤特征,并发现该现象与飞灰二次相生成物有关。滤液汞浓度随浸取液pH的增大成指数曲线下降趋势;随液固比增加,滤液汞浓度呈单峰分布,经化学动力学分析表明氢离子与硅铝玻璃体的配比是产生这一现象的主要原因;本研究对于燃煤汞污染的深度控制及治理方面有指导意义。     

Assessing determinants of industrial waste reuse: The case of coal ash in the United States

Devising effective strategies to facilitate waste reuse depends on the solid understanding of reuse behaviors. However, previous studies of reuse behavior have been limited in scope, focusing mostly on household recycling behaviors or very limited types of industrial wastes. To gain a better understanding of the business reuse behaviors, this study examined the impact of various factors in technical, economic, regulatory, and behavioral categories in the case of coal ash generated in the United States. The results of fixed effect models for fly ash and bottom ash particularly showed the significance role of the behavioral factor. In both models, a proxy variable, which represents knowledge sharing among the power plants or the utility's decision-making, turned out to be statistically significant and had the largest coefficient estimates among a group of variables. This finding may imply that the characteristics of waste reuse behavior are determined more by business decision-making behaviors than by market or institutional factors. However, the role of the behavioral variable was stronger in the bottom ash models than in the fly ash models. While the reuse of bottom ash was determined primarily by the behavioral variable, fly ash reuse was determined by more diverse factors including economic and regulatory variables. This could be explained by material characteristics in relation to competing resources and the nature of reuse applications.     

企业环境行为管理研究——以H省为例

有效防治工业污染、改善环境是工业企业的基本责任。以能够反映企业环境行为的信息为基础,通过建立科学的百分制量化评价体系,对H省具有代表性和典型性的重点排污工业企业的环境守法行为、企业污染控制行为、环境信息公开行为等环境行为进行评价。分析结果表明,该省企业环境行为有较大提升空间,重污染行业形势令人担忧,由此明确企业改善环境行为的关键因素和影响机制,并从企业、政府、社会三个角度提出措施改善企业环境行为的建议。     

Current status and perspectives of accelerated carbonation processes on municipal waste combustion residues

The increasing volumes of municipal solid waste produced worldwide are encouraging the development of processes to reduce the environmental impact of this waste stream. Combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash, and fly ash/APC residues. The disposal or reuse of these residues is however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation has been shown to have a potential for improving the chemical stability and leaching behaviour of both bottom ash and fly ash/APC residues. However, the efficacy of carbonation depends on whether the method of gas application is direct or indirect. Also important are the mineralogy, chemistry and physical properties of the fresh ash, the carbonation reaction conditions such as temperature, contact time, CO₂ partial pressure and relative humidity. This paper reviews the main issues pertaining to the application of accelerated carbonation to municipal waste combustion residues to elucidate the potential benefits on the stabilization of such residues and for reducing CO₂ emissions. In particular, the modification of ash properties that occur upon carbonation and the CO₂ sequestration potential possible under different conditions are discussed. Although accelerated carbonation is a developing technology, it could be introduced in new incinerator facilities as a “finishing step” for both ash treatment and reduction of CO₂ emissions.     

基于人工社会模型的退田还湖生态补偿机制实例研究

基于补偿者和受偿者意愿的研究方法是建立切实可行的生态补偿机制的有效手段。为探讨在我国许多地区开展退田还湖生态补偿政策的有效实施机制,减少洪涝灾害与生态环境退化负面效应,研究构建了基于农户、政府和企业三类主体及其相互作用的生态补偿模型,并重点分析生态补偿标准、洪灾风险、生态环境保护、劳动力本地转移政策等因素对农户主体土地利用决策的影响。以鄱阳湖区莲湖乡为实例,以农户和企业从事生产活动的行为特征和政府宏观调控方式为基本准则,利用构建的多主体模型模拟了不同补偿机制下退田还湖政策可能产生的土地利用长期效应。结果表明,政府给予农户的经济补偿可以使农户自愿实施退田,但在不同情景下,政府实施退田还湖的代价和达到预期目标的时限差距显著。企业参与不仅能减轻政府的经济负担,同时也有利于剩余农村劳动力的转移。政府发展壮大当地经济,提高农业劳动力向非农产业转移的速度和质量,均有助于推进退田还湖政策的有效实施。     

Evaluation of leaching characteristic and kinetic study of lithium from lithium aluminum silicate glass-ceramics by NaOH

The behavior and mechanism of Li leaching from lithium aluminum silicate glass-ceramics which can be used as a secondary source of Li using aqueous NaOH solution was investigated. The Li leaching efficiency is increased with increasing concentration of NaOH, specific surface area, and reaction temperature. When leached under optimum conditions, 2 mol/L NaOH, 53 μm particle undersize, 1:10 solid/liquid ratio, 250 r/min stirring speed, 100°C reaction temperature, 12 hr, the Li leaching efficiency was approximately 70%. However, when the leaching experiment was performed for 48 hr, the concentration of Li⁺ ions contained in the leach liquor decreased from 1160 to 236 mg/L. To investigate the origin of this phenomenon, the obtained leach residue was analyzed by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. These analyses show that zeolite was formed around the lithium aluminum silicate glass-ceramics, which affected the leaching of by adsorbing Li⁺ ions. In addition, using the shrinking-core model and the Arrhenius equation, the leaching reaction with NaOH was found to depends on the chemical reaction of the two reactants, with a higher than 41.84 kJ/mol of the activation energy.     

对固体废物中挥发性有机物浸出方法的几点实验探讨

采用零顶空提取器,对陈旧油墨渣和蒽琨渣样品中的挥发性有机物进行了浸出实验和分析测定,浸出液采用静态顶空分流进样、GC/MS法分析。对影响挥发性有机物浸出效率的因素进行了研究,结果表明,浸提剂加入方式、浸出时间和浸出液收集方法等对分析结果准确度有较大影响。