清洁的胡椒基T醚生产工艺的研究I,5-丙基-1,3-苯并二氧杂茂的氯甲基化废水的处理

报道了胡椒基丁醚生产中５－丙基－１，３－苯并二氧杂茂的氯甲基化的废水处理，该废水经蒸馏可回收９４％的盐酸，此酸吸收氯化氢后浓度在３６％以上，可再用于氯甲基化反应。蒸馏残液经分油、Ｆｅｎｔｏｎ试剂处理和五次生炭柱吸附后ＣＯＤＣｒ等项指标均可国家二类污染物的一级排放标准。     

几种重金属对紫背萍过氧化氢酶活性的影响

通过测定被暴露植物分解过氧化氢后放出氧气的体积，确定紫背萍过氧化氢酶（ＣＡＴ）的活性。结果表明，紫背萍暴露在Ｈｇ、Ｐｂ、Ｃｒ、Ｎｉ、Ｆｅ的溶液中，其ＣＡＴ活性除在Ｐｂ作用下明显降低外，在其它４种重金属的作用下都有不同程度的升高。这表明Ｐｂ对紫背萍 ＣＡＴ活性有抑制作用，而其它４种重金属对紫背萍ＣＡＴ均有刺激作用。紫背萍对５种重金属所表现出来的这种生态效应，是重金属水污染的植物潜在效应，植物的ＣＡＴ     

县级生态农业建设的人工神经网络模型

引入人工神经网络的评价识别方法，建立了ＢＰ模型，以前人建立的县级生态农业建设评价指标体系评价标准，和某县生态农业综合评价指标数据为实例，比较ＢＰ模型的有效性，得到的评价分类结果和指标优先发展顺序决策与实际情况相吻合。     

First-trimester prenatal diagnosis of aspartylglucosaminuria

Fetal aspartylglucosaminuria (AGU) was studied during the first trimester of pregnancy in six at-risk pregnancies using chorionic villus samples. The activity of aspartylglucosaminidase (AGA) was high in five cases, indicating an unaffected fetus. This was confirmed through delivery of healthy newborns with a normal pattern of urinary oligosaccharides. Low enzyme activity in an uncultured biopsy specimen and in cultured amniotic fluid cells in one case demonstrated that the fetus was affected. The pregnancy was terminated and the prenatal diagnosis was confirmed by showing reduced AGA activity in cultured fibroblasts of the fetus.     

Mn-Cu-O负载型催化剂上CO氧化性能的研究

研究了ＺｒＯ２或Ａｌ２Ｏ３负载Ｍｎ－Ｃｕ－Ｏ体系催化剂ＣＯ催化氧化活性，以及物相结构，表面氧性能与活性的关系。结果表明，锆基催化剂的氧化活性明显优于铝基催化剂，起燃温度Ｔ５０低达５０℃，ＺｒＯ２载 利于活性组份形成高活性物相，并促进表面吸附氧的脱附，表现出催化剂表面吸附氧的脱附温度高低次序与其氧化活性有一致的对应关系。     

改进灰色系统模型在城市噪声预测中的应用

把城市噪声作为一个灰色系统,分别通过GM(1,1)模型和改进灰色系统模型GM'(1,1),对城市噪声进行预测,并进行精度检验.改进的灰色系统模型GM'(1,1)在精度上均优于GM(1,1)模型,但是GM'(1,1)在计算上比较复杂,需要通过计算机迭代来实现.     

固相微萃取-毛细管气相色谱法测定水中有机污染物

固相微萃取是一种快速、简便、集萃取浓缩于一体的样品前处理技术,具有分析快速、灵敏度高、无需有机溶剂的优点。用固相微萃取-毛细管气相色谱分析水中甲醇、丙酮、异丙醇、乙醇、乙腈、丙烯腈,检出限可达0.003～0.03mg/L。     

Spatial variations in daily average CO2 concentrations above wetland surface of Xianghai National Nature Reserve, China

Horizontal and vertical variations of daily average CO2 concentration above the wetland surface were studied in Xianghai National Nature Reserve of China in August, 2000. The primary purpose was to study spatial distribution characteristics of CO2 concentration on the four levels of height(0.1 m, 0.6 m, 1.2 m and 2 m) and compare the differences of CO2 concentration under different land covers. Results showed that daily average CO2 concentration above wetland surface in Xianghai National Natural Reserve was lower than that above other wetlands in northeast China as well as the worldwide average, suggesting that Xianghai wetland absorbed CO2 in August and acted as“sink” of CO2. The horizontal variations on the four levels of height along the latitude were distinct, and had the changing tendency of“decreasing after increasing” with the increase of height. The areas with obvious variations were consistent on different levels of height,and those with the highest variations appeared above surface of shore, sloping field, Typha wetland and Phragmites wetland; the vertical variations were greatly different, with the higher variations in Phragmites wetland and Typha wetland, and the lands near the shore and the sloping field with the lower variations. Spatial variations of daily average CO2 concentrations above wet!and surface were affected by surface qualities and land covers.     

SiO_2-TiO_2纳米管的制备及其光催化性能的研究

文章采用水热法制备SiO2-TiO2纳米管,通过扫描电镜(SEM)和透射电镜(TEM)考察了该纳米管的结构形态,并用X-射线衍射考察其晶体结构。实验结果表明所制得的纳米管是锐钛晶型,其两端开口,具有多层管壁;管径为8nm左右,管壁厚1～2nm。光催化降解酸性橙Ⅱ实验表明:SiO2-TiO2纳米管光催化速率比TiO2纳米管高出10%。这可能是因为Si元素的存在增大了钛纳米管的比表面积,同时SiO2的存在能降低光生电子和空穴的复合率。     

石油化工厂区土壤中总石油烃分布的研究

为了进行石油化工厂区地下环境的现场评估，利用气相色谱法（EPA8015B）对其土壤中总石油烃（TPHs)进行了测定，测定结果以柴油范围的有机物（DRO）和润滑油范围的有机物（ORO）表示。结果表明：土壤各层DRO检出率在58％－72％之间，ORO检出率在82％－89％之间，大多数检出点位的DRO、ORO含量小于500mg/kg；个别点位的DRO、ORO高达30000mg/kg。