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871.
吸附模式对有机物光催化降解的影响2.H-酸在TiO2表面的光催化降解途径 总被引:3,自引:1,他引:2
水溶液中H-酸通过磺酸基团吸附在TiO2表面,UV照射TiO2所产生的自由基首先进攻吸附在TiO2表面的磺酸基团,从而进一步导致萘环开环.pH 2.5条件下,虽然饱和吸附量较大,但由于H-酸仅通过一个磺酸基团吸附在TiO2表面,过程中产生的硫酸根速率较慢,最终的光降解速率也较慢.pH 5.0条件下,虽然饱和吸附量较小,但由于吸附在TiO2表面的两个磺酸基团同时受到来自TiO2表面自由基的进攻,过程中产生的硫酸根速率较快,最终的光降解速率也较快.吸附模式的差异是导致H-酸在不同pH值条件下光催化降解途径和速率差异的关键因素. 相似文献
872.
873.
874.
The potential of cost-effective coconut husk for the removal of toxic metal ions for environmental protection 总被引:2,自引:0,他引:2
Coconut (Cocos nucifera) husk, an agricultural waste, has been thoroughly investigated for the removal of toxic Cd(II), Cr(III) and Hg(II) ions from aqueous media. The parameters like nature and composition of electrolyte, concentration of toxic ions, dosage of coconut husk, and equilibration time between the two phases were optimized for their maximum accumulation onto the solid surface. The effect of common ions on the uptake of metal ions has been monitored under optimal conditions. The variation of retention of each metal ion with temperature was used to compute the thermodynamic quantities DeltaH, DeltaS and DeltaG. The values 18.1+/-0.6 kJmol(-1), 74+/-2 Jmol(-1)K(-1), and -3.8+/-0.04 kJmol(-1) at 298 K; 10.8+/-0.8 kJmol(-1), 48.8+/-2.7 Jmol(-1)K(-1), and -4.6+/-0.3 kJmol(-1) at 298 K; and -37.4+/-2k Jmol(-1), 105+/-7 Jmol(-1)K(-1) and -2.58+/-0.5 kJmol(-1) at 298 K were obtained for Cd(II), Cr(III) and Hg(II) ions, respectively. The sorption data were analysed by applying different sorption isotherms. The sorption capacity and energy were evaluated for each metal ion. The values of the Freundlich constants 1/n and C(m) were 0.92+/-0.04 and 52.6+/-22.2 mmolg(-1); 0.85+/-0.05 and 56.0+/-0.03 mmolg(-1); and 0.88+/-0.03 and 6.84+/-0.45 mmolg(-1) for Cd(II) Cr(III) and Hg(II) ions, respectively. Similarly, the Dubinin-Radushkevich (D-R) constants beta, X(m,) and E were evaluated for the three metal ions. To check the selectivity of the sorbent, sorption of a number of elements was measured under similar conditions. Separation of Zn(II) from Cd(II); Cr(III) from I(I), Zr(IV), Se(IV), and Hg(II) from Se(IV) and Zn(II) can be achieved using this sorbent. This cheap material has potential applications in analytical chemistry, water decontamination, industrial effluent treatment and in pollution abatement. 相似文献
875.
The growth properties and biodegradation mechanism of a Gram-negative bacterium, Pseudomonas nitroreducens TX1 that was able to grow on branched octylphenol polyethoxylates (OPEO(n), average n=9.5) as the sole carbon source over a wide concentration range (1-100,000 mgl(-1)) were studied. Analysis of growth factors indicated the highest specific growth rate (micro) of 0.53 h(-1) was obtained at an initial concentration of 5,000 mgl(-1) OPEO(n). An optimal C/N ratio of 12 was obtained for (NH(4))(2)SO(4) as the nitrogen source in a cultivated medium at pH 7. The kinetic analysis demonstrated that bacterial growth and OPEO(n) degradation followed the Monod equation and were based on a substrate concentration inhibition model and pseudo-first-order reaction, respectively. The substrate inhibition coefficient was over 18,000 mgl(-1) and this indicates that the strain has an ability to sustain growth at high concentrations of OPEO(n) and use it as the sole carbon source under such a stress condition. Furthermore, LC-MS analysis showed that the biodegradation mechanism of dodecyl octaethoxylate (AEO8) by P. nitroreducens TX1 was the sequential cleavage of the ethoxylate chain. 相似文献
876.
Sustainable use of water and land resources requires that these scarce resources be appropriately allocated among various
competing human activities. Worldwide, there is a realization now that sustainable river basin management should be accorded
the highest priority, because it deals not only with technical, but also with ecological and socioeconomic aspects, and thus
calls for a multidisciplinary and integrated approach. However, most of the policy and planning documents have either remained
silent, or have made only implicit reference to the importance of environmental water demand (EWD) and its quantification.
Therefore, in the light of its importance, a methodology has been evolved in this article for quantifying EWD for various
forested areas in two distinctly different Indian river basins: Brahmani (humid zone) and Sabarmati (dry zone). The article
analyzes and discusses EWD estimates at three different spatial levels: river basins, states, and districts within them, and
finally presents a comparative analysis of all these results. Findings of the present study will be immensely useful in understanding
various ecological issues connected with water resource projects and proposals in these river basins. 相似文献
877.
Geographical areas constitute the basic implementation locus for integrated coastal zone management strategies and activities.
Because the definition of territorial planning objectives may be affected by socioeconomic and environmental characteristics,
one of the main steps in the process involves dividing the coast into homogeneous environmental management units (HEMUs).
This article presents a general and simple method for regionalizing the landside of a coastal zone into HEMUs and illustrates
it through application to the Catalan coast. Socioeconomic and natural (biophysical) subsystems were selected as the most
appropriate dimensions of the regionalization process. Dimensions were described using 11 spatial themes, which were managed
in a geographic information system environment that proved to be an adequate tool for the purpose. A final coastal zone map
of four classes of HEMUs connected to local administrative units was obtained, and because it reflects the current natural
and socioeconomic dynamics, it can be considered as an initial step in the planning process for the Catalan coast. Although
the proposed method was developed based on the characteristics of the Catalan coast, it is general enough to be adapted and
applied to most developed or developing coastal areas. 相似文献
878.
大气CO2浓度不断增加将以两种方式影响作物的代谢、生长发育和产量的形成:一是通过温室效应“加热”气候,改变降水类型,进而影响作物;二是浓度变化本身对作物生理过程的影响。介绍了国内外近年来在与CO2浓度有关的作物生理实验方面取得的进展及其主要结果。 相似文献
879.
Management by objectives (MBO) is a technique for integrating ecological concerns into national political and administrative
structures. Politicians determine environmental objectives and interim targets to be implemented and assessed by civil servants
in national, regional, and local contexts. Well-developed organizational communication is a prerequisite for MBO. However,
communication-related obstacles can arise when using MBO in public environmental management. We examine communicative aspects
of environmental MBO, looking specifically at the implementation, administration, and assessment of Swedish environmental
quality objectives. Our argument is illustrated by quotations from individual and focus group interviews. We conclude that
communicative problems may arise, because different actors interpret messages from different perspectives, depending on their
agendas, prior knowledge and experience, and positions in the administrative system. It is crucial to recognize the dialogical
aspects of communication, by involving the receiver of a message in a process of response. In addition, the different timeframes
underlying different arguments could contribute to misunderstandings between actors involved in handling environmental issues.
In assessing the achievement of environmental objectives, indicators are used as communicative tools. It is important to investigate
whether and how these indicators contribute to the de- and recontextualization of environmental objectives. 相似文献
880.
清洁生产是工业生产追求的最高境界,而结构调整阶段给企业提供了一个很好的实施清洁生产的契机,使企业可以借助结构调整机会,将清洁生产渗透至企业的所有方面,最大限度地取得清洁生产的效果。 相似文献