全文获取类型
收费全文 | 5131篇 |
免费 | 869篇 |
国内免费 | 2728篇 |
专业分类
安全科学 | 395篇 |
废物处理 | 242篇 |
环保管理 | 400篇 |
综合类 | 4479篇 |
基础理论 | 1674篇 |
环境理论 | 1篇 |
污染及防治 | 1112篇 |
评价与监测 | 281篇 |
社会与环境 | 109篇 |
灾害及防治 | 35篇 |
出版年
2024年 | 9篇 |
2023年 | 101篇 |
2022年 | 182篇 |
2021年 | 246篇 |
2020年 | 194篇 |
2019年 | 261篇 |
2018年 | 317篇 |
2017年 | 300篇 |
2016年 | 360篇 |
2015年 | 401篇 |
2014年 | 467篇 |
2013年 | 546篇 |
2012年 | 592篇 |
2011年 | 600篇 |
2010年 | 474篇 |
2009年 | 536篇 |
2008年 | 361篇 |
2007年 | 378篇 |
2006年 | 415篇 |
2005年 | 307篇 |
2004年 | 240篇 |
2003年 | 240篇 |
2002年 | 193篇 |
2001年 | 174篇 |
2000年 | 154篇 |
1999年 | 122篇 |
1998年 | 92篇 |
1997年 | 82篇 |
1996年 | 84篇 |
1995年 | 75篇 |
1994年 | 47篇 |
1993年 | 44篇 |
1992年 | 40篇 |
1991年 | 25篇 |
1990年 | 15篇 |
1989年 | 9篇 |
1988年 | 10篇 |
1987年 | 8篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有8728条查询结果,搜索用时 734 毫秒
911.
用批量平衡法研究了单甲脒农药在三种水体悬浮颗粒物上的吸附规律,所得数据进行回分析后,发现吸附规律符合Freundilich方程,并且在悬浮颗粒物上的吸附能力随着颗粒物中有机碳含量的增加而稍有减少。 相似文献
912.
采用气相色谱/傅立叶红外光谱和气相色谱/质谱仪分析大鼠肝脏中单甲脒的代谢产物,证明大鼠经口摄入单甲脒后,在肝脏中迅速代谢,其代谢中间产物为2,4-二甲基苯胺和含酰胺基的化全物。 相似文献
913.
Summary 2-methyl-1,4-benzoquinone as a target compound of the tergal gland secretion of the rove beetle,Aleochara curtula, was quantified from the reservoirs of individual beetles. Males store less secretion than females, and they evaporate more of the secretion as measured by adsorption from the air (closed-loop-stripping-analysis). The amount of emitted quinone is increased during aggressive interactions of rival males. The pulsed emission of the secretion during aggression is demonstrated by a novel technique combining observation of behavior with the on-line measurement of target fragment ions by mass-spectrometry (tandem bioassay — mass fragmentography). The emission of the secretion is used as a weapon in combats between males and may result in the repulsion of subordinate males from the mating site, but may also serve to mimic females chemically in order to avoid aggressive encounters. 相似文献
914.
拟面积多波长数据线性双组合解析萘,1—萘酚和2—萘酚同步荧光光谱的研究 总被引:2,自引:0,他引:2
本文研究了Δλ(λem-λex)为130nm和PH12.0条件下,萘、1-萘粉和2-萘酚混合物的同步荧光光谱,获三者同步荧光峰信息,且萘被完全分辨,另外,提出用拟面积多波长线性双组合计算解析重叠的1-萘酚和2-萘酚同步荧光光谱,解析结果的精密度、组份间浓度比范围均较多波长线性回归、双峰增配平和一阶导数解析混合物同步荧光光谱结果为优。 相似文献
915.
二氧化硫与1—己烯的光化学反应动力学 总被引:1,自引:0,他引:1
利用GC/MS方法研究了SO2与1-己烯在无氧和有氧体系中光化学反应动力学,确定了SO2与1-己烯光化学反应的级数,给出了293-333K温度范围内总的反应速度常数K,以及K与温度的关系、反应的活化能和指前因子。另外,对反应物己醛和2-己酮的生成反应速度常数及其活化能也进行了计算和讨论。 相似文献
916.
本文以煤气化工程的典型实例分析为基础,通过对气源厂经济效益的分析,提出了以气化替煤量和节煤量两项指标,进行宏观经济效益、社会效益和环境效益的综合效益分析的步骤及相应的计算公式与方法。 相似文献
917.
室内采用离体叶片法研究了转sck单价基因抗虫水稻86AS1和转cry1Ac/sck双价基因抗虫水稻MSB不同生育期主茎顶叶对二化螟幼虫的杀虫效果.结果发现,不同生育期的MSB对二化螟初孵幼虫表现出了很强的毒杀效果,二化螟幼虫校正死亡率在扬花期前均达到90%以上;扬花期和灌浆期抗虫性有所下降,校正死亡率高于80%;成熟期校正死亡率在60%以上.在整个生育期,二化螟幼虫取食86AS1主茎顶叶的校正死亡率均未超过50%.MSB对二化螟幼虫的毒杀效果明显高于86AS1.采用透射电镜观察二化螟幼虫取食转cry1Ac/sck双价基因抗虫水稻和转sck单价基因抗虫水稻主茎顶叶后中肠组织的病理变化.结果发现,两种转基因水稻都能够引起二化螟幼虫中肠组织发生病理变化,但病变程度有明显差异.二化螟幼虫取食转cry1Ac/sck双价基因抗虫水稻3d,中肠组织受到严重破坏且病理变化明显;取食转sck单价基因抗虫水稻3d,幼虫中肠组织的病理变化却较缓慢.图2参10 相似文献
918.
A review of the chemical ecology of the Cerambycidae (Coleoptera) 总被引:15,自引:0,他引:15
Summary. This review summarizes the literature related to
the chemical ecology of the Cerambycidae and provides a
brief overview of cerambycid biology, ecology, economic
significance, and management. Beetles in the family
Cerambycidae have assumed increasing prominence as pests
of forest and shade trees, shrubs, and raw wood products, and
as vectors of tree diseases. Exotic species associated with
solid wood packing materials have been notable tree killers
in North American urban and peri-urban forests. In forested
ecosystems native species respond to disturbances such as
fires and windstorms, and initiate the biodeterioration of
woody tissue. Eggs are laid by females, on or through the
bark surface of stem and branch tissue of moribund, recently
killed or decomposing woody plants; larval cerambycids
(roundheaded woodborers) typically feed in the phloem and
later in the xylem. Females will also, in some cases, select
living hosts, e.g. adult conifer and angiosperm trees, for
oviposition. Research on the chemical ecology of over 70
species has revealed many examples of attractive kairomones
(such as floral volatiles, smoke volatiles, trunk and leaf
volatiles, and bark beetle pheromones), repellents and
deterrents, oviposition stimulants, short- and long-range sex
pheromones, and defensive substances. Emerging generalities
are that attractants tend to be monoterpenoids and phenolic
esters; oviposition stimulants are monoterpenoids and
flavanoids; short-range sex pheromones are female-produced,
methyl-branched cuticular hydrocarbons; and
long-range sex pheromones are male-produced -hydroxy
ketones and (,)-diols ranging in length from 6 to 10 carbons.
The latter compounds appear to originate from glands
in the male thorax; putative defensive substances originate
from metasternal secretory pores or mandibular glands. In
one unusual case, a flightless, subterranean female that
attacks sugar cane produces a sex pheromone that is derived
from the amino acid isoleucine. With significantly more than
35,000 species of Cerambycidae worldwide, these generalities
will be subject to change as more species are examined.
Addendum
The authors would like to point out that the electronic version
is more accurate than the printed version. 相似文献
919.
分别研究了纳米TiO2 在主波长为 364nm的汞灯光照下催化氧化i C3H7OH和CH3COCH3水溶液的反应速率 .通过XRD ,TEM ,BET和FT IR PAS对催化剂进行表征 ,粉末的晶型主要为锐钛矿型 .平均粒径在 1 5nm左右 ,比表面积为 1 0 1 0± 0 2m2 ·g- 1 ,FT IR PAS的检测结果表明 ,CH3COCH3是i C3H7OH光催化氧化的中间产物 ,其光催化氧化反应为 :i C3H7OH [O]CH3COCH3[O]CH3COOH[O]…[O]CO2 H2 O 相似文献
920.
Adsorption of hydrophobic contaminants at the particle/water interface is one of the key processes controlling their fate in the aquatic environment. The sorption of the natural female hormones oestrone and 17-oestradiol has been studied under simulated riverine conditions. Both the kinetics and the effects of varying fundamental environmental parameters (e.g. sediment properties) on the thermodynamic equilibrium partition coefficient (K
p) have been studied in continuous and batch sorption experiments, respectively. Results showed that the sorption of oestrone and 17-oestradiol by sediment was relatively slow, reaching equilibrium in 50 days. In addition, relatively small adsorption of both oestrone and 17-oestradiol onto the sediment was observed, with K
p values between 200 and 250 mL g–1. The comparable K
p values of the two compounds reflect their structural similarity. It can be concluded that the two endocrine disruptors, oestrone and 17-oestradiol remain primarily in association with the aqueous phase. 相似文献