农村水污染治理驱动因素的利益相关者识别

引入利益相关者理论对我国农村水污染治理减低污染风险的驱动因素进行了识别。通过对农村水污染系统内的利益相关者进行界定,划分了政府、农村社区居民和社会力量3个利益群体,并通过Binary Logistic回归模型对3个利益群体的驱动力进行量化分析,经实证模型检验表明,反映政府作用的考核机制(含财政投入与监管能力)、反映社会力量的社会资金投入以及反映农村社区作用的自主管理能力和居民环保投入所占比重的发生比(OR值)分别为2.248、1.725、1.525和1.236,表明政府主导对减轻农村水污染起关键作用,社会力量和农民社区自身多方发挥作用对降低农村水污染风险的影响也是显著的。     

深水悬臂桥墩动力特性及地震响应分析

利用ADINA中的势流体单元对一已建成的深水高墩建模,桥梁上部结构对桥墩的影响以墩顶集中质量的形式体现,分别对不同水深条件下桥墩-水体系的动力特性和地震动响应进行了系统的求解;为了检验Morison方程在深水桥墩动力分析中的有效性,将基于忽略速度力项的Morison方程的计算结果与基于势流体的结果进行了比较.研究结果表...     

共代谢基质对芽孢杆菌Y-4降解异喹啉的影响

以吡啶,葡萄糖和邻苯二甲酸作为共代谢基质,研究了它们对芽孢杆菌Y_4降解异喹啉的影响。实验结果表明各降解过程均遵循二级反应动力学方程：-dS／dt=K2S2＋K1S＋K0。吡啶的加入会抑制异喹啉的降解,并且吡啶的浓度越高,抑制作用越明显。反应体系中葡萄糖的浓度为100-800mg／L时,葡萄糖的加入会促进异喹啉的降解,且葡萄糖浓度越大,异喹啉降解速率P越大,当葡萄糖的浓度为800mg／L时,其降解率速率P可由未加葡萄糖的0．1924h。上升为0．2255h-1。适宜浓度的邻苯二甲酸会对异喹啉的降解产生促进作用,邻苯二甲酸的浓度为50mg／L时,异喹啉的降解速率可由原来的0．1924h-1增加到0．2145h-1,邻苯二甲酸浓度过高反而会抑制异喹啉的降解。     

Thermodynamics and kinetics of cadmium adsorption onto oxidized granular activated carbon

Cadmium sorption behavior of granular activated carbon oxidized with nitric acid was systematically studied by sets of the equilibrium and time-based experiments under various conditions.The cadmium adsorption capacity of oxidized granular activated carbon enlarged with an increase in pH,and reduced with an increase in ionic strength.Experimental data were evaluated to find out kinetic characteristics.Adsorption processes were found to follow pseudo-second order rate equation.Adsorption isotherms correlate well with the Langmuir isotherm model and the maximum sorption capacity of cadmium evaluated is 51.02μmol/g.Thermodynamic parameters were calculated based on Van't Hoff equation.Equilibrium constant Kd was evaluated from Freundlich isotherm model constants,Langmnir isotherm model constants,and isotherms,respectively.The average change of standard adsorption heatΔH~0 was -25.29 kJ/mol.NegativeΔH~0 andΔG~0 values indicate the adsorption process for cadmium onto the studied activated carbon is exothermic and spontaneous.The standard entropyΔS~0 was also negative,which suggests a decrease in the freedom of the system.     

近海沉积物对粪固醇的等温吸附和热力学研究

采用大连湾近海表层沉积物为吸附剂,粪固醇为吸附质,通过批量平衡法,研究了近海沉积物对12种粪固醇的吸附行为.结果表明,12种粪固醇在24 h吸附达到平衡后,5种粪固醇的指纹值变化趋于稳定;用Henry、Freundlich、Langumir、Dubinin-Radushkevich(D-R模型)、Temkin这5种等温吸附模型来拟合,其中Langumir模型不适合拟合沉积物对粪固醇的吸附数据,其他4种模型均能较好地拟合.D-R模型拟合效果表明,12种粪固醇的吸附平均自由能在7 071.1～9 128.7 J.mol-1之间,12种粪固醇的吸附过程主要是物理吸附的作用.Temkin模型拟合效果表明,加氢胆固酮(Kf=8.89×106)的Kf值最大,说明沉积物吸附加氢胆固酮之间的作用最大,加氢胆固酮更容易被吸附.热力学参数吸附焓ΔH0<0,熵变ΔS0<0,ΔG0<0呈现出放热反应,自发过程的特征.     

APPLICATION OF THE GREEN-AMPT INFILTRATION EQUATION TO WATERSHED MODELING1

ABSTRACT: A computer model was developed, based on the Green-Ampt infiltration equation, to computed rainfall excess for a single precipitation event. The model requires an estimate of parameters related to hydraulic conductivity, wetting front section, and fillable porosity of the soil layers. Values of parameters were estimated from soil textural averages or regression equations based on percent sand, percent clay, and porosity. Average values of effective porosity and wetting front suction were largely acceptable due to the relatively low variability and low model sensitivity to the parameters. Hydraulic conductivity was the most erratic constituent of the loss rate computation due to the high variability and the high sensitivity of the computed infiltration to the parameter. The performance of the Green-Ampt infiltration model was tested through a comparison with the SCS curve number procedure. Seven watersheds and 23 storms with precipitation of one inch or greater were used in the comparison. For storms with less than one inch of rainfall excess, the SCS curve number procedure generally gave the best results; however, for six of the seven storms with precipitation excess greater than one inch, the Green-Ampt procedure delivered better results. In this comparison, both procedures used the same initial abstractions. The separation of rainfall losses into infiltration, interception, and surface retention is, in theory, an accurate method of estimating precipitation excess. In the second phase of the study using nine watersheds and 39 storms, interception and surface retention losses were computed by the Horton equations. Green-Ampt and interception parameters were estimated from value sin the literature, while the surface retention parameter was calibrated so that the computed runoff volumes matched observed volumes. A relationship was found between the surface retention storage capacity and the 15-day antecedent precipitation index, month of year, and precipitation amount.     

SYNERGETICS ANALYSIS OF ROCK MASS BASED ON ITS CHARACTERISTIC OF DISCONTINUATION

<正>Based on the noncontinuity of rock mass, views it as a system made of blocks that are divided by dissconti-nuties. Take the relative displacement of blocks as order parameter and establish its main equation using the micro-cosmic disposal method of synergetics. Then solve this equation and get its solution of nonstationary state. Narrate the characteristic of change and interrelated factors of blocks' displacement through the analysis of nonstationary state of main equation.     

上海市郊4种地表径流深度的测算

根据有关试验资料和美国土壤保持局推荐的方法，提出了上海市郊４种地表径流深度的计算公式。计算结果表明，当年降雨量为１０５３ｍｍ时，上海市郊４种地表径流的总量为１３．６亿ｍ＾３，平均径流深度为３００ｍｍ，径流系数为２８．４９％，４种径流量占郊区总量的７７．８２％，产流面积为郊区总面积的７５．１０％。     

利用多台首波Pn、直达波Pg走时确定地壳厚度及波速

本文通过对首波Pn、直达波Pg的走时的反演,推导出地壳厚度、震源深度、P波在地壳中、壳幔边界的传播速度之间的关系式,利用多台地震记录确定一个区域内这些参数的值,从而建立出该区域的地壳模型。     

Assessment of carbon leakage in multiple carbon-sink projects: a case study in Jambi Province,Indonesia

Rehabilitation of degraded forest land through implementation of carbon-sink projects can increase terrestrial carbon (C) stock. However, carbon emissions outside the project boundary, which is commonly referred to as leakage, may reduce or negate the sequestration benefits. This study assessed leakage from carbon-sink projects that could potentially be implemented in the study area comprised of 11 sub-districts in the Batanghari District, Jambi Province, Sumatra, Indonesia. The study estimates the probability of a given land use/cover being converted into other uses/cover, by applying a logit model. The predictor variables were: proximity to the center of the land use area, distance to transportation channel (road or river), area of agricultural land, unemployment (number of job seekers), job opportunities, population density and income. Leakage was estimated by analyzing with and without carbon-sink projects scenarios. Most of the predictors were estimated as being significant in their contribution to land use cover change. The results of the analysis show that leakage in the study area can be large enough to more than offset the project’s carbon sequestration benefits during the period 2002–2012. However, leakage results are very sensitive to changes of carbon density of the land uses in the study area. By reducing C-density of lowland and hill forest by about 10% for the baseline scenario, the leakage becomes positive. Further data collection and refinement is therefore required. Nevertheless, this study has demonstrated that regional analysis is a useful approach to assess leakage.