考虑流固耦合作用的深水桥墩地震响应分析

地震作用下,深水桥墩与周围水体的耦合振动是一个非常复杂的动力相互作用问题。本文基于非线性Mori-son方程,采用Airy波浪理论,建立了深水桥墩考虑流固耦合作用的有限元模型,应用Newmark-β法提出了求解该耦合非线性方程的算法,并用ANSYS软件和Matlab软件自编了求解程序。以某跨海大桥深水桥墩为算例,对其进行在地震作用下的非线性动力分析,并与已有计算方法进行对比。结果表明:按本文方法计算的墩顶最大位移、墩底最大剪力及墩底最大弯矩均较大,差异最大达到12.5%。因此在极端海况条件下,对深水桥墩进行地震作用下的动力分析时,建议采用本文考虑流固耦合的方法。     

模拟降雨条件下生物可利用磷在地表径流中的流失和预测

本文通过模拟降雨径流实验,运用两种生物可利用磷（ＢＡＰ）的化学浸提方法,在１．２ｍｍ．ｍｉｎ＾－１的大暴雨条件下,研究在施肥在未施肥两种情况下,ＢＡＰ的径流流失方式和过程,并建立模型ＢＡＰ的预测。结果表明,运用两种ＢＡＰ的化学浸提的结果差异性不显著（ｐ＝０．０５）,并具１：１的线性相关关系;ＢＡＰ的流失通过溶解态磷（ＤＰ）和颗粒态生物可利用磷（ＢＰＰ）两种形态方式,随着降雨径流时间的延长,累积的Ｂ     

南京北郊大气臭氧浓度变化特征

以南京北郊大气中O3质量浓度观测资料为基础,分析了O3变化特征和气象要素对其影响程度。结果表明：大气O3日均质量浓度平均为65.8μg·m-3。O3质量浓度最大值出现在午后15时左右,O3质量浓度日最大值在春季最大,而冬季最小。白天工作日O3质量浓度要高于周末,而夜间两者差异不大。气温,日照时数和降水量是影响南京大气O3质量浓度的重要因素。全年中5月份高日照时数和较低的降水量导致南京出现O3高值。在偏南气流作用下,O3质量浓度偏高。由气象要素得到的O3日均质量浓度和O3日最高质量浓度回归方程相关系数分别为0.61和0.71。     

An analytical model for the interpretation of pulse injection experiments performed for testing the spatial variability of clay formations

This paper presents an analytical model to describe pulse injection experiments. This model solves the advection-diffusion equation while taking into account back diffusion from the clay core to the inlet and from the outlet to the clay core. In most analytical models, back diffusion is neglected. For sufficiently high Péclet numbers, this is a good approximation. However, in experiments where the Péclet number is low, back diffusion is important and must be taken into account. An additional advantage of the present model is that both concentration and flux are conserved at the inlet and at the outlet of the clay core. This model is used to fit pulse injection experiments with iodide and tritiated water (HTO) in clay cores. The (new) model is required for fitting the experimental results since in clay layers advection is very slow leading to a low Péclet number. The experiments are performed on clay cores taken from different depths from the Boom Clay and the Ypres Clay layer under the site of the nuclear power plant of Doel (Belgium). The quality of all fits is excellent and the obtained parameter values are coherent. For HTO, the fitted value for the diffusion accessible porosity is consistent with measurements of the water content in Ypres Clay cores. In both types of clays, the apparent diffusion coefficient at zero flow is between 10(-10) and 2 x 10(-10) m(2)/s for iodide and between 2 x 10(-10) and 3 x 10(-10) m(2)/s for HTO. The dispersion length is in the order of 10(-3) m. The average value for the diffusion accessible porosity is between 0.35 and 0.4 for HTO and between 0.2 and 0.25 for iodide.     

济南市空气质量状况与气象条件关系分析

利用济南市空气污染指数资料和气象资料,分析空气质量状况与气象条件的关系规律,建立起空气污染指数与气象要素间的季节性回归方程,并筛选济南市近年来的空气质量重污染过程,分析污染过程时对应的天气形势特征,为济南市的空气污染指数预报和环境保护工作中的污染潜势预报提供参考。     

Remediation of sulfidic wastewater by catalytic oxidation with hydrogen peroxide

Oxidation of sulfide in aqueous solution by hydrogen peroxide was investigated in the presence of hydrated ferric oxide catalyst. The ferric oxide catalyst was synthesized by sol gel technique from ferric chloride and ammonia. The synthesized catalyst was characterized by Fourier transform infrared spectroscopy, X-Ray di raction analysis, scanning electrom microscope and energy dispersive X-ray analysis. The catalyst was quite e ective in oxidizing the sulfide by hydrogen peroxide. The e ects of sulfide concentration, catalyst loading, H2O2 dosing and temperature on the kinetics of sulfide oxidation were investigated. Kinetic equations and activation energies for the catalytic oxidation reaction were calculated based on the experimental results.     

Hg在玲珑金矿区典型农田土壤中的吸附特征研究

采集烟台玲珑金矿区不同性质的土壤,通过吸附解析实验研究了矿区2种典型农田土壤对重金属汞的吸附特征.等温吸附-解吸实验结果表明,酸性土壤对Hg（Ⅱ）的平均吸附率高于中性土壤,中性土对Hg（Ⅱ）的最大吸附量为156.9μg/g,酸性土达到201.38μg/g.2种土壤结合Hg（Ⅱ）的解吸量和解吸率都较低,且酸性土的解吸率（...     

基于TPB的通航企业事件信息自主上报意愿影响因素研究*

为探讨通航企业不安全事件信息自主上报意愿的影响因素,基于扩展计划行为理论的分析框架,采用结构方程模型和差异显著性分析,对我国通航企业170份样本数据进行分析。结果表明:企业性质、规模和成立年限显著影响企业事件信息报告行为意向。其中,国有企业行为意向显著高于民营企业,500人以上较大规模企业行为意向显著高于500人以下较小规模企业,成立3 a以上企业的行为意向显著高于成立3 a以下的企业。此外,通航企业不安全事件自主上报的行为意向直接影响因素包括行为态度、主观规范、知觉行为控制、感知成本及认知,间接影响因素是感知成本与感知收益、示范性规范与指令性规范。     

改性沸石负载纳米β-FeOOH对溶液中Cr(Ⅵ)的吸附性能

采用恒温水浴法制得纳米β-Fe OOH,将其负载在改性沸石(SMZ)上制得复合材料β-Fe OOH/SMZ。用β-Fe OOH/SMZ吸附溶液中的Cr(Ⅵ)。考察了吸附时间、溶液p H、初始Cr(Ⅵ)质量浓度等因素对其吸附Cr(Ⅵ)效果的影响。实验结果表明:β-Fe OOH/SMZ对Cr(Ⅵ)的最佳吸附时间为5 h,适宜的溶液p H为6.0;随着初始Cr(Ⅵ)质量浓度的增加,β-Fe OOH/SMZ对Cr(Ⅵ)的吸附量逐渐增加;在β-Fe OOH/SMZ加入量为5.0 g/L、溶液p H为6.0、初始Cr(Ⅵ)质量浓度为250 mg/L、吸附温度为25℃的条件下,吸附量最高(为22.1 mg/g)。准二级动力学方程适用于描述β-Fe OOH/SMZ对Cr(Ⅵ)的吸附过程。该吸附由多个过程共同控制,颗粒内扩散并非唯一控速步骤。Freundlich等温方程比D-R等温方程更适于描述Cr(Ⅵ)在β-Fe OOH/SMZ上的吸附行为,β-Fe OOH/SMZ对Cr(Ⅵ)的吸附为多层吸附。     

活性炭吸附有机蒸气性能的研究

吸附法在油气回收技术中运用很广泛.吸附剂的选择对吸附分离效果起到了决定性作用.选用3种商用活性炭,以正己烷和正庚烷为吸附质,在温度为293.15 K下进行了静态和动态吸附实验,并研究了活性炭孔结构对其吸附性能和吸附能的影响,同时利用Logistic模型的回归公式对活性炭的吸附穿透曲线进行拟合.结果表明,活性炭的比表面积和孔容是其吸附性能主要影响因素;正己烷和正庚烷的吸附行均符合Langmuir吸附等温模型;3种活性炭对正己烷和正庚烷的吸附能都随其比表面积变大而变大;Logistic模型拟合曲线与实验结果具有高度相似性,可用于活性炭吸附穿透曲线的预测.