水溶性巯基壳聚糖对污染土壤吸附态汞的解吸作用研究

用两种巯基化试剂半胱氨酸(Cys)和硫代乙醇酸(Thi)与壳聚糖(CTS)反应,制备了两种水溶性巯基壳聚糖,即Cys-CTS和Thi-CTS,对比研究了这两种巯基壳聚糖与CTS对被染毒土壤中吸附态汞的提取能力.结果表明,Thi-CTS在pH=3、质量浓度为0.5g/L、用量为20 mL的条件下.对汞的提取率为59.44%,相同条件下CTS和cys-CTS对汞的最高提取率只有31.81%和10.15%.     

煤炭行业推行安全生产责任保险作用及问题探讨

为了减少事故及其造成的损失,使企业不致因灾后赔付而陷人困境和摆脱“企业赚钱,政府发丧”的怪圈,在煤炭行业推行安全生产责任保险,把商业保险模式引入安全生产领域,分散转移风险,并运用保险行业风险管理方法,规避、控制和管理风险,强化事故预防,以达到安全发展、可持续发展的目标。笔者在认真研究有关政策法规,搜集整理相关资料,实地凋研考察的基础上,结合我国煤炭行业安全生产以及煤炭行业责任风险管理现状,对我国煤炭行业推行安全生产责任保险的作用以及试点省市安全生产责任保险实施过程中遇到的问题进行了分析探讨。     

我国矿业城市的产业结构调整及其发展途径

由于受资源递减规律影响,矿业城市的发展必将受到其不合理产业结构的限制。产业结构调整是矿业城市得以持续发展的必由之路,基于其资源与区位优势发展替代性产业是矿业城市产业结构调整的最佳选择。本文探讨了矿业城市产业结构调整的一些原则,提出了一些对策和建议。     

负外部成本内部化约束下的煤炭开采税费水平研究

煤炭开采中面临严重的代际负外部性和生态环境负外部性问题,分别运用使用者成本法和直接市场法测算了煤炭资源开采中的代际负外部成本和生态环境负外部成本。根据两个负外部成本充分内部化的要求,提出煤炭开采中税费水平的调整目标。以2008年为例,煤炭开采中资源税的征收标准应由目前的从量0.3-5元/t(约从价1%)提至从价10%;开采吨煤应交的生态环境费用标准应由目前的24元/t提至64.23-68.47元/t,即每吨提高40.23-44.47元。综合资源税和生态环境费用的提高幅度,煤炭开采活动中的税费水平应提高约21-22个百分点;通过比较现行税费制度下煤炭开采企业实交的资源税费、生态环境税费总额与企业应交的资源、生态环境费用总额之间的差距,指出目前我国政府对开采企业隐性税费补贴的规模水平,根据价差法计算得出取消此部分税费补贴将可以削减3 653.69万tCO2排放。     

以多联产为支撑点的"合成气城市"规划 --煤炭城市的可持续发展

目前,中国煤炭城市普遍面临城市产业结构迫切需要转型、城市生态环境问题严重、城市人口就业形势严重等挑战。在低价高硫煤资源丰富、石油和天然气资源缺乏、经济发展水平适中、产业结构亟待调整的典型地区实施以多联产为支撑点的“合成气城市”规划,是这类煤炭城市实现经济、社会、环境、资源相互协调的可持续发展之路。本文初步探讨了“合成气城市”规划研究的内容,并以山东省济宁市是为例分析了实施“合成气城市规划”的收益。     

中国西部能源及矿业开发与环境保护协调发展研究

中国西部地区自然环境脆弱且恶劣,但能源及矿产资源分布相对集中,能源及矿业开发已经成为其经济社会发展的支柱产业.本文力图从西部能源及矿业开发与环境保护协调发展、促进资源开发与生态保护的视角,综合辨析出西部地区能源及矿业开发引发的地质环境及生态环境恶化问题,主要包括土壤污染与土地破坏、水资源污染与短缺、矿区大气污染、噪声污染以及采矿诱发的各类地质灾害和生态环境破坏等.文章认为:西部地区矿产资源和能源开发等人为因素引发的地质环境及生态环境恶化问题日益突出,增强西部地区可持续发展能力,确保资源开发与环境保护的协调发展是西部地区提高能源资源保障能力的现实选择,也是转变发展方式、建设“两型”社会的必然要求.为此,本文对西部地区能矿资源开发与环境保护的协调发展提出了相关建议,主要包括:大力推行绿色发展,极开发绿色新能源;加强资源管理与污染控制,建立、健全矿产资源开发环境保护相关法律法规和体系,健全生态补偿机制;通过市场准入制度设立绿色门槛,继续整合小矿山;加强西部资源型城市与沿海地区的区域融合,减少资源开发的负外部性,破除“资源诅咒”;借鉴国际上“责任矿产开发倡议”,提高能源及矿产资源开发利益相关者的参与能力;统筹协调资源税费、地方发展基金,明确资源税的调节作用,健全利益分配机制,设立绿色发展基金;加强能矿资源开发全过程的第三方独立监管,在能源及矿产资源开发过程中实行有效透明的监管等.     

A conceptual approach to model sand–gravel extraction from rivers based on a game theory perspective

Sand–gravel mining is a significant parameter of economic development and social welfare function in modern societies. As demand for aggregate increases in construction industry, conflicts for the availability of the resource and environmental impacts become more intense. The present paper describes the contested status quo in riverbed sand–gravel mining activities with an example from Greece, as a case study. The scope is to propose a methodology about good governance of the mining sector that promotes a sustainable sharing of aggregate resource by securing environment and safekeeping revenues in the mining trade market.     

Linking landscape development intensity within watersheds to methyl-mercury accumulation in river sediments

An indicator of the disturbance of natural systems, the landscape development intensity (LDI) index, was used to assess the potential for land-use within watersheds to influence the production/accumulation of methyl-mercury (MeHg) in river sediments. Sediment samples were collected from locations impacted by well-identified land-use types within the Mobile-Alabama River Basin in Southeastern USA. The samples were analyzed for total-Hg (THg) and MeHg concentrations and the obtained values correlated to the calculated LDI indexes of the sampled watersheds to assess the impact of prevalent land use/land cover on MeHg accumulation in sediments. The results show that unlike THg, levels of MeHg found in sediments are impacted by the LDI indexes. Overall, certain combinations of land-use types within a given watershed appear to be more conducive to MeHg accumulation than others, therefore, pointing to the possibility of targeting land-use practices as potential means for reducing MeHg accumulation in sediments, and ultimately, fish contamination.     

A DFT study of the reactions of O3 with Hg° or Br

In the mid 1980s the study of ozone reactivity gained a significant interest with the discoveries of the stratospheric ozone hole (Farman et al., 1985) and of the ozone depletion events in the polar boundary layer (Oltmans et al., 1989). In the stratosphere, the mechanism involves heterogeneous reactions on polar stratospheric clouds that lead to chlorine activation (Solomon et al., 1986). In contrast, tropospheric ozone depletion occurring during polar springtime rather involves reactive bromine species. They are released during a series of photochemical and heterogeneous reactions often called the bromine explosion (see the review of Simpson et al., 2007). In this reaction sequence, an essential step is the generation of photolyzable Br₂, the precursor of two Br atoms, via the multiphasic reaction (1):

(1)

HOBr + Br⁻ + H⁺ → H₂O + Br₂

The production of reactive HOBr could occur with the oxidation of BrO by HO₂.     

Accumulation, distribution and cellular partitioning of mercury in several halophytes of a contaminated salt marsh

This work evaluates the role of a plant community in mercury (Hg) stabilization and mobility in a contaminated Portuguese salt marsh. With this aim, the distribution of Hg in below and aboveground tissues, as well as the metal partitioning between cellular fractions (soluble and insoluble) in four different species (Triglochin maritima L., Juncus maritimus Lam, Sarcocornia perennis (Miller) A.J. Scott, and Halimione portulacoides (L.) Aellen) was assessed. Mercury accumulation, translocation and compartmentation between organs and cellular fractions were related to the plant species.Results showed that the degree of Hg absorption and retention was influenced both by environmental parameters and metal translocation/partitioning strategies. Different plant species presented different allocation patterns, with marked differences between monocots (T. maritima and J. maritimus) and dicots (S. perennis, H. portulacoides). Overall, the two monocots, in particular T. maritima showed higher Hg retention in the belowground organs whereas the dicots, particularly S. perennis presented a more pronounced translocation to the aboveground tissues. Considering cellular Hg partitioning, all species showed a higher Hg binding to cell walls and membranes rather than in the soluble fractions. This strategy can be related to the high degree of tolerance observed in the studied species. These results indicate that the composition of salt marsh plant communities can be very important in dictating the Hg mobility within the marsh ecosystem and in the rest of the aquatic system as well as providing important insights to future phytoremediation approaches in Hg contaminated salt marshes.