Enhanced catalytic complete oxidation of 1,2-dichloroethane over mesoporous transition metal-doped γ-Al2O3

High-surface-area mesoprous powders of γ-Al₂O₃ doped with Cu^2 +, Cr^3 +, and V^3 + ions were prepared via a modified sol–gel method and were investigated as catalysts for the oxidation of chlorinated organic compounds. The composites retained high surface areas and pore volumes comparable with those of undoped γ-Al₂O₃ and the presence of the transition metal ions enhanced their surface acidic properties. The catalytic activity of the prepared catalysts in the oxidation of 1,2-dichloroethane (DCE) was studied in the temperature range of 250–400°C. The catalytic activity and product selectivity were strongly dependent on the presence and the type of dopant ion. While Cu^2 +- and Cr^3 +-containing catalysts showed 100% conversion at 300°C and 350°C, V^3 +-containing catalyst showed considerably lower conversion. Furthermore, while the major products of the reactions over γ-alumina were vinyl chloride (C₂H₃Cl) and hydrogen chloride (HCl) at all temperatures, Cu- and Cr-doped catalysts showed significantly stronger capability for deep oxidation to CO₂.     

海上应急保障资源调度的多目标模糊规划模型

针对现有应急资源调度模型无法完全适应海上应急保障环境的问题,建立了基于多目标模糊规划的海上应急资源调度模型.首先,将不确定的航行时间和资源需求量表示为三角模糊数,用时间隶属度函数的全积分对模糊应急开始时间进行确定化表示,用需求量隶属度表示需求点所接收的资源数量满足需求的程度.然后,考虑各需求点和各类资源的重要程度,以系统的时效性、需求满意度、安全性和经济性为优化目标建立多目标规划模型,最后,给出了模型的求解方法,并通过算例分析证明了方法的有效性.     

大气污染总量控制方案的区域排放当量制定方法

在分析现有的大气污染总量控制方案的制定方法的基础上,本文提出了区域排放当量概念及相应的大气污染物总量控制方法。应用该概念制定总量控制方案,首先是运用线性规划模型求解区域允许排放当量,线性规划模型中的技术系数是以区域内网格为基础的污染物转移函数;其次是分配区域允许当量至各个污染源,从而确定污染源的允许排放量。该方法已在南昌市的大气污染总量控制方案的制定中得到应用。     

矿产资源总体规划对四川省甘孜州资源-环境承载力影响分析研究

本文根据矿区资源环境承载力的内涵,构建了"目标层-准则层-因子层-指标层"资源环境承载力评价体系,并在此基础上通过专家咨询打分的方式,采用层次分析法(AHP法)计算得出甘孜州矿产资源总体规划实施现状年、近景年、远景年3个时间段资源-环境承载力综合指数,为四川省甘孜州矿产资源总体规划环评影响影响评价提供了技术支撑和科学根...     

滑坡预测的改进前馈网络方法研究

作者提出了滑坡位移预测的一种改进前馈网络方法——目的规划法,与通常的前馈网络方法相比,该方法改进了网络的准则函数,降低了网络的灵敏度,改善了网络的泛化性能,提高了滑坡位移的预测精度。同时它是一种面向数据的方法,适合于不同地区不同条件下滑坡的预测。清江隔河岩库区滑坡和卧龙寺滑坡的实例研究表明了该方法的可行性及有效性。     

湖北省土地利用减碳增效系统仿真及结构优化研究

土地利用变化是引起碳排放的重要原因之一,土地经济效益是利用土地的目标之一,如何通过优化土地利用结构实现土地利用减碳增效是值得研究的重要问题。基于系统结构与功能相互作用的视角,梳理复杂系统内变量间的反馈关系,运用系统动力学(SD)进行建模,将约束条件纳入到多目标规划(MOP)中,实现MOP与SD模型整合,进行系统仿真并得出优化后2020年湖北省土地利用结构。结果显示,利用SD-MOP模型能够实现减碳增效目标下土地利用结构优化,与2008年真实值相比,耕地、林地、牧草地及建设用地分别增加了0.33×10~4、30.17×10~4、0.08×10~4和16.37×10~4 hm~2,其他农用地及未利用地分别减少7.23×10~4、33.15×10~4 hm~2;与无约束SD单模型仿真相比,土地利用碳排放量减少了58×10~4 t,经济效益年增长率维持在3.58%,优化方案具有可行性。SD-MOP模型优化的土地利用结构符合区域可持续发展要求,兼顾了土地利用碳减排和经济效益增长的双重目标,能为区域土地资源优化配置提供参考。     

A Spatial Analysis of the Economic and Ecological Efficacy of Land Retirement

This paper uses a cellular automata simulation model of a hypothetical landscape to investigate the role of location as it relates to the efficacy of land retirement in achieving two environmental goals: hydrological improvement and habitat improvement. Statistical analysis of simulation results is used to show how absolute and relative location relate to achievement of these objectives. Linear and nonlinear compromise programming frameworks then combine these two environmental objectives and a cost minimization objective into a measure that allows decision-makers to rank the desirability of different retirement strategies. These frameworks are explored to determine what each implies about the tradeoffs that must be made among objectives and among the spatial land parcel characteristics that contribute to those objectives.     

WATER-SURFACE PROFILES WITHOUT ENERGY LOSS COEFFICIENTS1

ABSTRACT: This paper describes a new method of computing water-surface profiles, which does not require the assumption of hydrostatic pressure or of roughness coefficients. The method is based upon distributing entropy production values along a channel as uniformly as boundary conditions permit. The method requires a discharge capacity rating at a channel cross-section within the limits of the reach of the channel. A new theoretical relationship between the kinetic and momentum coefficients for the velocity profile is used, together with a dynamic programming technique for optimal distribution of energy losses along the channel. A computer model was developed and was used to verify the methodology for flood flow and channel data at four locations.     

OPTIMIZATION OF MULTIPURPOSE RESERVOIR SYSTEM OPERATION1

ABSTRACT: The goal programming approach for multipurpose reservoir operation has been proposed and applied to the Bhadra reservoir system, having irrigation and hydropower production as dual purposes, in India. The objective of the model is to satisfy sequentially a series of operating criteria. Two goal programming models, one with the objective function as minimizing the deviations from storage targets and the other with the objective function as minimizing the deviations from release targets, have been formulated and applied to the reservoir system under study. The results proved that the model with release targets is preferred over the model with storage targets for determining operational policies for multipurpose reservoir system.     

Community richness and stability in agricultural landscapes: The importance of surrounding habitats

In this paper, the role played by habitat diversity in the landscape on species richness and on the stability of farmland bird communities was investigated. Species richness was estimated on 374 samples monitored in farmland by the French breeding bird survey during the 2001–2005 period. A capture–recapture approach was used to estimate species richness accounting for the variation in detection probability among species of the 100 most common species detected in farmland. Landscape structure and composition were measured both in farmland and in adjacent habitats. The independent effect of each variable on community richness and stability was further assessed using hierarchical variance partitioning and taking spatial autocorrelation into account. A strong matrix effect was detected: non-cropped land deeply influenced richness and stability of bird assemblages.