碱激发胶凝材料及其固化Pb^2＋的试验研究

对碱激胶凝材料（碱-偏高岭土、碱-矿渣和碱-粉煤灰）与水-水泥体系固化Ph^2＋进行了试验研究,其中水-水泥体系为对比样。结果表明：对于相同稠度的碱激发胶凝材料,即使Pb^2＋含量达到2．4％,除了碱-粉煤灰的抗压强度略低外,其他都达到30MPa以上,满足填埋或做建筑基材的使用要求;与水泥相比,碱激发胶凝材料能显著降低重金属离子（Ph^2＋）浸出浓度,其规律性与其NH4交换容量大小的规律性一致,与其固化体的抗压强度的大小没有相关性。     

长江中上游防护林体系森林植被碳贮量及固碳潜力估算

基于“八五”期间长江中上游流域各省的森林资源调查资料,结合经典的材积源生物量法估算了长江中上游防护林体系生物量碳密度和碳贮量,并根据不同树种生物量-生产力回归关系推算了该地区当前的固碳潜力。结果表明：长江中上游地区森林平均碳密度为2575 t/hm2;碳贮量为1 39459 Tg (1 Tg = 1012 g),其中林分（包括经济林）碳贮量为1 20430 Tg,灌木林为13437 Tg,竹林为5592 Tg,三者分别占总碳贮量的8636%、963%和401%。整个防护林体系森林植被的固碳潜力为36856 Tg/a。位于本区西部的四川盆地嘉陵江流域和西部高山峡谷区,其森林碳密度、碳贮量和固碳潜力较高,而东部地区的川鄂山地长江干流、鄱阳湖水系以及洞庭湖水系相对较低,因此,长江中上游森林碳密度、碳贮量和固碳潜力总体上呈现自西向东逐渐降低的趋势。     

改性多壁碳纳米管对水中Cd~（2＋）的去除

为了增加多壁碳纳米管（multiwall carbon nanotubers,MWNTs）对水中Cd2＋的吸附量,使用混酸对多壁碳纳米管进行氧化处理,采用红外光谱进行结果表征,并探讨了吸附时间、pH值和MWNTs的使用量、Cd2＋的浓度及干扰离子对镉离子吸附的影响。结果表明,吸附时间为1.5 h、pH为5.3、吸附效果最佳,随MWNTs量的增加Cd2＋去除量增加,共存的阳离子会降低对Cd2＋的吸附效果,对Cd2＋的吸附符合Longmuir吸附定律。研究同时表明,pH小于2时Cd2＋能容易从碳纳米管上解吸。初步探讨了Cd2＋吸附机制。     

Evaluation of a classification method for biodegradable solid wastes using anaerobic degradation parameters

We studied the biochemical and anaerobic degradation characteristics of 29 types of materials to evaluate the effects of a physical composition classification method for degradable solid waste on the computation of anaerobic degradation parameters, including the methane yield potential (L₀), anaerobic decay rate (k), and carbon sequestration factor (CSF). Biochemical methane potential tests were conducted to determine the anaerobic degradation parameters of each material. The results indicated that the anaerobic degradation parameters of nut waste were quite different from those of other food waste and nut waste was classified separately. Paper was subdivided into two categories according to its lignin content: degradable paper with lignin content of <0.05 g g VS^?1, and refractory paper with lignin content >0.15 g g VS^?1. The L₀, k, and CSF parameters of leaves, a type of garden waste, were similar to those of grass. This classification method for degradable solid waste may provide a theoretical basis that facilitates the more accurate calculation of anaerobic degradation parameters.     

Homegardens as a Multi-functional Land-Use Strategy in Sri Lanka with Focus on Carbon Sequestration

This paper explores the concept of homegardens and their potential functions as strategic elements in land-use planning, and adaptation and mitigation to climate change in Sri Lanka. The ancient and locally adapted agroforestry system of homegardens is presently estimated to occupy nearly 15 % of the land area in Sri Lanka and is described in the scientific literature to offer several ecosystem services to its users; such as climate regulation, protection against natural hazards, enhanced land productivity and biological diversity, increased crop diversity and food security for rural poor and hence reduced vulnerability to climate change. Our results, based on a limited sample size, indicate that the homegardens also store significant amount of carbon, with above ground biomass carbon stocks in dry zone homegardens (n = 8) ranging from 10 to 55 megagrams of carbon per hectare (Mg C ha⁻¹) with a mean value of 35 Mg C ha⁻¹, whereas carbon stocks in wet zone homegardens (n = 4) range from 48 to 145 Mg C ha⁻¹ with a mean value of 87 Mg C ha⁻¹. This implies that homegardens may contain a significant fraction of the total above ground biomass carbon stock in the terrestrial system in Sri Lanka, and from our estimates its share has increased from almost one-sixth in 1992 to nearly one-fifth in 2010. In the light of current discussions on reducing emissions from deforestation and forest degradation (REDD+), the concept of homegardens in Sri Lanka provides interesting aspects to the debate and future research in terms of forest definitions, setting reference levels, and general sustainability.     

天然和CPB改性沸石对Hg^2＋的吸附特征

通过静态实验研究溴代十六烷基吡啶（CPB）改性沸石和天然沸石对废水中Hg^2＋的吸附特性,探讨了吸附动力学、吸附平衡和吸附热力学机制。研究表明：Langmuir方程能较好地描述2种沸石对Hg^2＋的吸附,CPB改性沸石对Hg^2＋的吸附率得到显著提高。实验条件下,改性沸石对Hg^2＋的吸附率从67．5％提高到98．9％,吸附容量从0．521mg／g提高到3．07mg／g。利用准一级动力学方程、假二级动力学方程、颗粒内扩散模型和Elovich方程分别对动力学过程进行拟合,发现2种沸石对Hg^2＋的吸附均满足假二级动力学方程,且离子的颗粒内扩散对整个吸附过程有影响。动力学拟合、D-R方程拟合和热力学研究综合表明：2种沸石对Hg^2＋的吸附既存在化学吸附又存在物理吸附,吸附吉布斯自由能变（△G^0）、焓变（△H^0）、熵变（△S^0）均小于0,反应为自发的放热反应,低温有利于吸附的进行。     

A Note on the Use of Conservation Practices in U.S. Agriculture

This article measures the effect of an increase in productivityattributable to an increase in soil organic carbon associated with theincrease in the use of conservation practices in agriculture in theUnited States. Both the direct and indirect effects are calibrated. Theanalytical approach used consists of a dynamic computable generalequilibrium model composed of 14 producing sectors, 10 consumingsectors, seven household categories classified by income, and agovernment. The results suggest that the impact of a change inproductivity is an increase in output over a six year period starting in1998 in field crops. The most significant impact is felt in thelivestock sector. This is because field crops are a major input in theproduction of livestock. The food processing sector also exhibits arelatively large increase because of the increase in inputs of both fieldcrops and livestock. Manufacturing output increases primarily becauseoverall investment rises and most investment utilizes manufacturinggoods. The other producing sectors are generally unaffected by theincrease in agricultural production due to an increase in soil organiccarbon. Coincident with the increase in the production of field cropsis a relatively large decrease in the price of field crops. Othernoticeable price reductions occur in the livestock sector and the foodprocessing sector. For the consuming sectors, the consumption offood and alcohol and tobacco increase but consumption in all of theother sectors remains basically unchanged. Prices in the food andalcohol and tobacco sectors decline by about 1% while theprices in the other sectors remain static. Household welfare increasesin the aggregate by only 0.1% with this increase occurringuniformly across all household categories. Revenue received by thegovernment increases a modest 2% in response to an increase inoutput and, hence, an increase in taxes paid. The results indicate thatthere are significant production benefits for several sectors that can berealized by an increase in the use of conservation practices inagricultural production which, in turn, enhances soil organic carbon.There are a number of policy options available to promote the use ofconservation practices. These include education and technicalassistance, financial assistance, research and development, landretirement, and regulation and taxes.     

Molecular composition of recycled organic wastes,as determined by solid-state 13C NMR and elemental analyses

Using solid state ¹³C NMR data and elemental composition in a molecular mixing model, we estimated the molecular components of the organic matter in 16 recycled organic (RO) wastes representative of the major materials generated in the Sydney basin area. Close correspondence was found between the measured NMR signal intensities and those predicted by the model for all RO wastes except for poultry manure char. Molecular nature of the organic matter differed widely between the RO wastes. As a proportion of organic C, carbohydrate C ranged from 0.07 to 0.63, protein C from <0.01 to 0.66, lignin C from <0.01 to 0.31, aliphatic C from 0.09 to 0.73, carbonyl C from 0.02 to 0.23, and char C from 0 to 0.45. This method is considered preferable to techniques involving imprecise extraction methods for RO wastes. Molecular composition data has great potential as a predictor of RO waste soil carbon and nutrient outcomes.     

National policies for biosphere greenhouse gas management: issues and opportunities

Biosphere greenhouse gas (GHG) management consists of preserving and enhancing terrestrial carbon pools and producing biomass as a fossil fuel substitute. The discussion of this topic has focused primarily on carbon-accounting and project-level issues, particularly relating to carbon sequestration as a source of emissions credits under the Kyoto Protocol. While international consensus on these matters is needed, this paper argues that an important domestic policy agenda also deserves attention. National policies for biosphere GHG management are necessary to bring about large-scale changes in land-use, forestry, and agricultural practices and can address some of the technical and policy issues that have proven to be particularly problematic from carbon-accounting and project-level perspectives. These policies should minimize land-use and resource-management conflicts, account for collateral benefits, and ensure institutional compatibility with existing resource-management regimes. Issues relating to project permanence, leakage, and transaction costs should also be addressed. A range of policy instruments should be used and biosphere GHG management should be one component of an integrated approach to environmental and resource management. Countries promoting biosphere GHG management as an important element of their climate change strategies should be developing these domestic policies to complement international negotiations and to demonstrate that carbon sequestration and biomass production can make an effective contribution to the stabilization of atmospheric GHG concentrations.     

Developing sinks for CO<Subscript>2</Subscript> through forestation of temperate coastal barriers: an environmental business

Since the 1940s, some sectors of the sand dune barriers of Buenos Aires Province have been forested to fix the sand in the neighborhoods of resort villages. Man took advantage of the maritime climate and the shallow groundwater to introduce pine forests. Today, these forests reach more than 20 m in height and have developed soils of more than 0.05 m in thickness on former arid sands. Field data were referred to Landsat (TM) composite and Normalized Difference of Vegetation Index, NDVI, images to calculate forest density and covered area. Considering published tables of wood density for each species, the amount of total carbon storage was estimated on 318 t C ha^-1 (Mg=10⁶ g) in biomass and 86 t C ha^-1 in soils. The three areas analyzed at Miramar, Necochea and Claromecó have captured 658,868 t of carbon in the last 50 years. It is estimated that 150,000,000 t C could be sequestered within temperate dune barriers of Argentina, Uruguay and Brazil. Besides this ecological point of view, there is an important socio-economic factor that cannot be excluded.Presented at and revised subsequent to the 4th LOICZ Open Science Meeting, Bahía Blanca, Argentina. October 1999.