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111.
Sumana Siripattanakul Wanpen Wirojanagud John McEvoy Eakalak Khan 《Water, Air, & Soil Pollution: Focus》2008,8(3-4):257-266
Atrazine biodegradation by immobilized pure and mixed cultures was examined. A pure atrazine-degrading culture, Agrobacterium radiobacter J14a (J14a), and a mixed culture (MC), isolated from an atrazine-contaminated crop field, were immobilized using phosphorylated-polyvinyl
alcohol (PPVA). An existing cell immobilization procedure was modified to enhance PPVA matrix stability. The results showed
that the matrices remained mechanically and chemically stable after shaking with glass beads over 15 days under various salt
solutions and pH values. The immobilization process had a slight effect on cell viability. With the aid of scanning electron
microscopy, a suitable microstructure of PPVA matrices for cell entrapment was observed. There were two porous layers of spherical
gel matrices, the outside having an encapsulation property and the inside containing numerous pores for bacteria to occupy.
J14a and MC were immobilized at three cell-to-matrix ratios of 3.5, 6.7, and 20 mg dry cells/mL matrix. The atrazine biodegradation
tests were conducted in an aerobic batch system, which was inoculated with cells at 2,000 mg/L. The tests were also conducted
using free (non-immobilized) J14a and MC for comparative purpose. The cell-to-matrix ratio of 3.5 mg/mL provided the highest
atrazine removal efficiency of 40–50% in 120 h for both J14a and MC. The free cell systems, for both cultures, presented much
lower atrazine removal efficiencies compared to the immobilized cell systems at the same level of inoculation. 相似文献
112.
大气光化学烟雾反应机理比较(Ⅰ)O3和NOx的比较 总被引:8,自引:0,他引:8
在相同初始和排放条件下,对四种应用较广的光化学烟雾反应机理(CB4-99,RADM2,RACM,SAPRC99)进行了比较.研究发现对于O3,在低VOCs/NOx时,四种机理模拟结果相关较小,平均相对标准偏差为7%,在高VOCs/NOx时,平均相对标准偏差为26%,差距较大;对于NOx,多数情况下RACM和RADM2的模拟结果较高,CB4-99和SAPRC99的模拟值偏低,其原因主要来源于不同机理中O3的生成对NOx及VOCs的敏感性不同而造成的.在用模式模拟O3和NOx时,应特别注意机理不同而带来的模拟结果差异. 相似文献
113.
Jie Liu Junjun Ma Weizhang Zhong Jianrui Niu Zaixing Li Xiaoju Wang Ge Shen Chun Liu 《Frontiers of Environmental Science & Engineering》2023,17(4):51
114.
Hassan Abdel-Gawad Hamdy Taha 《Journal of environmental science and health. Part. B》2013,48(8):683-690
Sunflower plants were treated with 14C-chlorpyrifos under conditions simulating local agricultural practice. Residues present in the oil, methanol extract and cake of the treated sunflower seeds were 7.2, 2.8, and 12 ppm, respectively. When rats fed on sunflower cake containing bound residues for three days, the animals eliminated 46 % of the radioactivity in urine, 25 % in feces and 10 % in the expired air. A further bioavailable amount of 8 % was found in selected organs indicating that the bound residues were highly bioavailable. Chromatographic analysis of urine extract revealed the presence of the parent compound, its oxon, desethyl chlorpyrifos and desethyl chlorpyrifos oxon as free metabolites in addition to a conjugated metabolite. It was liberated by acid hydrolysis and identified as 3,5,6-trichloro-2-hydroxypyridine. Bound residues were found to have biological effects such as inhibition of rat plasma ChE, elevations of liver parameters (ALT, AST, and ALP), decrease in total protein and albumin content suggesting a hepatotoxic potential. A significant increase in the values of creatinine, urea, cholesterol, triglycerides and significant decrease in Catalase and Glutathion-S-Transfrase were observed in treated rats. 相似文献
115.
In this paper we study both exhaustible and renewable resources in an endogenous growth model. In particular, we consider the hypotheses in which the rate of technical substitution (RTS) between those two inputs is or is not equal to one. Moreover, we depart from a basic theoretical framework to account for the negative externality constituted by waste accumulation. Finally, a comparative analysis is made between Pigouvian tax and waste recycling, as an environmental policy to correct market failure represented by refuse accumulation. 相似文献
116.
Jasmin Jaquet Pascal Weitzel Thorsten Junge Burkhard Schmidt 《Journal of environmental science and health. Part. B》2013,48(4):245-254
The metabolic fate of 14C-phenyl-labeled herbicide clodinafop-propargyl (CfP) was studied for 28 days in lab assays using a soil from Germany (Ap horizon, silt loam, and cambisol). Mineralization amounted to 12.40% of applied 14C after 28 days showing a distinct lag phase until day 7 of incubation. Portions of radioactivity extractable by means of 0.01 M CaCl2 solution (bioavailable fraction) decreased rapidly and were 4.41% after 28 days. Even immediately after application, only 57.31% were extracted with the aqueous solvent. Subsequent extraction using accelerated solvent extraction (ASE; acetonitrile/water 4:1, v/v) released 39.91% of applied 14C with day 0 and 26.16% with day 28 of incubation from the samples. Non-extractable portions of radioactivity thus, increased with time amounting to 11.99% (day 0) and 65.00% (day 28). A remarkable increase was observed between 14 and 28 days correlating with the distinct increase of mineralization. No correlation was found throughout incubation with general microbial activity as determined by DMSO reduction. Analysis of the CaCl2 and ASE extracts by radio-TLC, radio-HPLC and GC/MS revealed that CfP was rapidly cleaved to free acid clodinafop (Cf), which was further (bio-) transformed; DT50 values (based on radio-TLC detection of the parent compound) were far below 1 day (CfP) and about 7 days (Cf). TLC analysis pointed to 2-(4-hydroxyphenoxy)-propionic acid as further metabolite. Due to fractionation of non-extractable residues, most of the 14C was associated with fulvic and humic acids, portions in humin fractions and non-humics were moderate and low, respectively. Using a special strategy, which included pre-incubation of the soil with CfP and then mineralization of 14C-CfP as criterion, a microorganism was isolated from the soil examined. The microorganism grew using CfP as sole carbon source with concomitant evolution of 14CO2. The bacterium was characterized by growth on commonly used carbon sources and by 16S rDNA sequence analysis. The sequence exhibited high similarity with that of Rhodococcus wratislaviensis (99.56%; DSM 44107, NCIMB 13082). 相似文献
117.
During a survey of tropospheric ozone pollution carried out using tobacco plants (Nicotiana tabacum L.) cv. Bel-W3, ozone- supersensitive, and cv. Bel-B, ozone-resistant, as bioindicators, the effectiveness of the traditional biomonitoring method, based on the use of adult plants, was compared with an innovative miniaturized kit of seedlings. The ratio of foliar and cotyledonar necrosis, respectively, was estimated as ozone injury rate. The miniaturized kit proved to be advantageous, since seedlings need only easy growth procedures and a large number of individuals can be placed in a small space, supplying good data amounts for statistical elaboration. Moreover, correlation studies among cotyledonar and foliar injury index and ozone levels monitored through physico-chemical measurements and results of analysis of variance tests highlighted the high sensitivity of the innovative methodology. 相似文献
118.
By 2009, Ghana was the second-ranked African producer after South Africa, and had become the world's ninth largest producer of gold, at some 3.8% of global production, up from 2.6% five years earlier. Gold production volumes and revenues rose significantly over the decade from 2000. Yet gold mining tends to be perceived negatively in Ghana, and is seen as providing far less than it should in terms of public revenue, employment, skills development and spillovers, and localised economic development. Gold mining is often depicted as having an enclave status, disconnected and isolated from the rest of the economy. In contrast, the research findings here demonstrate that after a period of strong investment and growth, gold mining can no longer be viewed as an enclave activity: it is in fact more deeply linked into the Ghanaian economy than hitherto understood, through a set of as yet under-researched but promising economic linkages, notably backward linkages, which can potentially be strengthened by policy and support measures. 相似文献
119.
PM2.5与O3均为导致城市环境空气质量恶化的主要污染物,采用自动设备监测湖南省长沙、株洲、湘潭3市商业区和郊区空气中的PM2.5和O3质量浓度,并对数据进行相关性分析.结果表明:PM2.5和O3质量浓度的季节性变化大,其中O3质量浓度夏、秋2季高,春、冬2季低;PM2.5则秋、冬2季高,春、夏2季低;O3质量浓度峰值一般出现在当天午后,PM2.5质量浓度峰值一般出现在上午;空间分布上,O3质量浓度在郊区站点相对较高,而PM2.5质量浓度在商业区站点较高.PM2.5与O3质量浓度变化以负相关为主,即PM2.5质量浓度高时,O3质量浓度则低,反之亦然,二者一般不产生叠加污染.总体上,夏、秋季节应主要防O3污染,春、冬季节则主要防PM25污染. 相似文献
120.
根据北京市环境保护监测中心发布的PM2.5和O3小时质量浓度及气象、卫星遥感数据,分析了2013年7月2日至10日北京典型PM2.5及O3重污染过程的质量浓度特征及在大气边界层过程各个阶段的质量浓度演变.结果表明,北京夏季O3质量浓度先于PM2.5达到峰值,而天气型演变是导致这一现象的主要原因.具体过程为:1)重污染初始阶段,高压天气型利于前体物积累,PM2.5及O3质量浓度升高;2)在反气旋中部,由于各种污染物质量浓度较低,对大气紫外波段辐射的吸收较弱,导致该阶段紫外辐射强,因而加快了O3生成的光化学反应,O3质量浓度最先达到峰值;3)在反气旋后部,随PM2.5质量浓度增加,辐射变弱,因此O3质量浓度增加速度下降,而受高压后部影响,区域内PM2.5经东南风输送通道进入北京,导致北京PM2.5质量浓度相继达到峰值;4)在重污染清除阶段,在北方反气旋前部的冷锋清除作用下,PM2.5及O3质量浓度同时降低至谷值. 相似文献