植物对沼泽湿地生态系统N2O排放的影响

利用静态暗箱/气相色谱法连续3个生长季(2003-2005年)对三江平原小叶章草甸和毛果苔草沼泽N2O排放通量进行野外对比观测试验.结果表明,植物不同生长阶段对湿地生态系统N2O排放通量的影响不尽相同.植物的参与促进了湿地生态系统N2O的排放,2003-2005年生长季小叶章草甸土壤-植物系统N2O排放通量分别是土壤表观N2O排放通量的1.58倍、2.09倍和2.34倍,同期毛果苔草沼泽土壤-植物系统N2O排放通量分别是土壤表观N2O排放通量的1.86倍、1.50倍和1.33倍.3个生长季小叶章草甸N2O排放通量均大于毛果苔草沼泽,这主要是由土壤理化性质的空间变异性以及水文情况的差异造成的.     

油菜地CO2、N2O排放及其影响因素

2005年11月至2006年5月采用静态箱法对成都平原典型水稻 - 油菜轮作区油菜地CO2、N2O排放通量进行原位测定.结果表明,CO2排放通量为121.4～1 585.8 mg·m-2·h-1,平均656.8 mg·m-2·h-1;N2O排放通量为18.0～521.0 μg·m-2·h-1,平均168.0 μg·m-2·h-1.在整个油菜生长期内,地下5 cm土壤温度与CO2、N2O排放通量之间呈指数函数关系.3种不同处理油菜地CO2、N2O排放通量均为常规处理＞无氮处理＞裸地处理.土壤温度、施氮和植物生长是影响油菜地CO2、N2O排放的主要因素.     

聚四氟乙烯高压密封罐消解样品测定五氧化二钒

利用聚四氟乙烯高压密封罐消解矿石样品测定五氧化二钒,具有操作手续相对简便、轻松、快捷等优点,与传统的硫酸－磷酸混合酸消解或采用碱熔融前处理法比较,相对误差小于１．６％,样品的添加标准回收率为９２．９％～１０３．５％。     

Comparative Evaluation of Biomonitoring Techniques of Tropospheric Ozone

During a survey of tropospheric ozone pollution carried out using tobacco plants (Nicotiana tabacum L.) cv. Bel-W3, ozone- supersensitive, and cv. Bel-B, ozone-resistant, as bioindicators, the effectiveness of the traditional biomonitoring method, based on the use of adult plants, was compared with an innovative miniaturized kit of seedlings. The ratio of foliar and cotyledonar necrosis, respectively, was estimated as ozone injury rate. The miniaturized kit proved to be advantageous, since seedlings need only easy growth procedures and a large number of individuals can be placed in a small space, supplying good data amounts for statistical elaboration. Moreover, correlation studies among cotyledonar and foliar injury index and ozone levels monitored through physico-chemical measurements and results of analysis of variance tests highlighted the high sensitivity of the innovative methodology.     

橡胶促进剂M盐废水生物处理技术研究

为探讨微生物技术在橡胶促进剂M盐废水处理中的应用,利用高效优势蘸强化A2O工艺对橡胶促进剂M盐废水进行处理,整个系统运行过程分为污泥的培养与驯化阶段及稳定运行阶段。在稳定运行阶段COD0平均去除率达90．71％,氨氮平均去除率达78．31％。以Mn^2＋、Fe^2＋、Mg^2＋、Ni^2＋为4个影响因子,通过正交实验分析无机离子对橡胶促进剂M盐废水中有机物降解的促进作用。由实验数据的摄差大小可知,各无机离子对优势复合菌降解橡胶有机废水的影响从大到小依次为：Mn^2＋、Fe^2＋、Ni^2＋和Mg^2＋。4种离子最佳质量浓度组合为：0．500mg／L的Mn^2＋、1．00mg／L的Fe^2＋、35．0mg／L的Mg^2＋和0．025mg／L的Ni^2＋。     

焦化废水处理过程中固相物质的形成及处置方法评价

焦化废水处理过程中产生的焦油、污泥和结晶杂盐等固相物质,既有资源属性,又有污染特性,但目前缺乏基于能源、经济及环境影响方面的评估.本研究阐述了3类固相物质的形成机制,建立了质量当量计算及处置方法评价模型.以宝武集团韶关钢铁股份有限公司焦化厂（二期）焦化废水处理工程的A/O/H/O（厌氧/好氧/水解/好氧）流化床工艺作为考察对象,利用工程运行参数和水质统计数据进行固相物质的产量推算,结果发现,焦油、物化污泥、生物污泥（含水率为80%）和工业杂盐的产率分别为0.186、5.80、4.24和1.97 kg·m^-3.通过处置方法评价模型明确了焦油焚烧、污泥热解、结晶杂盐分盐提纯后工业应用是最佳处置方案,在60 m³·h^-1废水处理规模的固相物质处置过程中,每年约产生1177 MWh的能源,获得135.0万元的经济效益,排放627.0 t CO₂,表明能源回收、经济效益和环境影响的协同存在.     

CTS@Fe3O4-COOH对低pH值Chlorella vulgaris采收性能及机理

采用共沉淀法制备得到磁性材料壳聚糖@柠檬酸改性Fe₃O₄(CTS@Fe₃O₄-COOH),通过单因素与正交试验考察了不同条件下其对小球藻(Chlorella vulgaris)的采收效率.结合XRD、FT-IR和VSM等材料的结构性质表征、表面Zeta电位及Derjaguin-Landau-Verwey-Overbeek(DLVO)理论分析,探讨CTS@Fe₃O₄-COOH对小球藻的絮凝采收机理.结果表明,CTS@Fe₃O₄-COOH对小球藻具有高效采收效率,与未改性相比采收效率提高约30%.单因素试验表明材料投加量与pH值对小球藻采收效率的影响较大;正交试验表明当CTS@Fe₃O₄-COOH投加量为4.5g/L时,在pH 4的条件下,经500r/min快搅3min后再70r/min慢搅5min,对小球藻的采收效率高达98.35%.DLVO等理论分析表明,CTS@Fe₃O₄-COOH对小球藻的采收机理为电荷中和、静电修补、吸附架桥与整体絮凝联合作用.本文结果为CTS@Fe₃O₄-COOH采收固定烟气能源微藻的实际应用提供数据支持.     

Penicillin fermentation residue biochar as a high-performance electrode for membrane capacitive deionization

● We have provided an activated method to remove the toxicity of antibiotic residue. ● PFRB can greatly improve the salt adsorption capacity of MCDI. ● The hierarchical porous and abundant O/N-doped played the key role for the high-capacity desalination. ● A new field of reuse of penicillin fermentation residue has been developed. Membrane capacitive deionization (MCDI) is an efficient desalination technology for brine. Penicillin fermentation residue biochar (PFRB) possesses a hierarchical porous and O/N-doped structure which could serve as a high-capacity desalination electrode in the MCDI system. Under optimal conditions (electrode weight, voltage, and concentration) and a carbonization temperature of 700 °C, the maximum salt adsorption capacity of the electrode can reach 26.4 mg/g, which is higher than that of most carbon electrodes. Furthermore, the electrochemical properties of the PFRB electrode were characterized through cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) with a maximum specific capacitance of 212.18 F/g. Finally, biotoxicity tests have showed that PFRB was non-biotoxin against luminescent bacteria and the MCDI system with the PFRB electrode remained stable even after 27 adsorption–desorption cycles. This study provides a novel way to recycle penicillin residue and an electrode that can achieve excellent desalination.     

高原生境不同水力停留时间下A2/O工艺活性污泥微生物代谢机制研究

在高原生境下构建不同水力停留时间(HRT)运行工况的A²/O系统,结合水质分析及对好氧池活性污泥的16S rRNA基因测序,对微生物优势菌属功能和代谢途径进行研究。结果表明:高原生境下HRT为26.25 h时A²/O工艺处理效果总体最好,微生物优势菌属代谢功能以有机物降解、反硝化脱氮和聚磷菌除磷为主,代谢途径以碳氮磷代谢为主;在高原生境下,应对外界环境变化的细菌双组分调节功能(ko02020)丰度较大,该代谢途径在适应环境变化中有显著作用,是高原生境下的优势代谢途径;微生物细胞中rpoE基因丰度偏大,为微生物适应高原环境提供了保障。HRT为26.25 h时微生物功能基因总丰度最大,可见26.25 h是高原生境下A²/O工艺最佳HRT运行工况。     

Effects of labelled meaning on the affective quality of housing scenes

A series of studies examined the effects of labelled meaning on affective response to housing scenes. Students at Ohio State University assessed their feelings towards imagined housing (public or private) and cities (Memphis, Houston and San Francisco). Expected differences in the affective quality were found. Responses to color photographs of specific housing scenes labelled as either private condominiums or public housing were obtained. Differences in scene-affect as a function of labelled meaning were found. Responses to housing scenes labelled as located in either Memphis, Houston or San Francisco revealed no differences in scene-affect as a function of label meaning. This latter finding was confirmed in a non-repeated measure examination. Differences in the fittingness, potency or relevance of the information provided may account for the pattern of findings.