海洋大气环境下桥梁钢构件连接螺栓防腐技术研究

基于桥梁全寿命周期考虑,通过对包覆防腐、涂层防腐、密封胶与涂层联合防腐等常用防腐技术的防腐材料、施工工艺和防腐时效等进行了综合经济对比分析,得出氧化聚合型包覆防腐蚀技术具备防腐蚀材料先进性、施工质量可控性等优点,是桥梁钢构件连接螺栓的最优腐蚀防护方案。     

天山北坡城市群碳储量时空变化及预测研究

为了有效评估城市群碳储量变化,以天山北坡城市群为研究对象,运用PLUS模型和InVEST模型,动态评估2000～2020年及2030年不同情景下土地利用变化及碳储量变化特征.结果表明,2000～2020年天山北坡城市群碳储量呈现持续增加趋势,且碳储量变化与土地利用变化密切相关,主要表现为2000～2010年林地面积的减少导致其碳储量减少约266×106t,2010～2020年草地面积的增加使其碳储量增加约69.14×10⁶t.2030年自然发展情景、生态保护情景和经济快速发展情景下碳储量预测值分别为8875.88×10⁶t、8895.58×10⁶t和8841.58×10⁶t;经济快速发展情景下碳储量最低,生态保护情景下碳储量最高.土地利用是影响碳储量空间变化分布的第一主导因素,贡献率接近于90%,土地利用强度与碳储量协调性分析与两者双变量空间自相关分析进一步验证了这一结论.土地利用变化在一定程度上能够对碳储量产生积极影响,对于本研究区而言,生态保护发展情景可能更符合未来城市发展模式,研究结果能够为土...     

基于虚拟力的危化品仓储堆垛定位校正算法

超宽带定位技术作为一种室内高精度定位技术是解决危化品仓库堆垛贮存状态安全监测的有效方法,但在仓库非视距环境中,存在定位精度不足的问题,无法满足堆垛“五距”安全的监管要求。针对此问题,从UWB信号的信道模型和定位精度影响因素出发,利用高斯滤波消除了参考点在定位过程中由于系统和环境带来的随机误差影响,建立了参考点误差矢量库,并提出了一种虚拟力校正算法,利用建立的矢量库来对待测标签进行矢量补偿,达到提高定位精度的目的。实验表明,该方法可以提高危化品仓储堆垛定位精度,适用于监测危化品仓储状态。     

拱顶储罐气相层惰化过程数值模拟及工艺参数研究

针对油罐在检测、维修前须先将气相层可燃气体用氮气惰化到安全浓度,现场凭经验操作效率低且难以掌握氮气合理用量,容易造成氮气浪费或达不到安全浓度引发事故的问题,为确保惰化过程的安全经济,以常见拱顶储罐为例,首先利用改进后的公式法得出多组分可燃气体惰化效果评价指标;然后根据所得指标采用仿真对储罐气相层惰化过程进行数值模拟,并验证了仿真结果的正确性;最后采用仿真计算方法开展储罐气相层氮气惰化工艺参数的影响研究。研究结果表明:惰化效率与进口压力无关,只随进口流速变化,且大于1 m/s流速后,惰化效率已显著变化,此时可以增加进口管道数量,进一步提高惰化效率。理论研究结果可为现场实施提供参考和指导。     

Safety assessment of natural gas storage tank using similarity aggregation method based fuzzy fault tree analysis (SAM-FFTA) approach

Fault tree analysis (FTA) is an important method to analyze the failure causes of engineering systems and evaluate their safety and reliability. In practical application, the probabilities of bottom events in FTA are usually estimated according to the opinions of experts or engineers because it is difficult to obtain sufficient probability data of bottom events in fault tree. However, in many cases, there are many experts with different opinions or different forms of opinions. How to reasonably aggregate expert opinions is a challenge for the engineering application of fault tree method. In this study, a fuzzy fault tree analysis approach based on similarity aggregation method (SAM-FFTA) has been proposed. This method combines SAM with fuzzy set theory and can handled comprehensively diverse forms of opinions of different experts to obtain the probabilities of bottom events in fault tree. Finally, for verifying the applicability and flexibility of the proposed method, a natural gas spherical storage tank with a volume of 10,000 m³ was analyzed, and the importance of each bottom event was determined. The results show that flame, lightning spark, electrostatic spark, impact spark, mechanical breakdown and deformation/breakage have the most significant influence on the explosion of the natural gas spherical storage tank.     

对会计电算化环境下会计档案管理的思考

伴随着会计电算化工作在我国各企、事业单位中的普遍深入,会计电算化档案的管理工作面临着新的创新与发展.通过对会计电算化档案特点进行分析,介绍了在会计电算化环境下会计档案脱离于原计算机系统的收集方法、不同的信息载体存储介质及计算机软硬件环境下管理与保存、软件系统版本的不断升级对电算化会计档案的调阅利用.     

Water/acid gas interfacial tensions and their impact on acid gas geological storage

Acid gas geological disposal is a promising process to reduce CO₂ atmospheric emissions and an environment-friendly and economic alternative to the transformation of H₂S into sulphur by the Claus process. Acid gas confinement in geological formations is to a large extent controlled by the capillary properties of the water/acid–gas/caprock system, because a significant fraction of the injected gas rises buoyantly and accumulates beneath the caprock. These properties include the water/acid gas interfacial tension (IFT), to which the so-called capillary entry pressure of the gas in the water-saturated caprock is proportional. In this paper we present the first ever systematic water/acid gas IFT measurements carried out by the pendant drop technique under geological storage conditions. We performed IFT measurements for water/H₂S systems over a large range of pressure (up to P = 15 MPa) and temperature (up to T = 120 °C). Water/H₂S IFT decreases with increasing P and levels off at around 9–10 mN/m at high T (≥70 °C) and P (>12 MPa). The latter values are around 30–40% of water/CO₂ IFTs, and around 20% of water/CH₄ IFTs at similar T and P conditions. The IFT between water and a CO₂ + H₂S mixture at T = 77 °C and P > 7.5 MPa is observed to be approximately equal to the molar average IFT of the water/CO₂ and water/H₂S binary mixtures. Thus, when the H₂S content in the stored acid gas increases the capillary entry pressure decreases, together with the maximum height of acid gas column and potential storage capacity of a given geological formation. Hence, considerable attention should be exercised when refilling with a H₂S-rich acid gas a depleted gas reservoir, or a depleted oil reservoir with a gas cap: in the case of hydrocarbon reservoirs that were initially (i.e., at the time of their discovery) close to capillary leakage, acid gas leakage through the caprock will inevitably occur if the refilling pressure approaches the initial reservoir pressure.     

Life cycle assessment of a pulverized coal power plant with post-combustion capture, transport and storage of CO2

In this study the methodology of life cycle assessment has been used to assess the environmental impacts of three pulverized coal fired electricity supply chains with and without carbon capture and storage (CCS) on a cradle to grave basis. The chain with CCS comprises post-combustion CO₂ capture with monoethanolamine, compression, transport by pipeline and storage in a geological reservoir. The two reference chains represent sub-critical and state-of-the-art ultra supercritical pulverized coal fired electricity generation. For the three chains we have constructed a detailed greenhouse gas (GHG) balance, and disclosed environmental trade-offs and co-benefits due to CO₂ capture, transport and storage. Results show that, due to CCS, the GHG emissions per kWh are reduced substantially to 243 g/kWh. This is a reduction of 78 and 71% compared to the sub-critical and state-of-the-art power plant, respectively. The removal of CO₂ is partially offset by increased GHG emissions in up- and downstream processes, to a small extent (0.7 g/kWh) caused by the CCS infrastructure. An environmental co-benefit is expected following from the deeper reduction of hydrogen fluoride and hydrogen chloride emissions. Most notable environmental trade-offs are the increase in human toxicity, ozone layer depletion and fresh water ecotoxicity potential for which the CCS chain is outperformed by both other chains. The state-of-the-art power plant without CCS also shows a better score for the eutrophication, acidification and photochemical oxidation potential despite the deeper reduction of SO_x and NO_x in the CCS power plant. These reductions are offset by increased emissions in the life cycle due to the energy penalty and a factor five increase in NH₃ emissions.     

An engineering-economic model of pipeline transport of CO2 with application to carbon capture and storage

Carbon dioxide capture and storage (CCS) involves the capture of CO₂ at a large industrial facility, such as a power plant, and its transport to a geological (or other) storage site where CO₂ is sequestered. Previous work has identified pipeline transport of liquid CO₂ as the most economical method of transport for large volumes of CO₂. However, there is little published work on the economics of CO₂ pipeline transport. The objective of this paper is to estimate total cost and the cost per tonne of transporting varying amounts of CO₂ over a range of distances for different regions of the continental United States. An engineering-economic model of pipeline CO₂ transport is developed for this purpose. The model incorporates a probabilistic analysis capability that can be used to quantify the sensitivity of transport cost to variability and uncertainty in the model input parameters. The results of a case study show a pipeline cost of US$ 1.16 per tonne of CO₂ transported for a 100 km pipeline constructed in the Midwest handling 5 million tonnes of CO₂ per year (the approximate output of an 800 MW coal-fired power plant with carbon capture). For the same set of assumptions, the cost of transport is US$ 0.39 per tonne lower in the Central US and US$ 0.20 per tonne higher in the Northeast US. Costs are sensitive to the design capacity of the pipeline and the pipeline length. For example, decreasing the design capacity of the Midwest US pipeline to 2 million tonnes per year increases the cost to US$ 2.23 per tonne of CO₂ for a 100 km pipeline, and US$ 4.06 per tonne CO₂ for a 200 km pipeline. An illustrative probabilistic analysis assigns uncertainty distributions to the pipeline capacity factor, pipeline inlet pressure, capital recovery factor, annual O&M cost, and escalation factors for capital cost components. The result indicates a 90% probability that the cost per tonne of CO₂ is between US$ 1.03 and US$ 2.63 per tonne of CO₂ transported in the Midwest US. In this case, the transport cost is shown to be most sensitive to the pipeline capacity factor and the capital recovery factor. The analytical model elaborated in this paper can be used to estimate pipeline costs for a broad range of potential CCS projects. It can also be used in conjunction with models producing more detailed estimates for specific projects, which requires substantially more information on site-specific factors affecting pipeline routing.     

Prediction of phosphorus mobilisation in inundated floodplain soils

After flooding, iron reduction in riverine wetlands may cause the release of large quantities of phosphorus. As phosphorus is an important nutrient causing eutrophication in aquatic systems, it is important to have a tool to predict this potential release. In this study we examined the P release to the soil pore water in soil cores from floodplains in the Netherlands and from less anthropogenically influenced floodplains from Poland. During the inundation experiment, concentrations of P in the pore water rose to 2-90 times the initial concentrations. P release was not directly related to the geographic origin of the soils. An important predictor variable of P release was found in the ratio between the concentration of iron-bound P and amorphous iron. This ratio may provide a practical tool for the selection of new areas for wetland creation, and for impact assessment of plans for riverine wetland restoration and floodwater storage.