Subsea pipelines incidents prevention: A case study in Brazil

There are more than 4000 subsea pipelines in Brazil. These pipes include umbilicals, drilling risers, flexible risers, rigid risers, hybrid risers, flowlines, and export pipelines. Despite all standards, regulations, guides, and risk management tools designed to avoid events, subsea pipeline incidents still occur, revealing possible failures in companies' risk control. Identifying similarities between different subsea pipeline failure events is crucial to improving the design, risk management practices, and regulation requirements, besides promoting accident prevention. This paper proposes applying the life cycle and management practices combined to analyze subsea pipeline incidents from the RDI (Detailed Incident Report) and investigations reported to ANP (Brazilian National Agency of Petroleum, Gas, and Biofuels), the Brazilian safety regulatory agency. Furthermore, subsea pipeline incidents data were analyzed: correlated circumstances, consequences, and causes. The results show that most riser and flowlines causal factors are related to equipment failures, and recurrent root causes are design errors and integrity control. Based on the proposed approach, it was possible to identify gaps in most riser and flowlines accident investigations since there are few causal factors, root causes, and the absence of riser and flowlines failure mode and mechanisms. Therefore, the development of accident recommendations can be compromised. Thus, this paper proposes improvements to current Brazilian regulations to clarify the minimal subsea pipeline accident investigation requirements.     

Study on the preparation of novel FR-245/MCM-41 suppressant and its inhibition mechanism on oil shale deflagration flame

Oil shale development is of great significance because oil and gas resources are scarce. Research on the prevention of oil shale dust explosion is particularly important for guaranteeing the safe development and utilization of oil shale resources. In this work, the flame morphology and velocity of oil shale dust with and without MCM-41 or FR-245 were compared. Furthermore, the novel green FR-245/MCM-41 inhibitor was prepared by jet mill method and used in oil shale dust explosion for the first time. The best ratio of FR-245/MCM-41 for flame inhibition was obtained, which was 9: 1. The pyrolysis oxidation behavior of oil shale before and after adding FR-245/MCM-41 was analyzed and compared by FWO and KAS methods, respectively. The results showed that the activation energy calculated by FWO and KAS methods greatly increased after adding FR-245/MCM-41, which increased by 95.36% and 115.15% than that before adding inhibitor, respectively. Significantly, the activation energy is particularly high for two methods when α between 0.2 and 0.6, due to that MCM-41 and FR-245 coexisted to limit the oxidation of oil shale. For α between 0.7 and 0.9, the activation energy is still high because of the existence of MCM-41. Combining the oil dust flame propagation behavior with the characterization results before and after explosion, the physical-chemical synergy mechanism of oil dust flame propagation inhibition was revealed.     

油气田开发建设对土壤的影响与减缓措施

油气田开发和建设过程中排放的废水、废气和固体废物直接或间接进入土壤环境中,会对土壤生态系统产生影响,本文对油田开发污染物进入土壤的途径及其在土壤上吸附／解吸的规律的分析,提出相应的油田环境的保护和治理措施。     

Total Organic Carbon,an Important Tool in an Holistic Approach to Hydrocarbon Source Fingerprinting

The identification and allocation of multiple hydrocarbon sources in marine sediments is best achieved using an holistic approach. Total organic carbon (TOC) is one important tool that can constrain the contributions of specific sources and rule out incorrect source allocations in cases where inputs are dominated by fossil organic carbon. In a study of the benthic sediments from Prince William Sound (PWS) and the Gulf of Alaska (GOA), we find excellent agreement between measured TOC and TOC calculated from hydrocarbon fingerprint matches of polycyclic aromatic hydrocarbons (PAH) and chemical biomarkers. Confirmation by two such independent source indicators (TOC and fingerprint matches) provides evidence that source allocations determined by the fingerprint matches are robust and that the major TOC sources have been correctly identified. Fingerprint matches quantify the hydrocarbon contributions of various sources to the benthic sediments and the degree of hydrocarbon winnowing by waves and currents. TOC contents are then calculated using source allocation results from fingerprint matches and the TOCs of contributing sources. Comparisons of the actual sediment TOC values and those calculated from source allocation support our earlier published findings (Boehm et al ., 2001) that the natural petrogenic hydrocarbon background in sediments in this area comes from eroding Tertiary shales and associated oil seeps along the northern GOA coast and exclude thermally mature area coals from being important contributors to the PWS background due to their high TOC content.     

Tar Balls: The End State

Tar balls are frequently reported as an indicator of the extent of the impact of a spill incident. The determination of the density of tar balls is basic to the shoreline cleanup assessment team (SCAT) process, and is frequently used by the media as an indication of oil pollution. The processes involved in the evolution of tar balls are not well understood and there is a paucity of literature on the science of tar ball formation.     

废轮胎热解油脱色工艺研究

为解决废旧轮胎热解油颜色过深和存在异味而无法直接利用问题,文章采用活性炭对热解油吸附脱色工艺,将液相中含有的杂质、色素、异味等舍弃物吸附于活性炭表面上,以达到精致的目的。试验表明:热解油活性炭吸附脱色技术的最佳工艺条件为炭粒度550~1 700μm、脱色温度为室温、吸附时间为300 min、振荡频率为150 r/min。并证明了平2均孔径、中孔孔容积和中孔比表面积为26.4、0.307 m L/g和280 m/g的烟煤基活性炭对热解油具有很好的脱色能力。     

用陶瓷膜做滤材处理含油废水的研究

本实验是以无机膜之一的陶瓷做滤材，对含油污水处理进行研究．探讨了含油种类与膜的性质、含油浓度和透过速度的关系及反冲洗对透过速度的影响．通过实验证明：轻质油比重油的透过速度大；油水中含油浓度对透过浓度影响不大；反冲洗会使透过速度得到恢复；浊度去除率可达９６％以上，陶瓷膜超滤法处理含油废水是可行的．     

Regional resource management techniques: The case of Colorado oil shale development

Regions under stress from rapid development require comprehensive planning and management tools, capable of identifying the pace, location and magnitude of growth and assessing social, economic and environmental impacts. Northwest Colorado, endowed with massive rich deposits of oil shale, went through a boom-bust cycle of growth during the early 1980s as US interest in synthetic fuels peaked and then rapidly declined. An innovative resource information system has been developed which has assisted the region in anticipating growth and modifying its consequences. This article reviews the organization and development of the Colorado Resource Information System (CRIS) and evaluates its role and impact in the decisionmaking process. Experience shows that regions which develop and maintain planning and information tools can have significant influence on economic development.     

Jordan,minerals extraction and the resource curse

In its role as a competitive producer of phosphate and potash Jordan has not suffered noticeably from the Resource Curse over the past 50 years. However, the effects on its economy because of its geographical proximity to major oil-producing states have been both positive and negative. It is arguable that an oil resource curse has applied to Jordan.     

基于突变理论的国内外火灾科学研究进展和展望

简要归纳了突变模型的特征和突变理论的应用方式,重点综述了突变理论在火灾科学中的应用情况,概括了突变理论在火灾科学中三个应用特点。针对具体油气爆炸实验数据,利用随机突变理论,对油气爆炸的突变模式进行了初步研究,说明了建立统计突变模型的可行性。最后指出了突变理论应用于火灾科学的未来研究方向。