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861.
Modeling and interpreting bioavailability of organic contaminant mixtures in subsurface environments
Bioavailability often controls the fate of organic contaminants in surface and subsurface aquatic environments. Bioavailability can be limited by sorption, mass transfer, and intrinsic biodegradation potential and can be further altered by the presence of other compounds. This paper reviews current perspectives on the processes influencing subsurface contaminant bioavailability, how these processes are modeled, and how the relative role of the various processes can be assessed through bioavailability indices. Although these processes are increasingly well understood, the use of sophisticated models and indices often are precluded by an inability to estimate the many parameters that are associated with complex models. Nonetheless, the proper representation of sorption, mass transfer, biodegradation, and co-solute effects can be critical in predicting bio-attenuation. The influence of these processes on contaminant fate is illustrated with numerical simulations for the simultaneous degradation of toluene (growth substrate) and trichloroethylene (nongrowth cometabolite) in hypothetical, aerobic, solid-water systems. The results show how the relative impacts on contaminant fate of the model's various component processes depends upon system conditions, including co-solute concentrations. Slow biodegradation rates increase the inhibition effects of a cometabolite and suppress the rate enhancement effects of a growth substrate. Irrespective of co-solute effects, contaminant fate is less sensitive to biodegradation processes in systems with strong sorption and slow desorption rates. Bioavailability indices can be used to relate these findings and to help identify appropriate modeling simplifications. In general, however, there remains a need to redefine such indices in order that bioavailability concepts can be better incorporated into site characterization, remediation design, and regulatory oversight. 相似文献
862.
This is a study of the scientific component of an effort to restore an urban river by removing a low-head dam. The Secor Dam
is owned by a local government entity near Toledo, Ohio. The proposed removal of the last structure impeding flow on the Ottawa
River has broad appeal, but the owner is concerned about liability issues, particularly potential changes to the flood regime,
the presence of contaminated sediments behind the dam, and possible downstream transport of reservoir sediments. Assessing
sediment contamination involved sediment sampling and analysis of trace metals and organic contaminants. Forecasting sediment
transport involved field methods to determine the volume and textural properties of reservoir and upstream sediment and calculations
to determine the fate of reservoir sediments. Forecasting changes in the flood regime involved HEC-RAS hydrological models
to determine before and after dam removal flood scenarios using LiDAR data imported into an ArcGIS database. The resulting
assessment found potential sediment contamination to be minor, and modeling showed that the removal of the dam would have
minimal impacts on sediment transport and flood hazards. Based on the assessment, the removal of the dam has been approved
by its owners. 相似文献
863.
论述了几种常用总氮、总磷分析方法的原理和特点,运用准确度和精密度检验,比较了它们各自对不同有机氮、磷物质和有机污染水体的分析结果。实验结论表明,加和法和还原法不能满足一般方法要求;氧化法具有较高的准确度和精密度,实用性强,建议推广。 相似文献
864.
介绍了常用固相萃取剂的类型与适用范围,综述了近年来在极性有机污染物富集检测中获得应用的新型固相萃取剂,包括具有高比表面积和亲水表面的聚合物萃取剂,以及利用分子印迹和免疫亲和技术制备的新型萃取剂。 相似文献
865.
866.
用臭氧氧化处理镀镍漂洗废水中的有机物,主要考察pH、臭氧投加量、废水初始COD浓度、温度等因素对处理效果的影响,并对反应机理进行初步的探讨.实验结果表明,废水的COD去除率随pH的增大而升高,比较适宜的pH为6~7;适当地增加臭氧投加量有利于提高COD去除率;在一定温度范围(15~35℃)内,提高反应温度有利于废水中有机物的降解;当臭氧投加量为20 mg/(min·L),对于初始COD为56 mg/L、pH 6.5的实际镀镍漂洗废水,在25 ℃的条件下氧化100min,出水COD降至10mg/L,COD去除率达到82%;在臭氧氧化镀镍漂洗废水的反应中,部分有机物的降解是在Ni2 的催化下由臭氧分解生成氧化能力更强的自由基来完成.臭氧氧化可作为镀镍漂洗废水处理回用的预处理工艺. 相似文献
867.
Summer time haze characteristics of the urban atmosphere of Gwangju and the rural atmosphere of Anmyon, Korea 总被引:4,自引:0,他引:4
An extensive visibility monitoring was carried out simultaneously in the urban area of Gwangju and the rural area of Anmyon,
Korea. This study examines patterns of visibility impairment and haze-forming pollutant concentrations on both sites resulting
from natural and anthropogenic sources of gases and particles. Optical visibility measurements by a transmissometer, a nephelometer
and an aethalometer provide aerosol light extinction, scattering, and absorption coefficients for both sites. In order to
investigate the physico-chemical characteristics of atmospheric aerosols, aerosol samples were collected by various aerosol
samplers at GJVMS (Gwangju Visibility Monitoring Station) and at KGAWO (Korea Global Atmosphere Watch Observatory), respectively.
In addition, haze characteristics causing visibility impairment at those two sites were analyzed to obtain source contributions
by regionally transported aerosols using grid analysis and display system (GrADS) from NECP reanalysis data. During the intensive
monitoring period, ammonium sulfate was dominantly responsible for the fine particle mass loading at GJVMS, whereas organic
carbon was the largest contributor at KGAWO. Light scattering by particles accounted for 52.8 to 81.3% of the range at the
urban site, GJVMS and for 72.1 to 94.2% of the range at the rural site, KGAWO. Light absorption by the EC and NO2 was between 14.5 and 34.8% at GJVMS, which was higher than the observed 1.1 ∼ 6.8% at KGAWO, respectively. Light scattering
by aerosol was higher in the rural area than in the urban area. And organic carbon concentration was observed to be significantly
higher than the concentration of elemental carbon at KGAWO. These haze-forming carbonaceous particles originate from anthropogenic
pollutants at the urban atmosphere but they can be produced by natural environments such as marine and forest at the rural
atmosphere. 相似文献
868.
中国地表饮用水水源地有机类内分泌干扰物污染现况分析 总被引:2,自引:0,他引:2
有机类内分泌干扰物(EDCs)是一类对人类和生物内分泌系统产生干扰,并可造成其紊乱的特殊外来物质,对人类和生物健康有极大的危害.以与人类生活密切相关的地表饮用水水源地中的有机类EDCs为研究重点,对中国目前地表饮用水水源地EDCs污染状况、污染物种类及其来源及可能的污染途径进行了评述.目前,中国各地区地表饮用水水源地均有有机类EDCs检出.其中以有机氯农药六六六及其异构体、DDT及其代谢产物和多氯联苯检出率最高,且某些地区检测浓度相当高,主要来源是农药使用和污水排放.国内外对地表饮用水水源地EDCs突发污染事件的研究均较少,应引起高度重视. 相似文献
869.
水中有机污染物电化学清除的研究进展 总被引:14,自引:0,他引:14
介绍利用直接电解发、间接电解和电化学吸附等方法去除水中有机污染物的研究现状,并指出今后的工作方面。 相似文献
870.