溶胶凝胶法制备铜催化剂及其稳定性的研究

介绍了利用溶胶凝胶方法制备铜系催化剂，并考察了制备过程中各个工艺参数对铜系催化剂稳定性的影响。通过优化催化剂的设计和制备方法，可有效地改善Cu^2＋的溶出问题，使该类催化剂具有广阔的应用前景。     

CO2 storage capacity estimation: Methodology and gaps

Implementation of CO₂ capture and geological storage (CCGS) technology at the scale needed to achieve a significant and meaningful reduction in CO₂ emissions requires knowledge of the available CO₂ storage capacity. CO₂ storage capacity assessments may be conducted at various scales—in decreasing order of size and increasing order of resolution: country, basin, regional, local and site-specific. Estimation of the CO₂ storage capacity in depleted oil and gas reservoirs is straightforward and is based on recoverable reserves, reservoir properties and in situ CO₂ characteristics. In the case of CO₂-EOR, the CO₂ storage capacity can be roughly evaluated on the basis of worldwide field experience or more accurately through numerical simulations. Determination of the theoretical CO₂ storage capacity in coal beds is based on coal thickness and CO₂ adsorption isotherms, and recovery and completion factors. Evaluation of the CO₂ storage capacity in deep saline aquifers is very complex because four trapping mechanisms that act at different rates are involved and, at times, all mechanisms may be operating simultaneously. The level of detail and resolution required in the data make reliable and accurate estimation of CO₂ storage capacity in deep saline aquifers practical only at the local and site-specific scales. This paper follows a previous one on issues and development of standards for CO₂ storage capacity estimation, and provides a clear set of definitions and methodologies for the assessment of CO₂ storage capacity in geological media. Notwithstanding the defined methodologies suggested for estimating CO₂ storage capacity, major challenges lie ahead because of lack of data, particularly for coal beds and deep saline aquifers, lack of knowledge about the coefficients that reduce storage capacity from theoretical to effective and to practical, and lack of knowledge about the interplay between various trapping mechanisms at work in deep saline aquifers.     

纳米TiO2治理室内甲醛的实验研究

利用纳米材料TiO2对室内甲醛进行了治理研究。测定了TiO2在不同吸附剂量、吸附时间时的吸附效率、穿透时间和吸附容量。将TiO2、活性炭对甲醛的吸附效果进行了对比，结果表明，纳米材料TiO2对甲醛的吸附率比相同质量的活性炭高10％-15％；当吸附时间为13h时，TiO2对甲醛的吸附量比活性炭高28％；穿透时间比活性炭长2h。利用SEM图谱进行了机理分析。     

Air quality assessment along Dhanbad - Jharia road

Road ambient air pollution status along Dhanbad – Jharia road isstudied and presented in this article. The selection of this areais made considering the importance of the road in Dhanbad district and the nature of activities taking place along the road, which reflect that the portion of road upto Dhansar can be considered as having commercial areas on both sides and that from Dhansar to Jharia as having industrial areas on both sides.For the assessment of the ambient air quality along the road monitoring is done at the following five locations: Indian Schoolof Mines (ISM), main gate; Bankmore; Dhansar police check post; Dhansar opencast project agent office and a residential house beside the Rajapur opencast project. The location of ISM, maingate is specially chosen as this represents a commercial shoppingcomplexes and the situation can be compared with that at Bankmore. Monitoring of ambient air quality is done following thestandard procedure prescribed in IS: 5182. In addition the concentration of lead, zinc, copper, iron, manganese, cadmium metals in SPM is also monitored. The ambient air quality is monitored in the months of September and November 1999, respectively, to represent monsoon and winter seasons. The SPM concentration observed at all the five locations in the winterseason is more than the permissible limits for commercial andindustrial areas. However, in the monsoon season, the SPM concentration is higher than the permissible limit at the twocommercial locations, i.e., ISM gate and Bankmore, while it isless than the prescribed limit for industrial areas at the remaining three locations. At the ISM gate and Bankmore the SPM generation is mainly by vehicular traffic while at other three locations it was in addition due to mining and other activities.     

Dynamic of functional microbial groups during mesophilic composting of agro-industrial wastes and free-living (N2)-fixing bacteria application

Although several reports are available concerning the composition and dynamics of the microflora during the composting of municipal solid wastes, little is known about the microbial diversity during the composting of agro-industrial refuse. For this reason, the first parts of this study included the quantification of microbial generic groups and of the main functional groups of C and N cycle during composting of agro-industrial refuse. After a generalized decrease observed during the initial phases, a new bacterial growth was observed in the final phase of the process. Ammonifiers and (N₂)-fixing aerobic groups predominated outside of the piles whereas, nitrate-reducing group increased inside the piles during the first 23 days of composting. Ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB), showed an opposite trend of growth since ammonia oxidation decreased with the increase of the nitrite oxidation activity. Pectinolytics, amylolytics and aerobic cellulolytic were present in greater quantities and showed an upward trend in both the internal and external part of the heaps.Several free-living (N₂)-fixing bacteria were molecularly identify as belonging especially to uncommon genera of nitrogen-fixing bacteria as Stenotrophomonas, Xanthomonas, Pseudomonas, Klebsiella, Alcaligenes, Achromobacter and Caulobacter. They were investigated for their ability to fix atmospheric nitrogen to employ as improvers of quality of compost. Some strains of Azotobacter chrococcum and Azotobacter salinestris were also tested. When different diazotrophic bacterial species were added in compost, the increase of total N ranged from 16% to 27% depending on the selected microbial strain being used. Such microorganisms may be used alone or in mixtures to provide an allocation of plant growth promoting rhizobacteria in soil.     

Rehabilitation of a lowland river: Reconciling flood defence with habitat diversity and geomorphological sustainability

Geomorphologically appropriate rehabilitation measures were proposed to enhance the in-stream environment of the lowland River Idle, north Nottinghamshire, UK. However, the River Idle has multi-functional management requirements including those of flood defence so environmental enhancement must be pursued without significantly increasing the flood risk. Hydraulic testing of rehabilitation proposals is complicated because of the stringent assumptions about flow and morphology in ‘traditional’ hydraulic models. While new generation two- and three-dimension hydraulic models may overcome some of these problems, they are extremely data intensive, require advanced modelling capabilities and are, therefore, very expensive to apply. Also, they do not yet predict morphology-flow interactions adequately. As an alternative, several simple hydraulic models were applied to test the rehabilitation proposals, based on a fitness-for-purpose criterion.BENDFLOW was applied to fine tune the optimal siting of measures and to estimate the additional near-bank scour generated by proposed bend re-profiling. HMODEL2 and the FCFA method were used to test the impact on local channel conveyance capacities and HECRAS was applied to simulate the impact of the proposals on regional flood defence. Indicative results from the testing suggested a maximum increase in near-bank scour of 0·15 m in re-profiled bends, a loss of approximately 10% in flood conveyance locally due to deflector installation or reed and tree planting, and a 0·12 m increase in flood stage within the reach for a 15 year flood. The modelling results were acceptable to the management authority as an indication of an acceptable compromise between flood defence and conservation interests, and construction of the measures followed in 1996. It is clearly that it will require the results of post-project monitoring to indicate whether compromises made to the rehabilitation initiatives in order to satisfy flood defence requirements have unduly reduced their environmental enhancement potential but, for assessing the proposed methods, the models are recommended for use other lowland river environments.     

基于社会网络分析的江西各地市公路行业碳排放的关联与分异特征研究

针对各地公路碳排放的空间差异与关联特征，制定合理的低碳策略，实现各地协同碳减排，是行业可持续发展的热点问题。以江西省为研究对象，采用空间自相关、社会网络分析和引力模型等分析11地市公路行业碳排放的空间差异与关联，识别社会网络的结构特征及其演变趋势，明确不同地市在网络中的地位和作用，结果显示：（1）公路货运是公路行业碳排放的最主要来源；（2）江西省公路行业碳排放整体上呈现空间随机分布，不存在全局的空间聚集性，且局部空间聚集特征不断变化；（3）公路行业碳排放网络逐渐从南昌、新余双中心结构演变为南昌为主的单中心结构，网络的协同作用整体呈减弱趋势，核心地市对外围地市的影响力和带动作用不足。     

Elevated CO2 facilitates C and N accumulation in a rice paddy ecosystem

Elevated CO2 can stimulate wetland carbon(C) and nitrogen(N) exports through gaseous and dissolved pathways, however, the consequent influences on the C and N pools are still not fully known. Therefore, we set up a free-air CO2 enrichment experiment in a paddy field in Eastern China. After five year fumigation, we studied C and N in the plant–water–soil system. The results showed:(1) elevated CO2 stimulated rice aboveground biomass and N accumulations by 19.1% and 12.5%, respectively.(2) Elevated CO2 significantly increased paddy soil TOC and TN contents by 12.5% and 15.5%, respectively in the 0–15 cm layer, and22.7% and 26.0% in the 15–30 cm soil layer.(3) Averaged across the rice growing period,elevated CO2 greatly increased TOC and TN contents in the surface water by 7.6% and 11.4%,respectively.(4) The TOC/TN ratio and natural δ15N value in the surface soil showed a decreasing trend under elevated CO2. The above results indicate that elevated CO2 can benefit C and N accumulation in paddy fields. Given the similarity between the paddies and natural wetlands, our results also suggest a great potential for long-term C and N accumulation in natural wetlands under future climate patterns.