The solution phase complexing of atrazine by fulvic acid: Equilibria at 25°c

Abstract

The solution phase complexing equilibria of atrazine by fulvic acid at 25°C±1.° have been investigated over the pH range of 1.3 to 6.0. Experiments with 0.1MKC1 and chelated Cu(II) are compared with those without metal ions. The use of a fulvic acid having calibrated acidic and Cu(II) chelation properties has made it possible to obtain stoicheometricly “exact”; chemical information. This is correlated with previous hydrolysis kinetics work. It is concluded that atrazine is hydrogen bonded in a labile equilibrium, to an identifiable set of protonated carboxyl groups, which act as Brönsted acid catalysts for hydrolysis. 0.1M KC1 changes (1‐α_A), the degree of protonation of the carboxyl groups, without otherwise affecting the atrazine complexing. Cu(II) chelation both reduces and weakens the complexing through a combination of carboxyl group blocking, and fulvic acid aggregation. Simple equations are presented for predictive calculations.     

Revealing the effect of preparation parameters on zeolite adsorption performance for low and medium concentrations of ammonium

The effect of preparation parameters on the performance of zeolite for ammonium(20–300 mg N/L) adsorption from simulated wastewater is reported. It was found that the ratios of Na_2O/SiO_2 and Si/Al had a more important influence than crystallization time on zeolite adsorption properties. Relatively low Na_2O/SiO_2 ratios were beneficial for fabrication of zeolites with high proportions of micropore area and volume, which led to the surface adsorption mechanism being dominated by surface free energy and pore effects. However,with decreasing Si/Al ratios, the effect of ion-exchange was more prominent due to the high negative surface potential of zeolite. In addition, the concentration of weak acid sites on the zeolites was increased with lower ratios of Na_2O/SiO_2 and Si/Al, which may promote ammonium removal. Therefore, the most effective zeolite for ammonium removal, which was fabricated at Na_2O/SiO_2= 1.375, Si/Al = 4 and crystallization time of 48 hr, exhibited the cooperative effects of adsorption, ion-exchange and a large amount of weak acid sites. The maximum ammonium adsorption capacity(35.06 ± 0.98 mg/g) and the removal efficiency(94.44% ± 4.00%) were obtained at the dosage of 4.0 g/L zeolite NaX at ammonium concentrations of 300 mg N/L and 20 mg N/L, respectively. The Freundlich isotherm and pseudo-first-order kinetics models provided excellent fitting for the ammonium adsorption process. In addition, zeolite NaX showed about 1.23–3.2 times the ammonium adsorption capacity of clinoptilolite. The stable and efficient reusability of zeolite NaX after five regeneration cycles demonstrated that this adsorbent has considerable potential for practical industrial applications.     

Dancing Stories: A Community Dance Residency in a Hospice in New Zealand

Canoes forging through cold waters, mountains rising from the sea, a heart beating under a mountain lake, an albatross sailing toward the Antarctic: these were the story-images of Coastal Mappings, a large-scale community project set in and around Dunedin, New Zealand. In the Coastal Mappings performance project, people in the last months of their lives joined cancer survivors, family members and other interested people in explorations of Pakeha myths (by European-settler descendents) and Maori myths (by descendents of the crews of the first canoes, first inhabitants of New Zealand). Together, we created personal landscapes through movement, storytelling, photography and video. In this essay, I discuss some of the opportunities, challenges and experiences of leading a community dance project in an intercultural social environment, and with people whose relationship to their environment is different from mine.     

海洋水质在线监测系统中硝酸盐测量方法比较

硝酸盐是海洋水质监测的重要指标,目前在海洋水质在线监测系统中搭载的硝酸盐在线分析仪的种类较多,采用的测量原理也不尽相同.选取了 3种采用不同测量方法的代表性硝酸盐分析仪[氯化钒还原比色法硝酸盐分析仪、二乙烯三胺五乙酸还原比色法(DTPA)硝酸盐分析仪、紫外分光光度法硝酸盐分析仪],结合各自的测量原理、化学试剂特性等,就...     

Measuring Road Traffic Safety Performance: Monitoring Trends in Nonfatal Injury

Traditional indicators used to monitor trends in nonfatal injury are influenced by a range of factors other than the incidence of injury. Indicators based on threat-to-life scales offer a means of addressing this problem. The aim of the research described in this article was to compare trends in the official indicators with trends in selected threat-to-life indicators. We compared indicators based on the New Injury Severity Score and the International Classification of Diseases–based Injury Severity Score with the official New Zealand indicators; namely, (1) reported injuries, (2) reported injuries per 10,000 vehicles, (3) reported injuries per 100,000 people, and (4) number hospitalized (discharges). All the official indicators suggest that there has been a substantive decline in nonfatal Motor Vehicle Traffic Crashes (MVTCs) for the period 1988–2000, but a notable increase in 2001. The latter appear to be artifactual increases due to changes in patterns of data collection and do not reflect any real changes in incidence. Further support for this is provided by the results for the two threat-to-life indicators, which suggest that the decline observed for 1988–98 may have been attributable to a decline in the ascertainment or occurrence of minor injuries since those injuries, which represent a significant threat to life, have not declined to the same degree. Given the prominence of motor vehicle crashes as a cause of unnecessary morbidity, more thought needs to be given to deriving valid indicators for measuring trends in serious nonfatal injury.     

Metals removal from aqueous solution by iron-based bonding agents

GOAL AND SCOPE AND BACKGROUND: The application of a promising method, termed sorptive flotation, for the removal of chromium(VI) and zinc ions was the aim of the present paper. A special case of sorptive flotation is adsorbing colloid flotation. Suitable sorbent preparation techniques have been developed in the laboratory. METHODS: Sorptive flotation, consisting of the sorption and flotation processes combined in series, has proved to give fast and satisfactory treatment of the industrial streams and effluents bearing dilute aqueous solutions of zinc and chromium(VI). RESULTS AND DISCUSSION: Goethite has proved to be effective for the removal of chromium(VI) and zinc ions. Also, adsorbing colloid flotation with ferric hydroxide (as the co-precipitant) could be an alternative method to the above-mentioned separation of metal ions. In both cases, chromium(VI) (pH=4) and zinc (pH=7) removal was about 100%. CONCLUSION: The reasons for selecting the iron-based bonding materials, like goethite and/or in-situ produced ferric hydroxide, are that they are cheap, easily synthesized, suitable both for cation and anion sorption, and, furthermore, that they present low risks for adding a further pollutant to the system. Promising results were obtained. RECOMMENDATION AND OUTLOOK: The application of goethite and in-situ produced ferric hydroxide has demonstrated their effectiveness in the removal of heavy metal ions, such as chromium anions and zinc cations. A proposed continuation of current work is the utilization of similar iron oxides, for instance synthesized akaganeite. The comparison between the results reported in this paper with the results reported in the literature, also deserves attention.     

飞机风挡防(除)雾系统安全性能分析

飞机的风挡防（除）雾对飞行安全具有十分重要的意义。为此,重点研究飞机风挡内表面热气防（除）雾系统的性能,针对自由射流热空气防（除）雾系统,建立了其稳态安全性能评判模型,并以某型飞机风挡为例,在两种供气条件下,分析和计算了系统的结雾情况,根据综合分析得出结论     

铝锂合金在航空业的应用及SPF/DB工艺进展

简述了铝锂合金材料在航空制造中的应用 ,并对其超塑性成形及扩散连接工艺的最新进展作了简要的介绍     

新型汽车尾气净化催化剂的适应性能

研制了一种新的汽车尾气净化催化剂。其贵金属以Ｐｔ，Ｐｄ为主活性组分，载体以堇青石陶瓷蜂窝体涂复天然沸石粉，经测定，催化剂净化汽车尾气的活性，热稳定性，及抗铅，中毒等性能均较好，台架试验表明，催化箱对ＨＣ和ＣＯ均有很高的净化效果，ＨＣ转化率≥８５％，ＣＯ转化率≥９１％，并且该催化剂具有良好的冷起动性能。     

不同有机负荷下活性污泥特性若干问题的探讨

从活性污泥的性能对废水的处理效果及曝气量等方面,分析了实际运行中不同有机负荷下活性污泥的特性,同时对污泥膨胀的原因以及运行管理中采取的控制措施进行进一步的探讨.