Application of CFD model in an LPG tank explosion accident

In this research, a 3D tank farm model of a petrochemical plant was built in order to analyze an LPG tank explosion accident. Furthermore, the Computational Fluid Dynamic (CFD) algorithm was also applied to reconstruct the scenario of the accident. With its 3D dynamic abilities, the CFD simulation results can be used to facilitate the understanding of the spatial and transient distribution of different hazardous physical variables, which cannot be observed from the traditional methods.After the maximum physical variables of overpressure, pressure-impulse, and thermal radiation temperature were calculated, the results were adopted to estimate the corresponding 3D individual risk value. With the aid of the CFD simulation and the analysis method of maximum physical variable, the researchers can use the simulation results to scrutinize the possible causes and consequences of a chemical accident.     

上海石化近岸海床冲淤特征与海堤稳定性分析

运用GIS对2000~2013年上海石化近岸海床冲淤特征、机制及海堤稳定性进行研究。结果表明:(1)2000~2013年海床大范围为淤积区,但金山深槽冲刷强度较大。其中,2000~2004、2004~2008年以冲刷为主,年均净冲刷速率为5.27 cm和10.52 cm;2008~2012年以淤积为主,年均净淤积速率为8.50 cm;2012~2013年冲淤较稳定,稳定区占总面积的76.04%;(2)8个断面北岸及深槽中部(断面Ⅴ)地形较稳定,但在深槽西部(断面Ⅰ和Ⅱ)和东部(断面Ⅶ和Ⅷ)南侧冲刷;离岸15m以浅海床以淤积为主;(3)海堤稳定评估中,第六次围堤岸段稳定性较低。总之,海床的冲刷与金山涨潮冲刷槽补沙机制的丧失有关,同时城市沙滩、南汇促淤等工程也有影响,新一轮涉水旅游项目正在开发中,需密切关注。     

哈希在线分析仪在石化废水COD测定中的应用

介绍了美国哈希公司COD在线分析仪的工作原理、仪器结构与测量步骤,以及在中石化金陵分公司污染源在线监测系统中的应用.分析了仪器常见故障产生的原因与排除方法,提出应注重仪器的日常运行检查,采取相应的质量控制措施,确保自动监测数据的有效性.     

Relation between senior managers’ safety leadership and safety behavior in the Chinese petrochemical industry

Senior managers in organizations are authorized and obliged to maintain organizational safety. However, to date, little research has considered the relation of senior managers' safety leadership to safety behavior. This study addresses this gap by using path analysis to confirm the validity of a hypothetical model that relates six dimensions of senior managers' safety leadership to two safety behaviors through the safety climate in the petrochemical industry. A questionnaire survey was sent randomly to workers (other than senior managers) in two petrochemical companies in China, and data from 155 usable responses were compiled for the path analysis. Results indicate that in the petrochemical industry, senior managers' safety leadership has a positive impact on safety behavior, and the safety climate plays an intermediary role between them. From the perspective of the dimensions of senior managers' safety leadership and safety behavior, safety concern has the greatest positive effect on safety compliance. Moreover, safety vision has the greatest positive impact on safety participation, whereas safety inspiration and safety awards and punishment have negative effects on safety compliance. Personal character does not directly influence any dimension of safety behavior but indirectly does so by influencing the safety climate. On the basis of these results, measures of improving senior managers' safety leadership in the petrochemical industry are presented to help improve the overall safety performance of the industry. A new view is provided for the petrochemical industry in China to suggest that senior managers’ safety leadership can be treated earnestly.     

有关化工石化建设项目环境风险评价技术评估的探讨

根据国家化工石化行业建设项目加强环境风险评价的主要规定,结合化工石化行业建设项目特点及环境影响技术评估,反思化工石化项目评价及评估工作,重点从环境风险评价方面,对进一步完善环境风险评价与防范的后评估,从严建设项目技术评估与环境管理等进行了初步探讨,目的是为建设项目环境影响技术评估和环境管理提供参考。     

最小生成树法在环境背景值识别中的应用

本文用最小生成树法解决环境中的聚类分析问题。该法用x~2距离系数矩阵描述样本变量间的相似关系,同时用Kruskal法构造最小生成树,最后以分类图的形式给出分类结果。     

水幕隔尘用缝隙喷口的边界流线构造与出流速度分布

为解决常规水幕除尘装置阻隔巷道或隧道的问题,基于势流叠加原理,推导缝隙喷口边界流线方程,构造喷口流线型边界线。在SolidWorks中利用流线型边界线形成二维面,拉伸得到三维结构;针对该喷口及现有锥形缝隙喷口,采用CFD软件中的Realizable k-ε湍流模型,完成内部流场的数值模拟。研究结果表明：入水口附近存在流动分离,该分离影响出水端速度衰减快慢;相比常规锥形喷口,流线型缝隙喷口的内部流场稳定性提高,全段出流曲线上出流速度离散程度下降46.98%,等速核心区离散程度下降42.93%,研究结果可用以指导水幕隔尘用缝隙喷口的研发。     

石化污水处理场排放废气中有机污染的分析与评价

采用预浓缩、气相色谱-质谱联用及脉冲火焰光度检测的方法对石化污水处理场排放的废气污染物进行了定性与定量分析,并采用相应的污染物排放标准及其人体感知嗅阈值进行了污染程度评价.结果表明,污水处理场在各个采样点位均有挥发性有机污染物和恶臭污染物检出,其中以污水进口最为严重.从检出物的浓度水平而言,苯系物和恶臭污染物均存在超标现象,而且检出的恶臭污染物浓度水平远高于人体感知嗅阈值.     

大型石化项目环境监理实践及工作方法探讨

基于某大型石化项目的环境监理实践,从环境监理方案及实施细则的编制、设计阶段环境监理、施工阶段环境监理3个方面阐述此类项目环境监理的要点及工作方法。设计阶段的主要工作是对环保设计文件、设计图纸及基础设计资料等材料的审查,审查的重点是项目的平面布置、生产规模、工艺路线、污染物特征及各污染物控制节点、环保治理设施的处理工艺及规模等与环评报告及批复的相符性。施工阶段环境监理的工作重点是施工单位环境管理、施工期环保达标监理、隐蔽工程监理、环境风险防范措施监理、环保设施符合性核查、批建相符性核查等几方面。并简要分析了环境监理成果的体现方式。