Phosphate removal from domestic wastewater using thermally modified steel slag

This study was performed to investigate the removal of phosphate from domestic wastewater using a modified steel slag as the adsorbent. The adsorption effects of alkalinity, salt, water,and thermal modification were investigated. The results showed that thermal activation at 800℃ for 1 hr was the optimum operation to improve the adsorption capacity. The adsorption process of the thermally modified slag was well described by the Elovich kinetic model and the Langmuir isotherm model. The maximum adsorption capacity calculated from the Langmuir model reached 13.62 mg/g. Scanning electron microscopy indicated that the surface of the modified slag was cracked and that the texture became loose after heating. The surface area and pore volume did not change after thermal modification. In the treatment of domestic wastewater, the modified slag bed(35.5 kg) removed phosphate effectively and operated for 158 days until the effluent P rose above the limit concentration of 0.5 mg/L. The phosphate fractionation method, which is often applied in soil research, was used to analyze the phosphate adsorption behavior in the slag bed. The analysis revealed that the total contents of various Ca–P forms accounted for 81.4%–91.1%, i.e., Ca10–P 50.6%–65.1%, Ca8–P 17.8%–25.0%,and Ca2–P 4.66%–9.20%. The forms of Al–P, Fe–P, and O–P accounted for only 8.9%–18.6%. The formation of Ca10–P precipitates was considered to be the main mechanism of phosphate removal in the thermally modified slag bed.     

外源水对碳酸盐侵蚀速率研究——以桂林毛村地下河为例

本文对桂林毛村地下河流域,进行了野外监测与室内分析研究,详细研究了外源水与岩溶水对碳酸盐岩侵蚀速率差异。研究结果表明,碳酸盐岩在岩溶水与外源水中的侵蚀速率存在较大差异,雨季碳酸盐岩侵蚀速率:外源水外源水补给的岩溶水岩溶水空气;旱季碳酸盐岩溶蚀速率:外源水外源水补给的岩溶水空气岩溶水;外源水中的灰岩侵蚀速率白云岩侵蚀速率;碳酸盐岩试块的侵蚀速率具有明显的季节变化,主要受控于方解石饱和指数、pH值与水动力条件。     

综放工作面覆岩破坏特征及裂隙演化相似模拟试验研究

针对煤层开采后常出现矿压显现剧烈、煤岩透气性增大和地表下沉等问题,利用二维相似模拟试验研究综放工作面覆岩破坏特征并通过分形理论表征裂隙演化规律.试验结果表明:煤层基本顶初次来压步距为78 m,周期来压步距为24 m;煤层采动裂隙发育,距煤层顶板超过35 m;煤层开采后形成的覆岩裂隙具有分形特征,其分形维数随工作面的推进...     

成都施用磷肥中镭（^226Ra）含量调查及对农田环境影响评价

本文报道了成都磷肥及其原料矿石中外照射剂量水平；用国家标准规定的方法测定了磷肥及其矿石中＾２２６Ｒａ含量；调查了同一生产厂家不同批号磷肥中＾２２６Ｒａ含量变化情况；估算出施用磷肥后可能带来的放射性环境污染，并对磷肥中＾２２６Ｒａ可能导致的农田环境影响作了简要评价? ?     

基于力电耦合冲击矿压电磁辐射预测法的研究

笔者首先提出了煤岩变形破裂过程电磁辐射与应力耦合的概念 ,然后在实验研究、理论分析和数值模拟的基础上从力电耦合的角度研究了煤岩冲击矿压预测的电磁辐射法 (EME)。研究结果表明 :FLAC3D方法能对矿山巷道掘进过程煤岩内部应力场进行有效的数值模拟 ;电磁辐射信号主要来源于应力集中区 ,在场点监测到的电磁辐射信号主要是应力集中区煤岩变形破裂过程产生的 ;EME信号呈现出与煤岩内部应力变化相同的规律 ;利用力电耦合方法研究煤岩冲击矿压电磁辐射预测法是可行的。笔者最后还对未来煤岩冲击矿压电磁辐射预测法的研究进行了展望。     

沿空窄煤柱锚网带支护的巷道稳定性研究

锚杆支护是煤矿采准巷道的重要支护方式 ,沿空留巷技术是回采巷道支护技术改革的主要方面。笔者将两种技术相结合 ,用于保证回采巷道的稳定。在现场矿压观测的基础上 ,讨论了支承压力分布规律和窄煤柱护巷机理 ,运用极限平衡理论计算出护巷煤柱宽度 ,同时结合数值分析和现场巷道变形以观测结果 ,实践证明 ,只要设计参数合理 ,施工质量满足要求 ,沿空窄煤柱锚网带支护技术就可以保证回采巷道的稳定     

爆炸荷载作用下岩石的变形与破坏研究(Ⅱ)

无论是矿山工程、隧道工程中钻孔爆破效率的提高、工程爆破领域爆破振动参数的预测,还是最近一系列高技术常规局部战争中钻地炸弹对地下坚固目标的破坏,在不考虑岩石中强爆炸引起的光子和电磁辐射等极端效应情况下,都亟待要求对岩石中爆炸引起的应力、变形及其它运动参数和破坏效应作出比较准确的评估。目前对此问题的研究尚只能达到大致的机理及景象的定性认识和描述,定量上的确定存在数量级的误差,尤其是爆炸和冲击的近区,误差更大。其原因在于岩石中爆炸产生的变形和破坏特征,不仅与作用时发生相应的物理及力学运动密切相关,而且强烈地受岩石自身构造缺陷水平及其变化的制约。本文概述了爆炸作用下岩石的动力变形与破坏研究之现状。研究中考虑了岩石的构造特点及其对基本力学性状的影响,并简述了其研究的新趋向。     

Revegetation of serpentine substrates: Response to phosphate application

Revegetation was studied on stockpiled serpentine substrate. The native vegetation surrounding the revegetation site is annual grassland. The seed mixture applied to both subsoil and topsoil plots was largely ineffective for revegetation. No growth occurred in the subsoil plots and most of the growth in the topsoil plots was from indigenous seed. Phosphate application (100 kg P ha^–1 as NaH₂PO₄ · H₂O) to the topsoil plots resulted in a significant increase in total above-ground productivity. Annual legumes (mostlyLotus subpinnatus Lag.) and, to a lesser degree,Plantago erecta Morris responded to the added phosphate with an increased above-ground productivity. Other annual forbs and annual grasses showed no significant response. The legumes also increased in abundance. Mycorrhizal root colonization forPlantago was not significantly affected by phosphate application, but was lower in this disturbed serpentine site compared to other undisturbed serpentine annual grassland sites nearby.     

宁镇山脉圌山火山岩系的时代归属

根据化石组合和火山岩的同位素年龄,并结合区域火山岩资料,本文厘定江苏镇江(?)山火山岩系的时代属早白垩世晚期至晚白垩世早期,而火山活动主要是在晚白垩世,进而论证了下扬子区在晚白垩世期间普遍有零星的酸性岩浆活动。     

中国南方岩溶区石漠化研究

对中国南方岩溶区石漠化现状及成因进行了分析,提出应采取降低土地垦殖率,优化产业结构、恢复植被、环境移民、提高人口素质等手段防治石漠化。