High performance of multi-layered alternating Ni–Fe–P and Co–P films for hydrogen evolution

Judiciously engineering the electrocatalysts is attractive and challenging to exploit materials with high electrocatalytic performance for hydrogen evolution reaction. Herein, we successfully perform the interface engineering by alternately depositing Co–P and Ni–Fe–P films on nickel foam, via facile electroless plating and de-alloying process. This work shows that there is a significant effect of de-alloying process on alloy growth. The electronic structure of layered alloys is improved by interface engineering. The multilayer strategy significantly promotes the charge transfer. Importantly, the Co–P/Ni–Fe–P/NF electrode fabricated by interface engineering exhibits excellent electrocatalytic hydrogen evolution activity with an overpotential of 43.4 mV at 10 mA cm-2 and long-term durability for 72 h in alkaline medium (1 mol L-1 KOH). The innovative strategy of this work may aid further development of commercial electrocatalysts.     

复杂建筑空间人员应急疏散的无人机引导模型研究*

为提升紧急情况下复杂建筑空间中应急疏散引导的疏散效率,采用仿真模拟方法,提出1套可适用于复杂建筑空间人员应急疏散的无人机引导模型,该模型通过改进传统算法和构建新方法,实现无人机空间遍历移动规则寻优、无人机引导路径寻优以及基于“障碍物空间场域”建筑空间区域划分。研究结果表明:相较于没有无人机引导,采用单无人机和多无人机协同引导疏散,可大幅缩短整体疏散时间,有效减少疏散路径当量长度,提高疏散效率并保证路径安全,为无人机在应急救援和疏散的应用提供新思路。     

大空间建筑火灾中热烟气层发展规律的理论分析

对几类典型的大空间建筑火灾中热烟气层的发展规律进行了理论分析,并和文献中的实验结果进行了对比。理论分析表明热烟气层的发展速率除了与火源的功率和大空间的几何尺寸有关外,还取决于火羽流的种类。给出了轴对称火羽流、二维线性溢流和沿墙壁的二维线性火羽流情况下的热烟气层发展速率的表达式,对大空间建筑的火灾安全设计与灾害预测具有指导意义。     

一种新型旋风气幕式排风罩数值模拟研究

利用Fluent计算流体力学软件对新型旋风气幕式排风罩工作流场及有害物分布进行了数值模拟,并与传统排风罩进行了对比。结果表明:旋转射流屏蔽作用下的抽吸流场具有中部压力较低和提高抽吸能力的作用;新型旋风气幕式排风罩不仅能有效地控制有害物扩散,而且可以实现远距离捕集有害物及以较小的排风速度排放有害物。     

建筑小区内致病微生物暴露风险评价

利用数值模拟确定致病微生物浓度的时空分布,建立了基于瞬时浓度判据和积累浓度判据的污染物暴露评价模型,得到了建筑群内瞬时风险区域和人们在污染区域的最大停留时间。结果显示:瞬时风险区域面积基本与微生物生长曲线一致,即在2000s时达到最大,然后逐渐减小,至6000s后基本不变;最大停留时间与微生物的增长率有关,增长率大,最大停留时间变小。     

镧掺杂纳米材料合成及其高氟选择性吸附特性

采用共沉淀法制备了镧渗杂的纳米镁铝层状双氢氧化物材料(LDHs),获得了一类对氟具有选择性的新型吸附材料.实验表征了LDH、其焙烧产物(LDOs)以及吸附氟后的材料(F-LDHs)的微观形态、体相组成等性质的变化,通过批处理试验和吸附柱试验对其工艺特性及影响因素进行了深入分析.实验结果表明,材料经600℃焙烧10min,在含200mg·l~(-1)SO_4~(2-),氟浓度为10mg·l~(-1)的配水中投加0.1g LDOs吸附240min,最高除氟率可达93.53%;在含200mg·l~(-1)SO_4~(2-)的氟溶液中,镁铝铜LDOs吸附氟的容量高于镁铝LDOs;吸附柱实验中,14h时出水氟含量小于国家标准(1 mg·l~(-1));共存阴离子对材料的除氟干扰强度排序为:Co_3~(2-)>PO_4~(3-)>NO_3~->Cl~-.材料吸附氟后可用0.5mg·l~(-1)的Na_2CO_3洗脱,并经600℃焙烧10min再生,再生4次后选择性除氟效果稳定.     

金属有机骨架材料低温脱硝技术研究进展

金属有机骨架材料（MOFs）因其独特的结构作为催化剂应用于SCR系统表现出较好的低温脱硝效果和较强的抗SO₂、抗H₂O性能。综述了几种较典型的MOFs催化剂及其改性产物的低温催化性能,以及MOFs材料应用于SCR技术的研究进展,指出：对含有两种或两种以上金属的复合MOFs材料的深入研究,是开发稳定性更高、抗SO₂抗H₂O能力更强的MOFs催化剂的重要思路;此外,对有机组成部分进行改性,提高有机配体的热稳定性也是一个重要的研究思路。     

EVALUATION OF THE ROSGEN STREAM CLASSIFICATION SYSTEM IN CHEQUAMEGON‐NICOLET NATIONAL FOREST,WISCONSIN1

ABSTRACT: Data collected from 121 stream reaches during 1991 to 1993 were evaluated to determine the applicability of the Rosgen Stream Classification System (RSCS) to the low relief terrain within the Chequamegon‐Nicolet National Forest (CNNF) in Wisconsin, USA. All reaches were classified to RSCS Level I and II except that 10.7 percent had sinuosities below the continuum limits and one reach had a predominantly organic substrate. Five of eight possible RSCS Level I types were observed including B, C, D, A, E, and F; 86 percent were C and E types. Seventeen of 94 possible RSCS Level II types were observed. Most reaches were slightly entrenched, had low to moderate width/depth ratios, relatively low sinuosity, low slope, and sand or gravel as the dominant channel material. Discriminant analyses were used to verify the applicability of RSCS for streams within the CNNF; discriminant functions correctly classified 92.5 and 94.7 percent of the Level I and II RSCS types, respectively. When limits for E and F types were modified slightly at Level II by adding an additional category for slopes less than 0.1 percent (a modification we recommend for low relief terrain), discriminant functions correctly classified 99.1 percent of the types. Adding another slope break at 0.3 percent produced similar results. Based on our analyses, RSCS works well within the CNNF and is probably applicable to other areas with low‐relief terrain.     

军用物资集装箱运输机械环境条件及防护要求

分析集装箱运输军用物资的机械环境,通过测试给出了集装箱装卸冲击特性、运输振动冲击特性等环境量值,并结合机械环境对军用物资的影响．提出安全防护的几点要求。     

我国森林资源及其产品流动特征分析

论文运用物流分析的基本思想,基于我国森林资源产品的产量、贸易量统计资料,采用统一的“原木当量(m³)”单位,沿森林资源采伐→资源产品加工→资源产品消费链,研究了我国“九五”期间主要森林资源产品的流动状况。结果表明,我国“九五”期间年均消耗森林资源16962×10⁴m³,其中48.3%来自国外;本国森林资源主要流向原木、锯材、人造板加工制造行业,仅有9.3%用于制浆造纸;而纸类产品所用的森林资源主要依赖于进口;终端消费中75%的森林资源产品用于建筑装修、家具生产和包装3个主要消费项。因此,认为我国必须提高森林资源利用效率、增加纸类产品中的森林资源用量,以提高我国森林资源流动的经济效益;资源战略上既要充分利用国外森林资源,又要提高我国资源供给的保障能力。