模拟降雨条件下沉积物对磷的富集机理

通过模拟降雨径流实验，在７２ｍｍ／ｈ的大暴雨备件下，研究侵蚀性颗粒从土壤中的径流流失过程及其对磷的富集作用和机理。结果表明，深积物中不同粒长团聚体的组成和原来土壤中的组成有很大差异。径流流失的沉积物主要以０．２５ｍｍ以下的团聚体为主，径流中８０％以上的磷以颗粒态形式流失，而颗粒态磷的６０％－９０％随０．１ｍｍ以下的团聚体流失。不同粒径团聚体对磷的富集作用和富集系数不同。模拟实验建立了沉积物富集系数     

Investigation of the hydrodynamic behavior of diatom aggregates using particle image velocimetry

The hydrodynamic behavior of diatom aggregates has a significant influence on the interactions and flocculation kinetics of algae. However, characterization of the hydrodynamics of diatoms and diatom aggregates in water is rather difficult. In this laboratory study, an advanced visualization technique in particle image velocimetry (PIV) was employed to investigate the hydrodynamic properties of settling diatom aggregates. The experiments were conducted in a settling column filled with a suspension of fluorescent polymeric beads as seed tracers. A laser light sheet was generated by the PIV setup to illuminate a thin vertical planar region in the settling column, while the motions of particles were recorded by a high speed charge-coupled device (CCD) camera. This technique was able to capture the trajectories of the tracers when a diatom aggregate settled through the tracer suspension. The PIV results indicated directly the curvilinear feature of the streamlines around diatom aggregates. The rectilinear collision model largely overestimated the collision areas of the settling particles. Algae aggregates appeared to be highly porous and fractal, which allowed streamlines to penetrate into the aggregate interior. The diatom aggregates have a fluid collection efficiency of 10%-40%. The permeable feature of aggregates can significantly enhance the collisions and flocculation between the aggregates and other small particles including algal cells in water.     

餐厨垃圾生物有机肥对贫瘠黄褐土改良的研究

为了阐明餐厨垃圾生物有机肥改良贫瘠土壤的作用机制,以贫瘠黄褐土为研究对象,通过不施肥、长期（>5 a）施用化肥、中长期（5 a）施用少量餐厨垃圾生物有机肥和短期（1 a）施用大量餐厨垃圾生物有机肥4种施肥方式,分别记为CK组、CF组、LOF-5组和MOF-1组,对比分析不同施肥方式对土壤OM（有机质）、活性有机碳、营养元素和团聚体等的影响.结果表明:①施用餐厨垃圾生物有机肥可显著提高土壤OM、活性有机碳含量,其中,MOF-1组提高效果最显著,与CK组相比,w（OM）可提高173.29%,w（ROC）（ROC为易氧化有机碳）增加了39.17%,w（POC）（POC为颗粒有机碳）和w（DOC）（DOC为可溶性有机碳）分别是CK组的13.85和10.32倍.②中长期（5 a）施用少量餐厨垃圾生物有机肥可增加土壤中较大粒径团聚体的占比,且更有利于提高土壤团粒结构的稳定性,LOF-5组>2 mm粒级的团聚体占比是CK组的4.68倍;与CK组相比,LOF-5组MWD（平均重量直径）增加了100.00%,GMD（几何平均直径）增加了82.98%,>0.25 mm水稳定性团聚体质量占比（DR_0.25）增加了27.20%.③中长期（5 a）施用少量餐厨垃圾生物有机肥可增加土壤中w（TN）（TN为全氮）和w（AN）（AN为速效氮）,与CK组相比,LOF-5组w（TN）和w（AN）分别增加了77.42%和20.82%.施用餐厨垃圾有机肥也可同时增加土壤中w（AP）（AP为速效磷）和w（AK）（AK为速效钾）,MOF-1组增加效果较佳,w（AP）和w（AK）分别是CK组的9.43和3.39倍.研究显示,中长期（5 a）施用少量餐厨垃圾生物有机肥可提升土壤固碳能力,提高土壤养分利用的有效性,从而提升耕地土壤质量,减少化肥施用量,是我国贫瘠黄褐土改良的有效施肥模式.      

建筑垃圾资源化处理工艺改进研究

在分析国内建筑垃圾分类及传统处理工艺现状的基础上,针对传统工艺存在的问题进行改进和优化。所设计的新型处理工艺流程从提高破碎比、改善筛分效果,增强骨料强度和降低扬尘4个方面进行了改进,重点为破碎后骨料的颗粒整形强化工艺、凝胶强化工艺、破碎喷淋除尘工艺。具体表现为:在通用处理流程的基础上,把破碎环节改进为筛分后再进行二次破碎,改进筛分为多次筛分,利用不同的筛分原理实现不同筛分效果;骨料形成后的回收环节增加凝胶喷淋提高骨料强度,弥补了当前处理工艺流程的不足,提高了建筑垃圾的处理效率及品质,可为建筑垃圾资源化处理提供参考。     

成土母质对土壤团聚体形成的影响

成土母质对土壤团聚体数量及其稳定性的影响与不同母质所含无机胶体（粘粒、游离氧化物）的差别有关．对浙江省八类母质发育的土壤的团聚体组成的研究表明：母质对土壤团聚体及其水稳定性影响顺次为玄武岩＞石灰岩、Q2红土＞花岗岩、石英砂岩＞泥页岩＞紫砂岩＞红砂岩．其中母质对5－1mm粒级的水稳性团聚体的影响最为显著．     

重复再生混凝土性能和环境影响研究

基于生命周期评价方法,考虑混凝土重复再生利用的环境影响分配,对重复再生混凝土的性能和环境影响进行研究,并基于功效系数法优化出混凝土最佳重复再生次数.研究结果表明,再生混凝土的坍落度,强度和电通量随着重复再生循环次数的增加而下降,经3次重复再生后,混凝土28d立方体抗压强度为33.3MPa,满足设计要求,而坍落度和电通量与普通混凝土相比,分别减小和增大了38.9%和85.7%;混凝土材料的生态效率随着混凝土重复再生次数的增加而提高,混凝土材料的GWP、CED和CMR的值均随着混凝土重复再生次数的增加而降低,降低幅度从高到低依次为：CMR > GWP > CED;综合考虑混凝土的坍落度,混凝土抗压强度、电通量、GWP、CED和CMR等6个指标,4种混凝土配合比情景中,混凝土总功效系数从高到低依次为：一次再生混凝土 > 二次再生混凝土 > 三次再生混凝土 > 普通混凝土.     

Chemical conversion of paper industry effluents into carboxymethylcellulose

The synthesis of carboxymethylcellulose was investigated using effluents containing short cellulose fibers. Carboxymethylcellulose was synthesized according to the slurry process using different amount of sodium hydroxide and different incubation times at 30 °C after the etherification reaction as variables. Characterization of the product was conducted by Fourier transformed infrared spectroscopy, X-ray diffraction, degree of substitution, average degree of polymerization, water imbibing capacity, color, rheological properties, apparent viscosity and trace elements content. Incubation time slightly increased the yield of the reaction and the degree of substitution during the first 12 h. The reaction yield and degree of substitution both decreased when the initially concentration of NaOH was increased from 7.0 g/mL to 10.5 g/mL. The carboxymethylcellulose obtained was darker and had lower hydration properties than commercial samples. Trace elements content suggests that the product could be only used in paint factories or building materials industries.     

A GIS analysis of suitability for construction aggregate recycling sites using regional transportation network and population density features

Aggregate is used in road and building construction to provide bulk, strength, support, and wear resistance. Reclaimed asphalt pavement (RAP) and reclaimed Portland cement concrete (RPCC) are abundant and available sources of recycled aggregate. In this paper, current aggregate production operations in Virginia, Maryland, and the District of Columbia are used to develop spatial association models for the recycled aggregate industry with regional transportation network and population density features.The cost of construction aggregate to the end user is strongly influenced by the cost of transporting processed aggregate from the production site to the construction site. More than 60% of operations recycling aggregate in the mid-Atlantic study area are located within 4.8 km (3 miles) of an interstate highway. Transportation corridors provide both sites of likely road construction where aggregate is used and an efficient means to move both materials and on-site processing equipment back and forth from various work sites to the recycling operations.Urban and developing areas provide a high market demand for aggregate and a ready source of construction debris that may be processed into recycled aggregate. Most aggregate recycling operators in the study area are sited in counties with population densities exceeding 77 people/km² (200 people/mile²). No aggregate recycling operations are sited in counties with less than 19 people/km² (50 people/mile²), reflecting the lack of sufficient long-term sources of construction debris to be used as an aggregate source, as well as the lack of a sufficient market demand for aggregate in most rural areas to locate a recycling operation there or justify the required investment in the equipment to process and produce recycled aggregate.Weights of evidence analyses (WofE), measuring correlation on an area-normalized basis, and weighted logistic regression (WLR), are used to model the distribution of RAP and RPCC operations relative to transportation network and population distribution data. The models can be used on a regional scale to quickly map the relative site suitability for a RAP or RPCC aggregate recycling operation in a particular area based on transportation network and population parameters. The results can be used to identify general areas to be further evaluated on a site-specific basis using more detailed marketplace information. As transportation or population features change due to planning or actual development, the models can be easily revised to reflect these changes.     

再生混凝土骨料对钢渣骨料透水混凝土性能影响试验研究

将再生混凝土骨料以不同比例取代钢渣骨料配制透水混凝土,采用沸煮试验法考察废混凝土骨料对钢渣透水混凝土强度和体积稳定性的影响,结果表明:再生混凝土骨料可改善钢渣透水混凝土强度,减轻钢渣骨料膨胀对透水混凝土体积稳定性的影响,用再生混凝土骨料在改善钢渣骨料透水混凝土性能同时可消纳两种固体废弃物,具有环境效益和社会效益。     

Improved method for the formation of recycled resins from depolymerized products of waste fiber-reinforced plastics: simple and effective purification of recovered monomers by washing with water

The synthesis of recycled plastics from recovered monomeric materials obtained from the depolymerization reaction of fiber-reinforced plastics (FRP) was examined. The depolymerization reaction of FRP in the presence of N,N-dimethylaminopyridine (DMAP) smoothly yielded the corresponding monomers, which mainly consisted of dimethyl phthalates. The polymerization reaction with this monomer failed to form the corresponding unsaturated polyesters due to contamination by N-methyl-4-pyridone, a decomposition product of DMAP. An efficient purification of the recovered monomer was achieved by washing with water, and the purified monomer successfully yielded the corresponding polymers. A hardness test revealed that the polymers were as hard as the polyester made from virgin materials. The present modification provides a practical method for the preparation of recycled plastics from depolymerized plastics.