Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Improvements in financing for sustainability in solid waste management

Contributing elements toward the development of a sustainable solid waste management system in Tucumán, Argentina, are described. Changes in the working environment for the wastepickers have been instrumental in providing a livable wage and diminished health and environmental risks to the wastepickers and to neighboring residents. Income levels to the wastepickers are now approximately 1.75 times minimum wages in Tucumán and are being driven almost entirely by the recycling of plastics. Educational improvements in Tucumán, which are assisting sustainability of the solid waste system, are being significantly improved by the operation of a pilot scale project, by demonstrating opportunities to government officials and school children. Improved financial sustainability to the solid waste management system is also potentially available from carbon credit trading opportunities, presenting the opportunity for 1.2 times the income available from recycling efforts.     

AN ANALYTICAL FRAMEWORK FOR EVALUATING CHANNEL MAINTENANCE FLOWS IN COLORADO1

ABSTRACT: An accounting procedure is developed which determines a flow regime that is capable of transporting an amount of bedload sediment necessary to ensure channel stability downstream. The method allows for sediment buildup in the channel within geomorphic threshold limits during low flow periods. During periods of high runoff, enough water is bypassed to transport the stored sediment. The procedure utilizes only those flows of sufficient magnitude to maintain channel stability over the long run (25–50+ years). An example is presented which determines the volume of water and frequency of release for channel maintenance purposes downstream from a hypothetical water diversion project. Of some 1,200,000 acre feet generated during a 59-year period, 86,500 acre feet was required for channel maintenance flows. Bypass flows were not required each year, but only during those years when average daily flow reached bankfull or greater. Such releases were made on 202 of the 411 days when average flows either equalled or exceeded bankfull discharge.     

Total recycling of CCA treated wood waste by low-temperature pyrolysis

A system to turn a potentially harmful stream of solid waste into a set of substreams with either commercial value or highly concentrated residual streams is presented. The waste which is considered is metal impregnated (in particular Chromated Copper Arsenate (CCA) treated) wood waste and timber, such as telephone poles, railway sleepers, timber from landscape and cooling towers, wooden silos, hop-poles, cable drums and wooden playground equipment. These waste streams sum up to several 100,000 tons of material per year currently to be dumped in every major country of the European Community (EC). Technologies need to be developed to reduce this CCA treated wood waste, such that all of the metals are contained in a marketable product stream, and the pyrolysis gases and/or pyrolysis liquid are used to their maximum potential with respect to energy recuperation. Pyrolysing the CCA treated wood waste may be a good solution to the growing disposal problem since low temperatures and no oxidising agents are used, which result in lower loss of metals compared to combustion. An experimental labscale pyrolysis system has been developed to study the influence of the pyrolysis temperature and the duration of the pyrolysis process on the release of metals and the mass reduction. The macrodistribution and microdistribution of the metals in the solid pyrolysis residue is studied using Inductively Coupled Plasma Mass Spectrometry (ICP–MS) and Scanning Electron Microscopy coupled with Energy Dispersive X-ray Analysis (SEM–EDXA). Furthermore, a complete mass balance is calculated over the pyrolysis system. Based on these results a semi-industrial pyrolysis system (pilot plant scale) has been developed consisting of three stages: grinding, packed bed pyrolysis and metal separation. Special types of equipment have been developed to carry out the three stages. A new grinding system has been developed, based on a crushing mechanism rather than a cutting mechanism. The crushed wood is introduced by means of a screw feeding system into a reaction column. In this pyrolysis reactor the wood is heated by subjecting it to a flow of hot gases. This causes an adiabatic pyrolysis, which results in volatilisation of the volatile compounds whereas the mineral compounds (containing the metals) remain entrapped in a coal-type residue which is very rich in carbon. The condensable compounds in the pyrolysis gas condense while leaving the reaction zone due to the inverse temperature gradient. The pyrolysis gas leaving the reactor is used as fuel for the hot gas generator. The charcoal which is extracted at the bottom of the reactor, is cooled, compressed, removed and stored, ready to feed the subsequent stage. A specially developed grinder is used to remove the metal particles from the charcoal and the separation between metal and charcoal particles is accomplished in a pneumatic centrifuge as a result of the difference in density. Using this system the ultimate waste is less than 3% of the initial wood mass. Results obtained with a semi-industrial scale prototype confirm the effectiveness of the process.     

Modeling human-induced climatic change: A summary for environmental managers

The rapid increase in atmospheric concentrations of greenhouse gases has caused concern because of their potential to alter the earth's radiation budget and disrupt current climate patterns While there are many uncertainties associated with use of general circulation models (GCMs), GCMs are currently the best available technology to project changes in climate associated with elevated gas concentrations. Results indicate increases in global temperature and changes in global precipitation patterns are likely as a result of doubled CO₂. GCMs are not reliable for use at the regional scale because local scale processes and geography are not taken into account. Comparison of results from five GCMs in three regions of the United States indicate high variability across regions and among models depending on season and climate variable. Statistical methods of scaling model output and nesting finer resolution models in global models are two techniques that may improve projections. Despite the many limitations in GCMs, they are useful tools to explore climate-earth system dynamics when used in conjunction with water resource and ecosystem models. A variety of water resource models showed significant alteration of regional hydrology when run with both GCM-generated and hypothetical climate scenarios, regardless of region or model complexity. Similarly, ecological models demonstrate the sensitivity of ecosystem production, nutrient dynamics, and distribution to changes in climate and CO₂ levels. We recommend the use of GCM-based scenarios in conjunction with water resource and ecosystem models to guide environmental management and policy in a “no-regrets” framework or as part of a precautionary approach to natural resource protection.     

PAST AND FUTURE OF ANALYSIS OF WATER RESOURCES TIME SERIES1

ABSTRACT: water resources supply and demand time series consist of several or all of the four basic characteristics: tendency, intermittency, periodicity and stochasticity. Their importance changes from one type of variables to another. Historic developments of analysis of time series in hydrology have varied significantly over the past, from the stress on search for periodicities and persistence in annual series to the emphasis on the series stochastic properties. Supply and demand series are often highly interrelated, which fact is most often neglected in planning water resources systems in general, and water storage capacities in particular. The future of series analysis in water resources will likely be by a joint use of physically-based structural analysis and the use of advanced methods of treating data by stochastic processes, statistical estimation and inference techniques. The most intriguing challenge of the future of this analysis may be the treatment of nonnormal, nonlinear and in general nonstationary hydrologic and water use time series. The proper treatment of complex multivariate processes will also challenge the specialists, especially for the purposes of transfer of information between data on variables at given points, or between data at several points of a given variable, or both.     

global climate change: processes and products – an overview

Our knowledge of global climate change has many uncertainties.Whether global air temperature will increase, by how much, and when,are subject to debate, but there is little doubt that troposphericconcentrations of several trace gases are increasing. While possibleincreases in the average air temperature is a product of these changes,the increases in the trace gases alone will have an effect on agriculture.Increases in the ambient concentrations of carbon dioxide are expectedto have a positive net effect on crop production. In contrast, anyincreases in the penetration of surface-level ultraviolet-B (280–320 nm)radiation, and known increases in surface ozone concentrations, areconsidered to have adverse effects on certain crops. Our presentknowledge of the joint effects on crops of elevated levels of carbondioxide, ultraviolet-B radiation and ozone, and possible alterations in airtemperature and precipitation patterns, is virtually zero. Therefore, anypredictions of the effects of global climate change on agriculture aresubject to significant uncertainties. In contrast, coupling of climatechange (only temperature and precipitation) models to crop productionhas led to a number of future scenarios. In spite of theirpresent limitations, results from these efforts can be useful in planningfor future agriculture.     

高级氧化技术处理垃圾渗滤液的研究进展

本文介绍了包括化学氧化法、电化学氧化法、光催化氧化法、超声氧化法、辐照氧化法和催化湿式氧化法等在内的高级氧化技术的机理和运用于垃圾渗滤液处理的研究进展,并提出高级氧化技术与生物处理联合运用和各种高级氧化工艺之间的优化组合将是实现高级氧化技术在垃圾渗滤液处理中工程化运用的发展方向.     

SPATIAL AND TEMPORAL DYNAMICS OF WOOD IN HEADWATER STREAMS OF THE PACIFIC NORTHWEST1

This paper synthesizes information on the spatial and temporal dynamics of wood in small streams in the Pacific Northwest region of North America. The literature on this topic is somewhat confused due to a lack of an accepted definition of what constitutes “small” streams and what is the relative size of woody debris contained within the channel. This paper presents a matrix that defines woody debris relative to channel size and then discusses the components of a wood budget. Headwater streams are in close proximity to wood sources and, in steeplands, are often tightly constrained by steep hillslopes. Special consideration is given to ecosystem characteristics and to management practices that affect the wood dynamics in this context. Knowledge gaps and uncertainties that can be used to guide future research are identified. Very little is currently known about the role of mass wasting in wood recruitment and storage relative to other processes, such as bank erosion and mortality, in larger streams. Further, very little work has addressed the relative importance of different wood depletion processes, especially those associated with wood transport. The effect of other ecosystem variables on wood dynamics locally across a watershed (from valley bottom to mountaintop) and regionally across the landscape (from maritime to continental climates) is not addressed. Finally, the scientific community has only begun to deal with the effects of management practices on wood quantity, structure, and movement in small streams.     

Estimating Time Windows for Burning Oil at Sea: Processes and Factors

This paper discusses processes and factors for estimating time period windows of in situ burning of spilled oil at sea. Time-periods of in situ burning of Alaska North Slope (ANS) crude oil are estimated using available data. Three crucial steps are identified. The First Step is to determine the time it takes for the evaporative loss to reach the known or established limitation for evaporation and compare this time-period with estimated time of ignition at the ambient wind and sea temperatures. The Second Step is to determine the water up-take of the spilled oil and compare it with the known or established limitation for water-in-oil content. The Third Step is to determine the necessary heat load from the igniter to bring the surface temperature of the spilled oil to its flash point temperature so that it will burn at the estimated time period for ignition of the slick.