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81.
Whitfield Slund M Celejewski M Lankadurai BP Simpson AJ Simpson MJ 《Chemosphere》2011,83(8):1096-1101
1H NMR metabolomics can be used to assess the sub-lethal toxicity of contaminants to earthworms by identifying alterations in the metabolic profiles of contaminant- exposed earthworms in contrast to those of healthy (control) individuals. In support of this method this study sought to better characterize the baseline metabolic profile of healthy, mature earthworms of the species, Eisenia fetida, which is recommended for both acute and sub-lethal toxicity testing for soil contaminants. Profiles of D2O-buffer extracted metabolites were determined using 1H NMR spectroscopy and both inter-individual metabolic variability and pair-wise metabolic correlations were assessed. The control earthworm extracts exhibited low overall inter-individual metabolic variability, with a spectrum-wide median relative standard deviation (%RSD = standard deviation/mean × 100) of 14%, which suggests that the metabolic profile of E. fetida earthworms is well controlled in laboratory conditions and supports further use of this organism in environmental metabolomics research. In addition, strong positive correlations were detected between the levels of maltose, betaine, glycine, and glutamate as well as between the levels of lactate, valine, leucine, alanine, lysine, tyrosine, and phenylalanine which had not previously been reported. Since comparison of pair-wise metabolic correlations between control and treated organisms can reveal changes in the underlying pattern of biochemical relationships between the metabolites, identification of these significant metabolic correlations in control earthworms provides an additional characteristic that may be applied to delineate between control and treated earthworms in future NMR-based metabolomic studies. 相似文献
82.
This work focuses on the phenomenon of the immiscible two-phase flow of water and oil in saturated heterogeneous soil columns. The goal is to develop a fast and reliable method for quantifying soil heterogeneities for incorporation into the relevant capillary pressure and relative permeability functions. Such data are commonly used as input data in simulators of contaminant transport in the subsurface. Rate-controlled drainage experiments are performed on undisturbed soil columns and the transient response of the axial distribution of water saturation is determined from electrical measurements. The transient responses of the axial distribution of water saturation and total pressure drop are fitted with the multi-flowpath model (MFPM) where the pore space is regarded as a system of parallel paths of different permeability. The MFPM enables us to quantify soil heterogeneity at two scales: the micro-scale parameters describe on average the effects of pore network heterogeneities on the two-phase flow pattern; the macro-scale parameters indicate the variability of permeability at the scale of interconnected pore networks. The capillary pressure curve is consistent with that measured with mercury intrusion porosimetry over the low pressure range. The oil relative permeability increases sharply at a very low oil saturation (< 10− 3) and tends to a high end value. The water relative permeability decreases abruptly at a low oil saturation (~ 0.1), whereas the irreducible wetting phase saturation is quite high. The foregoing characteristics of the two-phase flow properties are associated with critical (preferential) flowpaths that comprise a very small percentage of the total pore volume, control the overall hydraulic conductivity, and are consistent with the very broad range of pore-length scales usually probed in soil porous matrix. 相似文献
83.
Environmental performance and spillover effects on productivity: evidence from horticultural firms 总被引:3,自引:3,他引:0
Galdeano-Gómez E Céspedes-Lorente J Martínez-Del-Río J 《Journal of environmental management》2008,88(4):1552-1561
This study investigates the effect of environmental investment and related spillover effects on productivity in the agricultural sector by using a panel data of horticultural firms in Andalusia (Southern Spain). The results indicate a positive relationship between firm investment in environmental practices and productivity improvement, also showing the presence of positive environmental spillovers. In a second-stage of analysis, the incidence of environmental factors in firm specific individual technical efficiency is estimated. This analysis also shows the link between environmental knowledge diffusion and horticultural firms' performance. 相似文献
84.
How does agricultural intensification modulate changes in plant community composition? 总被引:1,自引:0,他引:1
Laura José-María José M. Blanco-MorenoLaura Armengot F. Xavier Sans 《Agriculture, ecosystems & environment》2011,145(1):77-84
Agricultural intensification, at local and landscape scales, has caused a decrease in plant diversity and changes in species composition in cereal fields. To better understand the role of landscape complexity and farming systems in shaping plant assemblages, it is of interest to focus on functional traits rather than on floristic composition, which may help to highlight trends in vegetation patterns. We analysed the relative abundance of various functional attributes (different life forms, growth forms, wind-pollinated species and wind-dispersed species) at three contrasted field positions (boundary, edge and centre) of 29 organic and 29 conventional cereal fields distributed in 15 agrarian localities of NE Spain. Agricultural intensification affected the biological attributes of the vegetation in dryland Mediterranean cereal fields; local factors (farming system and position) had a more prominent role in affecting plant functional composition than the surrounding landscape. Local factors were important for life form distribution, growth form and pollination type, whereas landscape complexity mainly affected the proportion of wind-dispersed species. Therefore, depending on the objective of the study, it is important to select functional attributes sensitive to the different scales of agricultural intensification, especially because landscape complexity and land-use intensity are commonly related. 相似文献
85.
86.
2009年广州能见度变化规律及主要影响因素分析 总被引:7,自引:4,他引:3
通过对2009年的广州大气能见度和影响因素的数据资料统计,结合定性分析、相关性计算及各时间尺度中物理量的相互作用过程研究,得出能见度的变化规律和各因素的相关性特征。结果表明,2009年整体能见度水平略有提高;24h的降雨量、气温差值较大时,该日的能见度小时均值波动较大;风速、相对湿度与中尺度(24h)能见度的相关性较强;降雨量、气温对小尺度(1h、5min)能见度影响显著;相对湿度水平能制约风速对能见度的改善作用。灰霾现象等与能见度水平密切相关。 相似文献
87.
The topic of air pollution has drawn considerable attention globally. In this paper, we examine the immediate effect of air pollution on a substantial decision, that is, a housing purchase. By linking housing purchasing behavior with the air quality in Beijing, we document market participants' behaviors unexplained by rational economic theories. Our main result suggests that the transaction prices on a severely polluted day are 0.65% higher than those of the days without pollution, other things being equal. This translates into approximately 3.51 million yuan daily increase based on the average transaction volume and price on a typical day in Beijing. The heterogeneity analysis further suggests that this effect is mostly driven by non-local and low income buyers. After ruling out rational explanations, we demonstrate that our empirical results are consistent with salience theory under weak assumptions. 相似文献
88.
Mohammad Javaheri Kristian Jessen 《International Journal of Greenhouse Gas Control》2011,5(5):1272-1283
Carbon dioxide (CO2) injection into saline aquifers is one of the promising options to sequester large amounts of CO2 in geological formations. During as well as after injection of CO2 into an aquifer, CO2 migrates towards the top of the formation due to density differences between the formation brine and the injected CO2. The time scales of CO2 migration towards the top of an aquifer and the fraction of CO2 that is trapped as residual gas depends strongly on the driving forces that are acting on the injected CO2.When CO2 migrates to the top of an aquifer, brine may be displaced downwards in a counter-current flow setting particularly during the injection period. A majority of the published work on counter-current flow settings have reported significant reductions in the associated relative permeability functions as compared to co-current measurements. However, this phenomenon has not yet been considered in the simulation of CO2 storage into saline aquifers.In this paper we study the impact of changes in mobility for the two-phase brine/CO2 system as a result of transitions between co- and counter-current flow settings. We have included this effect in a simulator and studied the impact of the related mobility reduction on the saturation distribution and residual saturation of CO2 in aquifers over relevant time scales. We demonstrate that the reduction in relative permeability in the vertical direction changes the plume migration pattern and has an impact on the amount of gas that is trapped as a function of time. This is to our best knowledge the first attempt to integrate counter-current relative permeability into the simulation of injection and subsequent migration of CO2 in aquifers. The results and analysis presented in this paper are directly relevant to all ongoing activities related to the design of large-scale CO2 storage in saline aquifers. 相似文献
89.
在线水质自动监测系统质量保证与质量控制 总被引:1,自引:0,他引:1
质量保证与控制是水质自动监测中的非常重要一项工作,在线水质自动分析仪一般情况下都是持续工作,溶液的稳定性、分析仪器的基线漂移、仪器的运行情况都直接影响数据的质量。因此,为取得准确的数据,就必须对自动监测系统进行全程的质量控制。 相似文献
90.
Ruixue Wang Ning Yang Jianlong Li Li Xu Narcisse T. Tson Lin Du Wenxing Wang 《环境科学学报(英文版)》2022,34(4):149-159
Despite the heterogeneous reaction of sulfur dioxide (SO2) on mineral dust particles significantly affects the atmospheric environment, the effect of acidic gases on the formation of sulfite and sulfate from this reaction is not particularly clear. In this work, using the in-situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) technique, we employed a mineral dust particle model (CaCO3) combined with NO2 and acetic acid to investigate their effects on the heterogeneous reaction of SO2 on CaCO3 particles. It was found that water vapor can promote the formation of sulfite and simulated radiation can facilitate the oxidation of sulfite to sulfate. The addition of NO2 or acetic acid to the reaction system altered the production of sulfate and sulfite accordingly. There was a synergistic effect between NO2 and SO2 that promoted the oxidation of sulfite to sulfate, and a competitive effect between acetic acid and SO2 that inhibited the formation of sulfite. Moreover, light and water vapor can also affect the heterogeneous reaction of SO2 with the coexistence of multiple gases. These findings improve our understanding of the effects of organic and inorganic gases and environmental factors on the formation of sulfite and sulfate in heterogeneous reactions. 相似文献