金属铁还原降解2,4-二硝基甲苯的实验研究

研究了金属铁对2,4-二硝基甲苯(2,4-DNT)的还原降解情况.实验结果表明,2,4-DNT的还原降解与溶液初始pH值、初始浓度和溶解氧等因素有关.氯离子能消除金属铁的钝化现象.金属铁表面附载的铜对2,4-DNT的还原降解具有催化作用.     

乙酸型顶极群落的内平衡与反馈调节机制研究

通过产酸脱硫反应器处理高浓度硫酸盐有机废水的连续流试验，从“动态”角度考察COD／SO4^2-比改变引起的pH值、氧化还原电位（ORP）、碱度（ALK）和末端产物（VFAs）等的变动及生态因子的叠加效应引发的优势种群变迁，分析了乙酸型顶极群落的稳定性及其发生定向性生态演替的规律，进而阐明了乙酸型顶极群落抵抗环境压力的内平衡与反馈调节机制，并指出乙酸型代谢和乙酸型顶极群落是产酸脱硫生态系统的典型特征。     

A/O和A2/O法除磷脱氮工艺影响因素及除磷动力学的研究

重点介绍A/O除磷工艺和A~2/O除磷脱氮工艺,以及影响除磷脱氮工艺因素和除磷动力学的研究。工艺研究采用了动态与静态实验方法,采用色质联机研究了有毒有机物的降解情况。试验结果表明,A/O、A~2/O工艺的BOD_5去除率近于二级污水处理厂,A~2/O法TP去除率近于三级污水处理厂,且去除难降解有毒有机物的效率高于传统的活性污泥法。动力学公式的修正使之更适于低碳源的情况。八种影响因素的研究为工艺的设计与运行提供了依据。     

销毁遗弃化学武器的环境风险评价方法研究

为履行《禁止化学武器公约》，各缔约国销毁化学武器的工作已启动。根据当前世界上化学武器的销毁情况，并针对二战期间在中国遗弃的化学武器的特点，给出了一套适应化学武器销毁流程的环境风险评价方法和技术。这套方法对将在我国进行的销毁遗弃化学武器风险评价工作有一定的实际意义。     

Trisomy 7 in chorionic villi: Follow-up studies of pregnancy,normal child,and placental clonal anomalies

Cytogenetic study of chorionic villi sampled because of advanced maternal age revealed, after overnight culture, an apparently non-mosaic trisomy 7. Amniocentesis showed exclusively normal mitoses, and the pregnancy continued normally. One hundred mitoses from cord blood of the normal newborn revealed a non-mosaic 46,XX complement. No cells with a proven trisomy 7 were found in cultures from either of two biopsies of the morphologically normal placenta, but the peripheral biopsy showed in multiple cultures an abnormal clone: 47,XX, + 20,-2,-21, + t(2;21)(p13;q22). To our knowledge, this is the first case of non-mosaic trisomy 7 detected on CVS which has had follow-up studies of amniotic fluid, cord blood, and term placenta.     

环境风险评价研究综述

论述了环境风险评价研究的有关基本概念以及主要研究内容的发展，指出了风险评价存在的不足，并在此基础上提出一些合理建议。     

Quantitative structure-property relationship of aromatic sulfur-containing carboxylates

IntroductionItiswidelyrecognizedthatthephysicochemicalprofileoforganicchemicalslargelydeterminestheirdistributionbetweenenvironmentalmedia .Fortheenvironmentalbehaviorsoforganiccontaminants,watersolubility(SW)andoctanol waterpartitioncoefficient(KOW)aretremendouslyimportant.Octanol waterpartitioncoefficienthasbeenwidelyrelatedtobiochemicaland orbiologicalactivityinquantitativestructure activityrelationships(QSARs) (Leo ,1 971 ) .Watersolubilitycorrespondstothedispersiontendencyandtothereca…     

Influence of chlorsulfuron herbicide on size of microbial biomass in the soil

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅｕｓｅｏｆｃｈｅｍｉｃａｌｓ,ｉｎｃｌｕｄｉｎｇｐｅｓｔｉｃｉｄｅｓ,ｈａｓｂｅｃｏｍｅａｎｉｎｔｅｇｒａｌａｎｄｅｃｏｎｏｍｉｃａｌｌｙｅｓｓｅｎｔｉａｌｐａｒｔｏｆｍｏｄｅｒｎａｇｒｉｃｕｌｔｕｒｅ.Ｐｅｓｔｉｃｉｄｅ?..     

Methods for project-based mechanisms (JI/CDM)—relevance of IPCC inventory guidelines

A baseline for a project consists of estimates of annual emissions of greenhouse gases (GHG) for a given time period without implementing the project. A general three-step process for determining the baseline is suggested. The emission reduction of the project is given by the difference between the baseline and the monitored annual emissions. A preferred method, direct measurement of the emission reduction, is possible for some types of projects. Methods for estimating the annual baseline emissions are not necessary for the latter category, and a definition of this project category is suggested. IPCC Guidelines for National GHG Inventories categorise the emission sources so that only direct emissions from consumption of fuel and feedstock are calculated. There are thus no emission factors for indirect emissions (e.g. electricity consumption or km transported) or emission factors that depend on technology only, independent of consumption of fuel and feedstock. Technology-dependent emission factors may thus need to be developed for estimating indirect emissions and multi-project baselines. Consistency should be sought with the IPCC Guidelines when estimating annual baseline emissions and in monitoring project emissions to ensure comparability with the National Inventories.     

Enhanced cyanogen chloride formation after UV/PS and UV/H2O2 pre-oxidation and chlorination in natural river water

Ultraviolet/persulfate (UV/PS) and Ultraviolet/hydrogen peroxide (UV/H₂O₂) have attracted much attention in recent years as advanced oxidation processes for water treatment. However, it is not all clear how these two methods affect the formation of cyanogen chloride (CNCl) in the subsequent water chlorination process. In this study, it was found that both UV/H₂O₂ and UV/PS pre-oxidation promoted the formation of CNCl in six actual water samples collected from urban rivers. Glycine, uric acid, arginine and histidine were investigated as the model compounds to explore the effects of different methods on the production of CNCl. The results showed that compared with chlorination alone, pre-oxidation by UV/H₂O₂ and UV/PS can reduce the production of CNCl for glycine and uric acid by up to 95% during post-chlorination process. However, they can greatly promote the formation of CNCl for arginine and histidine by up to 120-fold. In a more detailed investigation, pre-oxidation of histidine formed highly reactive intermediates to chlorine, leading to increased CNCl formation and chlorine consumption. The results showed that the precursors of CNCl was altered after pre-oxidation, and need to be re-evaluated.