Mesoporous WO3-graphene photocatalyst for photocatalytic degradation of Methylene Blue dye under visible light illumination

Advanced oxidation technologies are a friendly environmental approach for the remediation of industrial wastewaters. Here, one pot synthesis of mesoporous WO_3 and WO_3-graphene oxide(GO) nanocomposites has been performed through the sol–gel method. Then, platinum(Pt) nanoparticles were deposited onto the WO_3 and WO_3-GO nanocomposite through photochemical reduction to produce mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites. X-ray diffraction(XRD) findings exhibit a formation of monoclinic and triclinic WO_3 phases. Transmission Electron Microscope(TEM) images of Pt/WO_3-GO nanocomposites exhibited that WO_3 nanoparticles are obviously agglomerated and the particle sizes of Pt and WO_3 are ~ 10 nm and 20–50 nm, respectively. The mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites were assessed for photocatalytic degradation of Methylene Blue(MB) as a probe molecule under visible light illumination.The findings showed that mesoporous Pt/WO_3, WO_3-GO and Pt/WO_3-GO nanocomposites exhibited much higher photocatalytic efficiencies than the pure WO_3. The photodegradation rates by mesoporous Pt/WO_3-GO nanocomposites are 3, 2 and 1.15 times greater than those by mesoporous WO_3, WO_3-GO, and Pt/WO_3, respectively. The key factors of the enhanced photocatalytic performance of Pt/WO_3-GO nanocomposites could be explained by the highly freedom electron transfer through the synergetic effect between WO_3 and GO sheets, in addition to the Pt nanoparticles that act as active sites for O2 reduction, which suppresses the electron hole pair recombination in the Pt/WO_3-GO nanocomposites.     

Geostatistical Uncertainty Modelling for the Environmental Hazard Assessment During Single Erosive Rainstorm Events

This paper presents an environmental hazard assessment to account the impacts of single rainstorm variability on river-torrential landscape identified as potentially vulnerable mainly to erosional soil degradation processes. An algorithm for the characterisation of this impact, called Erosive Hazard Index (EHI), is developed with a less expensive methodology. In EHI modelling, we assume that the river-torrential system has adapted to the natural hydrological regime, and a sudden fluctuation in this regime, especially those exceeding thresholds for an acceptable range of flexibility, may have disastrous consequences for the mountain environment. The hazard analysis links key rainstorm energy variables expressed as a single-storm erosion index (EI_sto), with impact thresholds identified using an intensity pattern model. Afterwards, the conditional probabilities of exceeding these thresholds are spatially assessed using non-parametric geostatistical techinques, known as indicator kriging. The approach was applied to a test site in river-torrential landscape of the Southern Italy (Benevento province) for 13 November 1997 rainstorm event.     

混凝法在滇池蓝藻暴发期净水除藻的可行性研究

采用精制硫酸铝为混凝剂,L93^4正交法安排滇池蓝藻暴发期混凝沉降除藻除净水工艺实验。结果表明,混凝剂种类、水样pH值对蓝藻去除率有很大影响。研究确定了混凝剂除藻最佳操作条件,为混凝法去除蓝藻的工业化提供了理论和实际操作依据。     

冀南野生木本资源植物研究

冀南产野生木本资源植物200种，隶属43科91属。其中超过5种的科有13个，蔷薇科30种最多，其次为豆科24种，忍冬科、榆科、杨柳科均在10种以上。1、油松Pinustabulaeformis松科。木材可供建筑、电杆、矿柱、造船、家具及木纤维工业原料等用材；树干可提取松节油；树皮可提取栲胶     

固定化酵母菌对活性艳蓝KN-R的脱色研究

采用海藻酸钙加活性碳的方法对酵母菌进行固定化。正交试验结果表明，三者合适配比为海藻酸钠3％，活性碳10％，氯化钙4％。此方法制得的凝胶颗粒机械强度好、经久耐用。固定化酵母菌凝胶小球最适条件为：培养时间为48h，培养温度为37℃，培养基pH为3．0，凝胶量为10g。固定化细胞经多次脱色后能重复使用，4次脱色后其脱色率还达79．2％。     

Wetland loss and substitution by the Section 404 permit program in southern California,USA

To test the effectiveness of the 404 permit program in preventing a net loss of wetland resources, 75 Section 404 projects permitted in the years 1987–1989 and located in a portion of southern California were evaluated. From this group of projects, 80.47 ha of wetlands were affected by Section 404 permits and the Army Corps of Engineers required 111.62 ha of wetland mitigation. To verify the successful completion of each mitigation project, all 75 project sites were visited and evaluated based on the amount of dead vegetation, growth and coverage, and the number of invasive species. Based on the field verification results, the actual amount of completed mitigation area was 77.33 ha, resulting in a net loss of 3.14 ha of wetland resources in the years 1987–1989. By comparing the types of wetlands lost to the types of wetlands mitigated, it is apparent that, in particular, freshwater wetlands are experiencing a disproportionately greater loss of area and that riparian woodland wetlands are most often used in mitigation efforts. The net result of these accumulated actions is an overall substitution of wetland types throughout the region. Results also indicate that, typically, large-scale mitigation projects are more successful compared to smaller projects and that successful compliance efforts are not evenly distributed throughout the region. We recommend that better monitoring, mitigation in-kind, mitigation banking, and planning on a regional or watershed scale could greatly improve the effectiveness of the Section 404 permitting program.     

Class: an Essential Aspect of Watershed Planning

A study of a watershed planning process in the Cache River Watershed in southern Illinois revealed that class divisions, based on property ownership, underlay key conflicts over land use and decision-making relevant to resource use. A class analysis of the region indicates that the planning process served to endorse and solidify the locally-dominant theory that landownership confers the right to govern. This obscured the class differences between large full-time farmers and small-holders whose livelihood depends on non-farm labor. These two groups generally opposed one another regarding wetland drainage. Their common identity as “property owner” consolidated the power wielded locally by large farmers. It also provided an instrument – the planning document – for state and federal government agencies to enhance their power and to bring resources to the region. The planning process simultaneously ameliorated conflicts between government agencies and the large farmers, while enhancing the agencies’ capacity to reclaim wetlands. In this contradictory manner, the plan promoted the environmental aims of many small-holders, and simultaneously disempowered them as actors in the region’s political economy. An erratum to this article is available at .     

玄武湖蓝藻水华成因探讨

为了解南京玄武湖蓝藻水华的成因,对玄武湖长期监测资料进行了分析和现场调查。结果表明,玄武湖鲢鳙急剧减少中断了正常的食物链,使浮游植物的牧食压力降低,在东南湖回水的诱因作用下,发生了以微囊藻为优势种群的蓝藻水华。指出,玄武湖蓝藻水华的发生进程表明,东南湖回水可能是蓝藻水华发生的诱因,生态失衡是蓝藻水华发生的主要原因,蓝藻水华的暴发与富营养化程度无显著相关性,其暴发加重了玄武湖富营养化程度。     

Watershed Evapotranspiration Increased due to Changes in Vegetation Composition and Structure Under a Subtropical Climate1

Abstract: Natural forests in southern China have been severely logged due to high human demand for timber, food, and fuels during the past century, but are recovering in the past decade. The objective of this study was to investigate how vegetation cover changes in composition and structure affected the water budgets of a 9.6‐km² Dakeng watershed located in a humid subtropical mountainous region in southern China. We analyzed 27 years (i.e., 1967‐1993) of streamflow and climate data and associated vegetation cover change in the watershed. Land use/land cover census and Normalized Difference of Vegetation Index (NDVI) data derived from remote sensing were used to construct historic land cover change patterns. We found that over the period of record, annual streamflow (Q) and runoff/precipitation ratio did not change significantly, nor did the climatic variables, including air temperature, Hamon’s potential evapotranspiration (ET), pan evaporation, sunshine hours, and radiation. However, annual ET estimated as the differences between P and Q showed a statistically significant increasing trend. Overall, the NDVI of the watershed had a significant increasing trend in the peak spring growing season. This study concluded that watershed ecosystem ET increased as the vegetation cover shifted from low stock forests to shrub and grasslands that had higher ET rates. A conceptual model was developed for the study watershed to describe the vegetation cover‐streamflow relationships during a 50‐year time frame. This paper highlighted the importance of eco‐physiologically based studies in understanding transitory, nonstationary effects of deforestation or forestation on watershed water balances.     

Generation of Monthly Precipitation Under Climate Change for the Upper Blue Nile River Basin,Ethiopia1

Abstract: This work develops a methodology to project the future precipitation in large river basins under limited data and climate change while preserving the historical temporal and spatial characteristics. The computationally simple and reliable conditional generation method (CGM) is presented and applied to generate reliable monthly precipitation data in the upper Blue Nile River Basin of Ethiopia where rain‐fed agriculture is prevalent. The results showed that the temporal analysis with the CGM performs better to reproduce the historical long‐term characteristics than other methods, and the spatial analysis with the CGM reproduced the historical spatial structure accurately. A 100‐year time series analysis using the outcomes of the six general circulation models showed that precipitation changes by the 2050s (2040 through 2069) can be ?7 to 28% with a mean increase of about 11%. The seasonal results showed increasing wet conditions in all seasons with changes of mean precipitation of 5, 47, and 6% for wet, dry, and mild seasons, respectively.