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31.
32.
Yingyi Zhang Senchao Lai Zhen Zhao Fobang Liu Hongwei Chen Shichun Zou Zhiyong Xie Ralf Ebinghaus 《Chemosphere》2013
An intensive campaign was conducted in September 2012 to collect surface water samples along the tributaries of the Pearl River in southern China. Thirteen perfluoroalkyl acids (PFAAs), including perfluorocarboxylates (PFCAs, C4–C11) and perfluorosulfonates (PFSAs, C4, C6–C8, and C10), were determined using high-performance liquid chromatography/negative electrospray ionization–tandem mass spectrometry (HPLC/(-)ESI–MS/MS). The concentrations of total PFAAs (ΣPFAAs) ranged from 3.0 to 52 ng L−1, with an average of 19 ± 12 ng L−1. The highest concentrations of ΣPFAAs were detected in the surface water of the Dong Jiang tributary (17–52 ng L−1), followed by the main stream (13–26 ng L−1) and the Sha Wan stream (3.0–4.5 ng L−1). Perfluorooctanoate (PFOA), perfluorobutane sulfonate (PFBS), and perfluorooctane sulfonate (PFOS) were the three most abundant PFAAs and on average accounted for 20%, 24%, and 19% of ΣPFAAs, respectively. PFBS was the most abundant PFAA in the Dong Jiang tributary, and PFOA was the highest PFAA in the samples from the main stream of the Pearl River. A correlation was found between PFBS and PFOA, which suggests that both of these PFAAs originate from common source(s) in the region. Nevertheless, the slope of PFBS/PFOA was different in the different tributaries sampled, which indicates a spatial difference in the source profiles of the PFAAs. 相似文献
33.
Land use conflicts are becoming increasingly apparent from local to global scales. Surface gold mining is an extreme source
of such a conflict, but mining impacts on local livelihoods often remain unclear. Our goal here was to assess land cover change
due to gold surface mining in Western Ghana, one of the world’s leading gold mining regions, and to study how these changes
affected land use systems. We used Landsat satellite images from 1986–2002 to map land cover change and field interviews with
farmers to understand the livelihood implications of mining-related land cover change. Our results showed that surface mining
resulted in deforestation (58%), a substantial loss of farmland (45%) within mining concessions, and widespread spill-over
effects as relocated farmers expand farmland into forests. This points to rapidly eroding livelihood foundations, suggesting
that the environmental and social costs of Ghana’s gold boom may be much higher than previously thought. 相似文献
34.
Zero-valent iron nanoparticles in treatment of acid mine water from in situ uranium leaching 总被引:3,自引:0,他引:3
Acid mine water from in situ chemical leaching of uranium (Straz pod Ralskem, Czech Republic) was treated in laboratory scale experiments by zero-valent iron nanoparticles (nZVI). For the first time, nZVI were applied for the treatment of the real acid water system containing the miscellaneous mixture of pollutants, where the various removal mechanisms occur simultaneously. Toxicity of the treated saline acid water is caused by major contaminants represented by aluminum and sulphates in a high concentration, as well as by microcontaminants like As, Be, Cd, Cr, Cu, Ni, U, V, and Zn. Laboratory batch experiments proved a significant decrease in concentrations of all the monitored pollutants due to an increase in pH and a decrease in oxidation-reduction potential related to an application of nZVI. The assumed mechanisms of contaminants removal include precipitation of cations in a lower oxidation state, precipitation caused by a simple pH increase and co-precipitation with the formed iron oxyhydroxides. The possibility to control the reaction kinetics through the nature of the surface stabilizing shell (polymer vs. FeO nanolayer) is discussed as an important practical aspect. 相似文献
35.
In the new European Pesticide Regulation (EC) No. 1107/2009, the harmonisation of approaches for estimation of the environmental exposure of pesticides is considered a major goal. Several member states currently require their own models for the calculation of predicted environmental concentrations (PEC) in surface water. The variety of methods makes risk evaluations rather time-consuming for both notifiers and evaluating authorities. In the present study we compare surface water concentrations of 19 compounds using EU and country-specific models and risk assessment approaches to evaluate to which extent the resulting estimated exposure concentrations differ. Our results show that EU and country specific approaches and the resulting surface water concentrations differ considerably regarding basic model assumptions and assessment methods. The results indicate that the aimed harmonisation of risk assessment approaches within the EU will be difficult based on current models. New scenarios may help to achieve a harmonisation taking country-specific features into account. 相似文献
36.
Concerns regarding the impacts of pesticides on aquatic species and drinking water sources have increased demands on water quality monitoring programs; however the costs of sample analysis can be prohibitive. In this study we investigated enzyme-linked immunosorbent assay (ELISA) as a cost-effective, high through-put method for measuring pesticide concentrations in surface waters. Seven hundred and thirty-nine samples from 158 locations throughout Ontario were analysed for atrazine and metolachlor from April to October 2007. Concentrations ranged from <0.1 to 3.91 μg L−1 (median = 0.12 μg L−1) for atrazine and from <0.1 to 1.83 μg L−1 (median = 0.09 μg L−1) for metolachlor. Peak concentrations occurred in late spring/early summer, in rural agricultural locations, and decreased over the remainder of the growing season for both herbicides. About 3% of the samples that had ELISA results occurring above the limit of quantification (0.10 μg L−1) were evaluated against gas chromatography-mass spectrometry (GC-MS). Linear regression analysis revealed a R2 value of 0.88 and 0.39, for atrazine and metolachlor, respectively. ELISA tended to overestimate concentrations for atrazine and metolachlor, most likely because the ELISA kits also detect their metabolites. Atrazine data suggest that ELISA may be used complementary with GC-MS analysis to enhance the spatial and temporal resolution of a water quality monitoring study. The commercially available metolachlor ELISA kit requires further investigation. ELISA may be used to detect atrazine and metolachlor in surface water samples, but it is not recommended as a quantitative replacement for traditional analytical methods. 相似文献
37.
38.
地面水中叶枯灵的高效液相色谱测定 总被引:2,自引:0,他引:2
本文采用反相高效液相色谱法,在质控条件下,对河水,塘水两种地面水中叶枯灵的检验方法进行了测试,用Shimapck ODS柱为分析柱,以甲醇:水=50:50为流动相,并用冰醋酸调PH至4-5,紫外检测波长281nm,两种水样的平均回收率分别为91.7-96.3%,90-95.8%,相对标准偏差为4.3%,最低检出限为0.0261mg/l,为地面水中叶枯灵卫生标准的实施提供了简便,灵敏,正确的配套测试手段。 相似文献
39.
Chang WR 《Journal of Safety Research》2004,35(1):71-79
PROBLEM: Surface roughness affects friction, so selection of floor surfaces with certain roughness characteristics could potentially reduce slip and fall accidents. This article summarizes the preferred surface microscopic geometric features that could increase friction on surfaces covered with liquid contaminants. METHOD: Three types of surface features, represented by the average of the maximum height above the mean line in each cut-off length (R(pm)), the arithmetical average of surface slope (Delta(a)), and the kernel roughness depth (R(k)), are identified as preferred surface microscopic geometric features for a higher friction. The proper settings on the profilometers (instruments used to measure surface roughness) for optimizing these surface parameters are specified. The friction mechanisms involved reveal why these features are more desirable. RESULTS: Although surface roughness is important in determining slipperiness, there is still insufficient information to establish a safety criterion based on roughness; however, the method presented in this paper can readily provide a relative comparison. IMPACT ON INDUSTRY: The summary presented will help safety professionals properly select new floor surfaces or assess existing floors to reduce slip and fall accidents. 相似文献
40.
Chemical Treatments of Natural Fiber for Use in Natural Fiber-Reinforced Composites: A Review 总被引:2,自引:0,他引:2
Xue Li Lope G. Tabil Satyanarayan Panigrahi 《Journal of Polymers and the Environment》2007,15(1):25-33
Studies on the use of natural fibers as replacement to man-made fiber in fiber-reinforced composites have increased and opened
up further industrial possibilities. Natural fibers have the advantages of low density, low cost, and biodegradability. However,
the main disadvantages of natural fibers in composites are the poor compatibility between fiber and matrix and the relative
high moisture sorption. Therefore, chemical treatments are considered in modifying the fiber surface properties.
In this paper, the different chemical modifications on natural fibers for use in natural fiber-reinforced composites are reviewed.
Chemical treatments including alkali, silane, acetylation, benzoylation, acrylation, maleated coupling agents, isocyanates,
permanganate and others are discussed. The chemical treatment of fiber aimed at improving the adhesion between the fiber surface
and the polymer matrix may not only modify the fiber surface but also increase fiber strength. Water absorption of composites
is reduced and their mechanical properties are improved. 相似文献