微波密封消解法快速测定总磷

对微波密封消解法测定总磷进行了研究．实验结果表明：该法操作简单、消解时间短，准确度高，精密度好，值得普及和推广．     

典型北方高碱度微污染水体强化混凝的示范研究

以高碱度、受有机物污染的典型北方水体为例,探索适宜的强化混凝技术.在水质调查的基础上,提出适合水质特征的强化混凝目标.研究了高碱度水体强化混凝技术方法.研究表明,可以通过3条技术途径提高水体中有机物的去除效率.其一在混凝前优化pH,促进絮凝剂水解形成中聚体,AlCl3在pH 6左右,FeCl3在pH 5左右时,有机物去除率可以提高一倍左右;其二是强化沉淀软化;其三是絮凝剂优化.结合我国实际情况,通过对传统絮凝剂进行改性,研制出了适合我国北方水质特征的高效絮凝剂,能较传统絮凝剂将有机物去除率提高30%以上.     

Simultaneous determination of dissolved organic nitrogen, nitrite, nitrate and ammonia using size exclusion chromatography coupled with nitrogen detector

Accurate quantification of dissolved organic nitrogen (DON) has been a challenge due to the cumulative analytical errors in the conventional method via subtracting dissolved inorganic nitrogen species (DIN) from total dissolved nitrogen (TDN). Size exclusion chromatography coupled with an organic nitrogen detector (SEC-OND) has been developed as a direct method for quantification and characterization of DON. However, the applications of SEC-OND method still subject to poor separations between DON and DIN species and unsatisfied N recoveries of macromolecules. In this study, we packed a series of SEC columns with different lengths and resin materials for separation of different N species and designed an independent vacuum ultraviolet (VUV) oxidation device for complete oxidation converting N species to nitrate. To guarantee sufficient N recoveries, the operation conditions were optimized as oxidation time ≥ 30 min, injection mass (sample concentration × injection volume) < 1000 µL × mg-N/L for macromolecular proteins, and neutral pH mobile eluent. The dissolved O₂ concentration in SEC mobile phase determined the upper limit of VUV oxidation at a specific oxidation time. Compared to conventional HW50S column (20 × 250 mm), HW40S column (20 × 350 mm) with mobile phase comprising of 1.5 g/L Na₂HPO₄·2H₂O + 2.5 g/L KH₂PO₄ (pH = 6.85) could achieve a better separation of DON, nitrite, nitrate, and ammonia. When applied to river water, lake water, wastewater effluent, groundwater, and landfill leachate, the SEC-OND method could quantify DON as well as DIN species accurately and conveniently even the DIN/TDN ratio reached 0.98.     

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.     

光化学反应的环境效应

光化学反应具有良好的环境效应，本文概述了有机合成和环境化学中光化学反应对环境的影响。     

温泉宾馆室内PM_(10),PM_(2.5),CO_2和~(222)Rn的研究

对广东省 4座温泉宾馆室内外氡(222Rn)浓度和温泉水氡浓度进行研究,同时利用便携式探测器对室内外 PM10,PM2.5,CO2和CO 等污染物暴露水平进行直接测定.结果表明,温泉宾馆室内使用温泉水时氡浓度明显高于广东省室内平均氡浓度.除 CO 外,室内 PM10,PM2.5 和CO2 浓度都较高,其中 PM10 和 CO2 的超标率分别达到 67%和 89%.说明温泉宾馆室内不仅存在一般性污染物,而且存在高浓度的 Rn. 222     

对水体中有机污染综合指标及其相互间的关系探研

通过对水体中各有机污染综合指标的含义及各指标测定方法条件控制的论述,阐明了各指标间的相互关系,对我们在水质监测中的质量控制、数据的综合分析和判断有一定的指导意义。     

下古生界海相碳酸盐烃源岩地球化学的研究现状

本文对国内外下古生界海相碳酸盐岩研究的四个主要方面作了总结：（1）有机质丰度及其影响因素；（2）有机质赋存形式；（3）下古生界海相碳酸盐岩有机质丰度和生烃潜力恢复方法和原理；（4）下古生界海相碳酸盐岩热成熟度研究。这四个方面是评价我国下古生界海相碳酸盐岩勘探前景至关重要的因素，也是近年来我们研究下古生界海相碳酸盐岩的热点和难点问题。     

活性炭厌氧流化床处理毒性有机废水存在的问题与对策

活性炭厌氧流不处理毒性有机废水存在问题，对含有活性炭能吸附而生物难降解成份的废水，通过定期替换少量活性炭、能维持工艺的稳定运行。