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881.
S. B. Weisberg H. T. Wilson D. G. Heimbuch H. L. Windom J. K. Summers 《Environmental monitoring and assessment》2000,61(3):373-385
Aluminum is often used as a conservative tracer toseparate natural from anthropogenic components ofmetal contamination in marine sediments, butidentifying uncontaminated sites to develop baselinemetal:aluminum relationships can be problematic inpopulated areas. Here we present a new method foridentifying baseline relationships in high populationdensity areas. The method involves comparing theresidual from the metal:aluminum regression with anindependent estimate of laboratory measurement error,based on the premise that mean square error from theregression must equal laboratory measurement error forany data set that is free of anthropogenicallyenriched sites. The method is applied to data setsfrom the mid-Atlantic and Gulf coasts of the UnitedStates to test consistency in baseline relationshipsbetween these two coasts of geologically differentorigin. Differences in metal:aluminum relationshipsbetween coasts were found to be small and limited tothe least abundant trace metals. 相似文献
882.
Conti ME Iacobucci M Cecchetti G Alimonti A 《Environmental monitoring and assessment》2008,141(1-3):27-34
Fifty seven samples of Mytilus galloprovincialis (Lamarck, 1819) collected along the breakwater barriers of Fano (station 1) and Pesaro (station 2), Adriatic Sea, Marche
Region, central Italy, were analyzed by atomic absorption spectrometry and Cd, Cu, Pb and Zn concentrations in the soft tissues
were measured. The aims of this work were the statistical analysis of Cd-weight, Cu-weight, Pb-weight, Zn-weight relationships,
and the building of a tendency function that allows assessing with a good approximation the concentrations of a metal in different
weight organisms. In Mytilus galloprovincialis the content of Cd proportionally grew with the weight and therefore its concentration was independent from this factor; while
the concentration of Pb decreased as the weight increased. In both cases the accuracy of multiple regression models improved
considering the variable ‘site’, while the same approach appeared not reliable for Cu and Zn, that were two essential metals.
Our results showed that a tendency function was reliable, solid and able to predict to a very satisfying extent the concentration
of non-physiological metals, like Cd and Pb; while it did not show a good approximation with real Cu and Zn contents. 相似文献
883.
This study was conducted to evaluate, using soil columns, the mobilization and redistribution of heavy metals (Zn, Cd, and
Pb) among different soil fractions by soluble organic ligands within poultry litter. Uncontaminated soil was amended with
Zn, Cd, and Pb to achieve concentration levels of 400, 8, and 200 mg kg−1 soil, respectively. Columns repacked with this amended soil were leached with distilled water, 0.01 M EDTA, 0.01 M CaCl2, or poultry litter extract (PLE) solutions. After leaching, the soil samples in the columns were sequentially extracted for
exchangeable (EXC), carbonate (CARB) organic matter (OM), Mn oxide (MNO), Fe oxide (FEO), and residual (RES) fractions. Considerable
mobilization of Zn, Cd, and Pb occurred in soil during EDTA leaching. Leaching with PLE and CaCl2 solutions significantly decreased Zn and Cd concentrations in the EXC, CARB, and OM fractions. These solutions significantly
decreased Pb concentration in the EXC fraction, while PLE solubilized more Pb from EXC fraction than CaCl2. Thus, the applied poultry litter may change Zn, Cd, and Pb fractions in metal-amended soil and possibly enhance metal mobility. 相似文献
884.
Enrichment and fractionation of heavy metals in bed sediments of River Narmada, India 总被引:2,自引:0,他引:2
A metal fractionation study on bed sediments of River Narmada in Central India has been carried out to examine the enrichment
and partitioning of different metal species between five geochemical phases (exchangeable fraction, carbonate fraction, Fe/Mn
oxide fraction, organic fraction and residual fraction). The river receives toxic substances through a large number of tributaries
and drains flowing in the catchment of the river. The toxic substances of particular interest are heavy metals derived from
urban runoff as well as municipal sewage and industrial effluents. Heavy metals entering the river get adsorbed onto the suspended
sediments, which in due course of time settle down in the bottom of the river. In this study fractionation of metal ions has
been carried out with the objective to determine the eco-toxic potential of metal ions. Although, in most cases (except iron)
the average trace/heavy metal concentrations in sediments were higher than the standard shale values, the risk assessment
code as applied to the present study reveals that only about 1–3% of manganese, <1% of copper, 16–19% of nickel, 4–20% of
chromium, 1–4% of lead, 8–13% of cadmium and 1–3% of zinc exist in exchangeable fraction and therefore falls under low to
medium risk category. According to the Geo-accumulation Index (GAI), cadmium shows high accumulation in the river sediments,
rest of other metals are under unpolluted to moderately polluted class. 相似文献
885.
Impact of poor solid waste management on ground water 总被引:1,自引:0,他引:1
Eight sediment cores recovered from Tamaki Estuary were analysed for Cu, Pb, Zn, and Cd using downward cored sub-samples.
The results indicate a significant upward enrichment in heavy metals with the highest concentrations found in the uppermost
0–10 cm layer. Assessment of heavy metal pollution in marine sediments requires knowledge of pre-anthropogenic metal concentrations
to act as a reference against which measured values can be compared. Pristine values for the cored sediments were determined
from flat “base-line” metal trends evident in lower core samples. Various methods for calculating metal enrichment and contamination
factors are reviewed in detail and a modified and more robust version of the procedure for calculating the degree of contamination
is proposed. The revised procedure allows the incorporation of a flexible range of pollutants, including various organic species,
and the degree of contamination is expressed as an average ratio rather than an absolute summation number. Comparative data
for normalized enrichment factors and the modified degree of contamination show that Tamaki Estuary sediments have suffered
significant systematic heavy metal contamination following catchment urbanization. Compared to baseline values the uppermost
sediment layers show four-fold enrichment averaged across eight cores and four analysed metals. 相似文献
886.
Metal and metallothionein level in the heat-treated cytosol of gills of transplanted mussels Mytilus galloprovincialis Lmk 总被引:3,自引:0,他引:3
A stock of mussels Mytilus galloprovincialis was transplanted over 1 year to four sites in a semi-enclosed bay in Croatia which is under the influence of various sources of pollution. The positive correlation of metal (Cd, Zn, Cu, Mn, Fe) and metallothionein (MT) tissue contents based on the analysis of heat-treated cytosol of gills with shell mass, as an indicator of mussel age, indicated to accumulation of metals, as well as the increase of MTs with mussel age. The principal component analysis (PCA) revealed that 74% of total variance of obtained results could be explained through two principal components. The first principal component was highly correlated with MT, Cd and Zn indices (metal or MT content/shell mass), and the second one with Cu, Mn, and Fe indices, as well as the gill index. High correlation of MTs with Zn and Cd is consistent with their affinity for binding to MTs. 相似文献
887.
In this study, the surface chemical functional groups of Bacillus cereus biomass were identified by Fourier transform infrared (FTIR) analytical technique. It had been shown that the B. cereus cells mainly contained carboxyl, hydroxyl, phosphate, amino and amide functional groups. The potentiometric titration was conducted to explain the surface acid-base properties of aqueous B. cereus biomass. The computer program FITEQL 4.0 was used to perform the model calculations. The optimization results indicated that three sitesthree pKas model, which assumed the cell surface to have three distinct types of surface organic functional groups based on the IR analysis results, simulated the experimental results very well. Moreover, batch adsorption experiments were performed to investigate biosorption behavior of Cu(Ⅱ) and Pb(Ⅱ) ions onto the biomass. Obviously, the adsorption equilibrium data for the two ions were reasonably described by typical Langmuir isotherm. 相似文献
888.
Utilization of washed MSWI fly ash as partial cement substitute with the addition of dithiocarbamic chelate 总被引:1,自引:0,他引:1
The management of the big amount of fly ash as hazardous waste from the municipal solid waste incinerator (MSWI) has encountered many problems in China. In this study, a feasibility research on MSWI fly ash utilization as partial cement substitute in cement mortars was therefore carried out. MSWI fly ash was subjected to washing process to reduce its chlorine content (from 10.16% to 1.28%). Consequently, it was used in cement mortars. Ten percent and 20% replacement of cement by washed ash showed acceptable strength properties. In TCLP and 180-day monolithic tests, the mortars with washed ash presented a little stronger heavy metal leachability, but this fell to the blank level (mortar without washed ash) with the addition of 0.25% chelate. Therefore, this method is proposed as an environment-friendly technology to achieve a satisfactory solution for MSWI fly ash management. 相似文献
889.
用幼苗法指示污泥和土壤中重金属的植物有效性 总被引:13,自引:0,他引:13
利用小麦幼苗与黑麦幼苗研究了污泥和土壤中重金属的植物有效性,并对二者进行了比较。结果表明, 在两种污灌区土壤、四种污泥以及一种污泥施用于两种清洁土壤中,黑麦和小麦测定的Cd,Pb,Cu,Zn,Ni五种重金属有效性的顺序,以及有效性大小的数量级上是一致的;除了在污泥中,二者的茎Pb,Ni及根Zn相关不显著,以及在Lou土中施用污泥后,两种植物各部位相关不好外,在污泥及污泥施于赤红壤各处理中黑麦与小麦相关均匀为极显著。上述结果表明,应用小麦幼苗可以替代黑麦幼苗指标土壤中重金属的植物有效性,但同时也应考虑不同植物间的差异。 相似文献
890.
Heavy Metal Distribution in Valley Sediments in Wadi Al-Karak Catchment Area, South Jordan 总被引:4,自引:0,他引:4
Valley sediments samples collected from the major and minor valleys of Al-Karak catchment area (southern Jordan) were leached with hot dilute HCl and analysed for their heavy metals content. The results of leachable metal concentrations indicated the absence of anomalous values for metal occurrences. However, appreciable contamination of the sediments with Cu, Zn, Pb, Cd and Cr was observed. Using an index of pollution the extent of contamination was better delineated. The geographical distribution of the samples showed higher Cu, Zn, Pb, Cd and Cr concentrations mainly around heavily inhabited areas indicating an anthropogenic source of contamination. Lithological influence indicated from the anomalies of Fe and Mn was found to be very low. 相似文献