Risk analysis for road and rail transport of hazardous materials: a GIS approach

An approach to transportation risk analysis for road and rail transport of dangerous goods is proposed, which is based on the use of geographic information systems (GIS) to manage territorial information, coupled with a product data bank in a risk evaluation tool. Such an approach enables to accurately take into account the local data affecting risk analysis, such as population, accident rate, and weather conditions along all the route, by means of a system which can be easily updated. The resulting risk evaluation tool assists in the step of route identification and allows to rapidly perform an accurate transportation risk analysis, for a single transportation event as well as for multiple substances, trips and itineraries.     

移动式旋风颗粒层除尘器的设计研究

本文阐述了一种新型二级垂直移动式颗粒层除尘器，它的关键技术采用独创的床外清灰及气流输送、滤料循环系统．该除尘器１９９１年已获国家实用新型专利，它的适用范围广，除尘效率高，无二次污染。适用于粉尘、烟气等污染源的治理，使排放浓度达标．     

氰化物分析的条件优选及相关问题探讨

用正交试验法优选氰化物分析的主要测试条件，试验、讨论影响测定结果精确度的关键因素及其作用规律，并对存在的各种技术问题提出探讨意见。     

False-positive results of UN test O.2 liquid oxidizer test of polychlorosilanes

According to UN Test O.2, surprisingly, the polychlorosilanes hexachlorodisilane (HCDS), octachlorotrisilane (OCTS) and decachlorotetrasilane (DCTS) formally fulfill the criteria of the “test for oxidizing liquids”. This result is in contrast to the properties of polychlorosilanes that are described in the literature and those we have experienced in our own production.By investigating the reaction products from the UN O.2 test reactor, using IR, Raman and XPS spectroscopy, it was shown that the results are not due to oxidizing properties of HCDS, OCTS or DCTS, but are caused by the specified test substance cellulose. To our knowledge, this is the very first substance class in which the reference substance oxidizes the test sample, instead of vice versa. This represents an important limitation of the internationally used UN Test O.2 for this substance class. The cause for this false-positive result is the known high degree of affinity of oxygen to silicon.It is shown that the correctly executed UN Test O.2 produces false-positive results and that the polychlorosilanes do not have an oxidizing effect and, therefore, do not have to be classified as “oxidizing substances”.     

聚合氯化铝与聚磷硫酸铁絮凝除藻比较研究

针对武汉市莲花湖湖水,采用聚合氯化铝(PAC)和聚磷硫酸铁(PPFS)进行絮凝实验,比较了两种无机絮凝剂的絮凝效果及原水处理前后藻类群落变化。主要结论如下:①PPFS与PAC的最佳投加量分别为1.5mg/L、2.0mg/L;②PPFS在去除藻类细胞、浊度和色度方面均优于PAC,当PPFS投加过量时,因水体中Fe3+过量分布,使水样色度去除率下降;③PPFS絮凝处理微囊藻为主体的水华原水时,其效果比PAC更好。本文研究后表明:PPFS是一种新型高效絮凝剂,其絮凝性能明显优于PAC,当水体以微型藻类为主时,可使用PPFS以替代PAC,能提高絮凝效果。     

Distribution and transportation of mercury from glacier to lake in the Qiangyong Glacier Basin, southern Tibetan Plateau, China

The Tibetan Plateau is home to the largest aggregate of glaciers outside the Polar Regions and is a source of fresh water to 1.4 billion people. Yet little is known about the transportation and cycling of Hg in high-elevation glacier basins on Tibetan Plateau. In this study, surface snow,glacier melting stream water and lake water samples were collected from the Qiangyong Glacier Basin. The spatiotemporal distribution and transportation of Hg from glacier to lake were investigated. Significant diurnal variations of dissolved Hg(DHg) concentrations were observed in the river water, with low concentrations in the morning(8:00 am–14:00 pm) and high concentrations in the afternoon(16:00 pm–20:00 pm). The DHg concentrations were exponentially correlated with runoff, which indicated that runoff was the dominant factor affecting DHg concentrations in the river water. Moreover, significant decreases of Hg were observed during transportation from glacier to lake. DHg adsorption onto particulates followed by the sedimentation of particulate-bound Hg(PHg) could be possible as an important Hg removal mechanism during the transportation process. Significant decreases in Hg concentrations were observed downstream of Xiao Qiangyong Lake, which indicated that the high-elevation lake system could significantly affect the distribution and transportation of Hg in the Qiangyong Glacier Basin.     

Evaluation of the explosibility of malt grain dust based on static electrification during pneumatic transportation

The possibility of dust explosions by static electricity in a malt grain silo was investigated. Two kinds of experimental equipment were applied. One was to supply electrostatic charge in order to investigate the charge build up characteristics. The other was to transport the malt grain pneumatically in order to investigate the frictional charge accumulation in the transportation system.

The particle charge of the pulverized malt grain was in the order of 10⁻¹⁴ C. The particle charge of the malt grain was in the order of 10⁻⁹ C and the pipe charge in the transport system was also in the order of 10⁻⁹ C. The charge accumulated on both the pulverized particle and the grain particle were small in view of the incendiary potentiality. However, attention must be paid when the particles are dumped into isolated space. There might be a charge accumulation that will lead to the ignition of the dust cloud.     

ITS数据质量控制技术及应用研究

通过总结智能交通系统 (ITS)数据质量控制中所涉及的数据属性 ,提出了ITS数据质量控制算法 :根据阈值理论和交通流理论 ,针对错误数据、丢失数据和不精确数据设计相应的判别规则 ,利用数值计算方法对其进行修正 ,并提出了针对数据中的不规则时间点的修正算法。在对北京市和美国圣安东尼奥市的两组不同时间序列的ITS数据进行实践应用后 ,比较质量控制前后的数据特征 ,证明所提出的算法能够有效地解决数据质量问题 ,提高数据的精确度。最后 ,对国内外ITS数据进行质量控制后的结论和经验作了总结。     

新型气体灭火剂开发技术研究

为了提高哈龙替代灭火剂的灭火性能,减少其对环境的不利影响,必须加快开发新一代气体灭火剂的步伐。提出了理想哈龙替代灭火剂的筛选标准和12种主要性能的分级方法,探讨了筛选过程的设计策略和选择筛选试验方法的基本原则,通过对典型气体灭火剂主要性能的对比,揭示了气体灭火剂的发展历程。剖析了气体灭火剂的灭火浓度、大气寿命、分散性、灭火剂及其分解和燃烧产物的毒性等重要性能的筛选技术发展现状和存在问题。认为应尽快建立并完善气体灭火剂的各项主要性能筛选试验方法,构建完整的气体灭火剂替代品性质数据库,在此基础上形成科学的性能预测体系,以便更好地从大量备选化学物质中找出综合性能优异、适合面广的新一代气体灭火剂系列品种。