Temporal variability of groundwater chemistry in shallow and deep aquifers of Araihazar, Bangladesh

Samples were collected every 2-4 weeks from a set of 37 monitoring wells over a period of 2-3 years in Araihazar, Bangladesh, to evaluate the temporal variability of groundwater composition for As and other constituents. The monitoring wells are grouped in 6 nests and span the 5-91 m depth range. Concentrations of As, Ca, Fe, K, Mg, Mn, Na, P, and S were measured by high-resolution ICPMS with a precision of 5% or better; concentrations of Cl were measured by ion chromatography. In shallow wells <30 m deep, As and P concentrations generally varied by <30%, whereas concentrations of the major ions (Na, K, Mg, Ca and Cl) and the redox-sensitive elements (Fe, Mn, and S) varied over time by up to +/-90%. In wells tapping the deeper aquifers >30 m often below clay layers concentrations of groundwater As were much lower and varied by <10%. The concentrations of major cations also varied by <10% in these deep aquifers. In contrast, the concentration of redox-sensitive constituents Fe, S, and Mn in deep aquifers varied by up to 97% over time. Thus, strong decoupling between variations in As and Fe concentrations is evident in groundwaters from shallow and deep aquifers. Comparison of the time series data with groundwater ages determined by (3)H/(3)He and (14)C dating shows that large seasonal or inter-annual variations in major cation and chloride concentrations are restricted to shallow aquifers and groundwater recharged <5 years ago. There is no corresponding change in As concentrations despite having significant variations of redox sensitive constituents in these very young waters. This is attributed to chemical buffering due to rapid equilibrium between solute and solid As. At two sites where the As content of groundwater in existing shallow wells averages 102 microg/L (range: <5 to 648 microg/L; n=118) and 272 microg/L (range: 10 to 485 microg/L; n=65), respectively, a systematic long-term decline in As concentrations lends support to the notion that flushing may slowly deplete an aquifer of As. Shallow aquifer water with >5 years (3)H/(3)He age show a constant As:P molar ratio of 9.6 over time, suggesting common mechanisms of mobilization.     

COMPROMISE PROGRAMMING METHODOLOGY FOR DETERMINING INSTREAM FLOW UNDER MULTIOBJECTIVE WATER ALLOCATION CRITERIA1

ABSTRACT: This paper presents a quantitative assessment framework for determining the instream flow under multiobjective water allocation criteria. The Range of Variability Approach (RVA) is employed to evaluate the hydrologic alterations caused by flow diversions, and the resulting degrees of alteration for the 32 Indicators of Hydrologic Alteration (IHAs) are integrated as an overall degree of hydrologic alteration. By including this index in the objective function, it is possible to optimize the water allocation scheme using compromise programming to minimize the hydrologic alteration and water supply shortages. The proposed methodology is applied to a case study of the Kaoping diversion weir in Taiwan. The results indicate that the current release of 9.5 m³/s as a minimum instream flow does not effectively mitigate the highly altered hydrologic regime. Increasing the instream flow would reduce the overall degree of hydrologic alteration; however, this is achieved at the cost of increasing the water supply shortages. The effects on the optimal instream flow of the weighting factors assigned to water supplies and natural flow variations are also investigated. With equal weighting assigned to the multiple objectives, the optimal instream flow of 26 m³/s leads to a less severely altered hydrologic regime, especially for those low‐flow characteristics, thereby providing a better protection of the riverine environment.     

现代道路交通系统交通安全状况变化特性探析

以日本现代道路交通系统发展过程为例 ,通过对其发展过程中不同时期道路交通安全状况特征、内在原因的深入分析 ,探讨了以汽车为主要交通工具的现代道路交通安全系统道路交通安全状况的变化特性。笔者认为 ,准确把握现代道路交通安全系统发展过程中道路交通安全状况的变化特性对改善我国当前道路交通安全状况、进一步提高道路交通管理水平将具有积极意义。     

丹江口水库对汉江中下游影响的生态学分析

基于黄家港水文站1954～2000年的日径流量资料,以1967年为节点,将47年水文序列划分为节点前的“近自然状态河流”和节点后的“人工干扰状态河流”两种水文情势。采用Richter提出的变动范围法,基于包含32个水文参数的水文改变指标体系,定量评估了黄家港水文站1967年前后水文情势的变化。根据分析,把1967年之前的各个水文参数的第1至第3四分位数间的数值范围设为管理目标。进一步分析了丹江口水库的修建对汉江中下游生态水文的影响。结果表明,1967年以后,丹江口水库的修建对汉江中下游水文情势的影响较为显著：极大地改变了径流的年内分配,使流量过程均化,使极值流量出现日期提前、历时缩短等等。在此基础上,结合汉江中下游河道生态系统的特点,以鱼类为指示生物,初步探讨了上述水文情势的变化对汉江中下游鱼类的生长、繁殖和越冬等带来的影响,并对如何降低不利影响提出了相应的改进措施.     

A Protocol to Select High Quality Datasets of Ecotoxicity Values for Pesticides

Abstract

The key to any QSAR model is the underlying dataset. In order to construct a reliable dataset to develop a QSAR model for pesticide toxicity, we have derived a protocol to critically evaluate the quality of the underlying data. In developing an appropriate protocol that would enable data to be selected in constructing a QSAR, we concentrated on one toxicity end point, the 96 h LC50 from the acute rainbow trout study. This end point is key in pesticide regulation carried out under 91/414/EEC. The dataset used for this exercise was from the US EPA-OPP database.     

Rival recognition affects male contest behavior in sand lizards (Lacerta agilis)

Individual male sand lizards meet repeatedly during mate search and engage in costly interactions. If males can recognize rivals, the number of costly fights with a predictable outcome may be reduced. In staged contests between males, second interactions are on average significantly shorter than first ones, suggesting individual recognition. When aggressive behavior differs substantially between the sexes, the more aggressive sex may be predicted to have more variation in skin traits located on the parts of the body displayed during contests; this would facilitate individual recognition. Male (aggressive) sand lizards are more variable in two of three lateral skin traits displayed during males' contests, while females (non-aggressive) are more variable in one dorsal skin trait; in four other dorsal traits there was no difference in variability between the sexes.     

Optimizing Liquid Effluent Monitoring at a Large Nuclear Complex

Effluent monitoring typically requires a large number of analytes and samples during the initial or startup phase of a facility. Once a baseline is established, the analyte list and sampling frequency may be reduced. Although there is a large body of literature relevant to the initial design, few, if any, published papers exist on updating established effluent monitoring programs. This paper statistically evaluates four years of baseline data to optimize the liquid effluent monitoring efficiency of a centralized waste treatment and disposal facility at a large defense nuclear complex. Specific objectives were to: (1) assess temporal variability in analyte concentrations, (2) determine operational factors contributing to waste stream variability, (3) assess the probability of exceeding permit limits, and (4) streamline the sampling and analysis regime. Results indicated that the probability of exceeding permit limits was one in a million under normal facility operating conditions, sampling frequency could be reduced, and several analytes could be eliminated. Furthermore, indicators such as gross alpha and gross beta measurements could be used in lieu of more expensive specific isotopic analyses (radium, cesium-137, and strontium-90) for routine monitoring. Study results were used by the state regulatory agency to modify monitoring requirements for a new discharge permit, resulting in an annual cost savings of US $223,000. This case study demonstrates that statistical evaluation of effluent contaminant variability coupled with process knowledge can help plant managers and regulators streamline analyte lists and sampling frequencies based on detection history and environmental risk.     

Factors affecting the variability of household water use in Melbourne,Australia

This study investigates the variability of household water use in Melbourne with the aim of improving the current understanding of factors affecting residential water use. This understanding is critical to predicting household water demand, particularly at an appropriate spatial and temporal resolution to support Integrated Urban Water Management based planning and to improve the understanding on how different household water demands respond to demand management strategies. The study used two sets of data each collected from 837 households under significantly different water use conditions in the years 2003 and 2011. Data from each household consist of the household characteristics and quarterly metre readings. Ordinary Least Square regression analysis followed by detailed analysis of each factor was used to identify key factors affecting household water use. The variables studied are household size, typology of dwelling, appliance efficiency, presence of children under 12 years, presence of children aged between 12 and 18 years, tenancy, dwelling age, presence of swimming pool, evaporative cooler, and dishwasher. All of them except presence of children aged between 12 and 18 years, tenancy and dwelling age were identified as variables that contribute to the variability of household water use in Melbourne. The study also found that the explanatory capacity of these variables increases with decreasing water use. This paper also discusses the significance of the explanatory variables, their impact and how they vary over the seasons and years. The variables found in this study can be used to inform improved prediction and modelling of residential water demand. The paper also explores other possible drivers to explain residential water use in light of the moderate explanatory capacity of the variables selected for this study thus, provides useful insights into future research into water demand modelling.