Review of pollutants removed by electrocoagulation and electrocoagulation/flotation processes

The word “electrocoagulation” (EC) will be sometimes used with “electroflotation” (EF) and can be considered as the electrocoagulation/flotation (ECF) process. Through the process of electrolysis, coagulating agents such as metal hydroxides are produced. When aluminium electrodes are used, the aluminium dissolves at the anode and hydrogen gas is released at the cathode. The coagulating agent combines with the pollutants to form large size flocs. As the bubbles rise to the top of the tank they adhere to particles suspended in the water and float them to the surface. In fact, a conceptual framework of the overall ECF process is linked to coagulant generation, pollutant aggregation, and pollutant removal by flotation and settling when it has been applied efficiently to various water and wastewater treatment processes. This review paper considers a significant number of common applications of EC and ECF processes which have been published in journal and conference papers.     

Emergy Evaluation of the Natural Value of Water Resources in Chinese Rivers

Emergy theory and method were used to evaluate the economy of China and the contributions of water resources in Chinese rivers to the real wealth of the Chinese economy. The water cycle and energy conversion were reviewed, and an emergy method for evaluating the natural value of water resources in a river watershed was developed. The indices for China calculated from the emergy evaluation were close to those of developing countries. Despite a small surplus in its balance of payments, China had a net emergy loss from its trade in 2002. The efficiency of Chinese natural resource use was still not high and did not match its economic growth rate. Furthermore, the Chinese economy placed a stress on its ecological environment and natural resources. Several indices of Chinese rivers from the emergy evaluation were close to those of average global river water. The main average indices of Chinese rivers were transformity (4.17 × 10⁴ sej/J), emergy per volume (2.05 × 10¹¹ sej/m³), and emdollar per volume (0.06 $/m³). The total value of all the rivers’ water made up 13.0% of the GDP of China in 2002, and that of water consumption accounted for 2.1%. The value of the water resources in the Haihe-luanhe River (11.39 × 10⁴ sej/J) was the highest, followed by the Yellow River (10.27 × 10⁴ sej/J), while the rivers in Southwest China had the lowest values (2.92 × 10⁴ sej/J).     

Contribution of Wastewater Treatment Plant Effluents to Nutrient Dynamics in Aquatic Systems: A Review

Excessive nutrient loading (considering nitrogen and phosphorus) is a major ongoing threat to water quality and here we review the impact of nutrient discharges from wastewater treatment plants (WWTPs) to United States (U.S.) freshwater systems. While urban and agricultural land uses are significant nonpoint nutrient contributors, effluent from point sources such as WWTPs can overwhelm receiving waters, effectively dominating hydrological characteristics and regulating instream nutrient processes. Population growth, increased wastewater volumes, and sustainability of critical water resources have all been key factors influencing the extent of wastewater treatment. Reducing nutrient concentrations in wastewater is an important aspect of water quality management because excessive nutrient concentrations often prevent water bodies from meeting designated uses. WWTPs employ numerous physical, chemical, and biological methods to improve effluent water quality but nutrient removal requires advanced treatment and infrastructure that may be economically prohibitive. Therefore, effluent nutrient concentrations vary depending on the particular processes used to treat influent wastewater. Increasingly stringent regulations regarding nutrient concentrations in discharged effluent, along with greater freshwater demand in populous areas, have led to the development of extensive water recycling programs within many U.S. regions. Reuse programs provide an opportunity to reduce or eliminate direct nutrient discharges to receiving waters while allowing for the beneficial use of reclaimed water. However, nutrients in reclaimed water can still be a concern for reuse applications, such as agricultural and landscape irrigation.     

Landscape Planning for Agricultural Non–Point Source Pollution Reduction. II. Balancing Watershed Size,Number of Watersheds,and Implementation Effort

Agricultural non–point source (NPS) pollution poses a severe threat to water quality and aquatic ecosystems. In response, tremendous efforts have been directed toward reducing these pollution inputs by implementing agricultural conservation practices. Although conservation practices reduce pollution inputs from individual fields, scaling pollution control benefits up to the watershed level (i.e., improvements in stream water quality) has been a difficult challenge. This difficulty highlights the need for NPS reduction programs that focus efforts within target watersheds and at specific locations within target watersheds, with the ultimate goal of improving stream water quality. Fundamental program design features for NPS control programs—i.e., number of watersheds in the program, total watershed area, and level of effort expended within watersheds—have not been considered in any sort of formal analysis. Here, we present an optimization model that explores the programmatic and environmental trade-offs between these design choices. Across a series of annual program budgets ranging from $2 to $200 million, the optimal number of watersheds ranged from 3 to 27; optimal watershed area ranged from 29 to 214 km²; and optimal expenditure ranged from $21,000 to $35,000/km². The optimal program configuration was highly dependent on total program budget. Based on our general findings, we delineated hydrologically complete and spatially independent watersheds ranging in area from 20 to 100 km². These watersheds are designed to serve as implementation units for a targeted NPS pollution control program currently being developed in Wisconsin.     

建立水质自动监测系统的思考

结合章郭水质自动监测系统的可行性研究,在建立水质自动监测系统过程中对监测站位的选取、监测项目的选择、水质自动监测系统的组成、数据的采集与处理、系统的维护及管理、存在的问题等方面进行探讨,水质自动监测系统的建设可以弥补水质监测的不足,同时为实施总量控制及环境管理提供了可靠的依据。     

生态工程治理玄武湖水污染效果的监测与评价

选取总磷、总氮、叶绿素a、浮游生物、浮游植物等多项环境监测指标,对利用生态工程治疗玄武湖水环境污染的效果进行了环境监测与评价。指出生态工程治理玄武湖水环境污染效果显著,经过治理使湖水中生物多样性大大增加,浮游植物大幅减少,湖水透明度增加,总磷、总氮等主要指标大幅下降,生态工程区中的水环境已从高度富营养化降到中度富营养化。     

Multivariate analysis of drinking water quality parameters in Bhopal, India

Pollution of water bodies is one of the areas of major concern to environmentalists. Water quality is an index of health and well being of a society. Industrialization, urbanization and modern agriculture practices have direct impact on the water resources. These factors influence the water resources quantitatively and qualitatively. The study area selected were the Upper lake and Kolar reservoir of Bhopal, the state capital of Madhya Pradesh, India. The Upper lake and Kolar reservoir both are the important sources of potable water supply for the Bhopal city. The physico–chemical parameters like temperature, pH, turbidity, total hardness, alkalinity, BOD, COD, Chloride, nitrate and phosphate were studied to ascertain the drinking water quality.     

Genotoxicity evaluation of water soil leachates by Ames test, comet assay, and preliminary Tradescantia micronucleus assay

Combining genotoxicity/mutagenicity tests and physico-chemical methodologies can be useful for determining the potential genotoxic contaminants in soil samples. The aim of our study was to evaluate the genotoxicity of soil by applying an integrated physico-chemical-biological approach. Soil samples were collected at six sampling points in a Slovenian industrial and agricultural region where contamination by heavy metals and sulphur dioxide (SO₂) are primarily caused by a nearby power plant. The in vitro alkaline version of the comet assay on water soil leachates was performed with Caco-2 and HepG2 cells. A parallel genotoxicity evaluation of the samples was performed by Ames test using Salmonella typhimurium and the Tradescantia micronucleus test. Pedological analyses, heavy metal content determination, and different physico-chemical analyses, were also performed utilizing standard methodology. Water leachates of soil samples were prepared according to standard methods. Since only a battery of biotests with prokaryotic and eukaryotic organisms or cells can accurately estimate the effects of (geno)toxicants in soil samples and water soil leachates, a combination of three bioassays, with cells or organisms belonging to different trophic levels, was used. Genotoxicity of all six water soil leachates was proven by the comet assay on both human cell lines, however no positive results were detected by bacterial assay, Ames test. The Tradescantia micronucleus assay showed increase in micronuclei formation for three samples. According to these results we can assume that the comet assay was the most sensitive assay, followed by the micronucleus test. The Ames test does not appear to be sensitive enough for water soil leachates genotoxicity evaluations where heavy metal contamination is anticipated.     

Mapping nitrate leaching to upper groundwater in the sandy regions of The Netherlands, using conceptual knowledge

The European Community asks its Member States to provide a comprehensive and coherent overview of their groundwater chemical status. It is stated that simple conceptual models are necessary to allow assessments of the risks of failing to meet quality objectives. In The Netherlands two monitoring networks (one for agriculture and one for nature) are operational, providing results which can be used for an overview. Two regression models, based upon simple conceptual models, link measured nitrate concentrations to data from remote sensing images of land use, national forest inventory, national cattle inventory, fertiliser use statistics, atmospheric N deposition, soil maps and weather monitoring. The models are used to draw a nitrate leaching map and to estimate the size of the area exceeding the EU limit value in the early 1990s. The 95% confidence interval for the fraction nature and agricultural areas where the EU limit value for nitrate (50 mg/l) was exceeded amounted to 0.77–0.85 while the lower 97.5% confidence limit for the fraction agricultural area where the EU limit value was exceeded amounted to 0.94. Although the two conceptual models can be regarded as simple, the use of the models to give an overview was experienced as complex.     

Heavy metal pollution in surface sediment and mussel samples in the Gulf of Gemlik

Different sources of pollution in Karasu Creek were investigated to obtain the water quality and ratio of contamination in this region. To achieve the main objectives of the present study, water samples were collected from Karasu Creek, starting from flow pattern at the upstream site of Akkaya Dam to the end of the dam, crossing the place where the Creek drains into. Dissolved oxygen, electrical conductivity, temperature and maximum/minimum pH were measured systematically for 12 months in the stations, where the water samples were collected. Chemical analyses of the water samples were carried out by using Cadas 50 S brand UV spectrometer to find out the Pb, Fe, Cu, Zn, Ni, Cr, Cd, S, F and Cn concentrations. These concentration were determined in μg/lt as 80–850; 180–4,920; 10–6,100; 440–25,530; 130–2,400; 120–280; 20–150; 214,250–1,113,580; 1,560–4,270 and 40–690, respectively. To determine metal levels of the water samples, multivariate analyses (element coefficient correlation, coefficient correlation dendrogram, hierarchical cluster analysis dendrogram, model summary and ANOVA) were used. The analyses yielded highly accurate results. There were positive correlations between some elements and their possible sources were the same. The stations which resembled each other along the creek were divided into three groups. The water quality of the creek was low and had toxic qualities. Eutrophication developed in Akkaya Dam along the creek. The source of pollution was thought to be industrial and residential wastes. Absolute (0–100 m), short distance (100–500 m) and medium distance (500–2,000 m) conservation areas should be determined in pollution areas along Karasu Creek and they should be improved.