Spectrophotometric determination of nitrite with diphenylamine in potable and polluted water

This paper describes a new method for the determination of nitrite in potable and polluted water, based on the reaction of nitrite with p-nitroaniline to form diazonium salt and its subsequent coupling with diphenylamine in acidic medium. The pink coloured dye formed obeys Beer's law in the range 0.16 to 0.56 μg/ml at λ_max = 540 nm. The molar absorptivity and Sandell's sensitivity being 57.5 × 10³ lmole^?3cm^?1 and 0.0008 μg/cm², respectively. The optimum reaction conditions and other analytical parameters have been studied. Extraction of the dye with chloroform enhances the sensitivity considerably and makes 0.04 μg/ml of nitrite determinable.     

Inputs and fates of petroleum hydrocarbons in a subtropical marine estuary

Inputs and fates of petroleum from a higly urbanized area to a subtropical marine estuary were investigated by measuring hydrocarbon concentrations in municipal wastewater treatment plants, urban stormwater drains, sediments, and benthic organisms in and around Tampa Bay, FL. The concentrations of petroleum hydrocarbons discharged from secondary and tertiary treatment plants in this area were lower than concentrations previously reported for other treatment plants in temperate regions. Samples collected from urban storm drains under base flow conditions were also low. The generally low levels of petroleum hydrocarbons in the sediments and organisms throughout Tampa Bay suggest that the bay is relatively pristine with respect to petroleum hydrocarbon contamination. Since it is unlikely that the anthropogenic input of hydrocarbons to this estuary is significantly lower than in other urbanized areas, we suggest that elevated annual temperatures in this subtropical system result in increased metabolic rates of microorganisms and more rapid degradation or metabolism of the petroleum hydrocarbons.     

“New” DDT inputs to North America: Atmospheric deposition

Measurement of untransformed (p,p'- and o,p'-) DDT in rain, snow, and peat indicates that input of “new” DDT continues over a large portion of eastern North America. Peat cores obtained from ombrotrophic bogs indicate that current atmospherically derived fluxes are about 10–20% of those which occurred during peak DDT usage (～1960). Since DDT has been banned in North America and considering the magnitude of present fluxes, these residues must result from atmospheric transboundary transport. It is suggested that “new” DDT is being transported from neighboring areas where current use is substantial, Mexico and Central America.     

Factors affecting photooxidation of oil constituents in the marine environment. I. Photochemical transformations of dimethylnaphthalenes in an aqueous environment in the presence and absence of oil

Photooxidation studies of 1,3-, 1,4-, 1,8- and 2,3-dimethylnaphthalene (DMN) suspended in and layered on seawater and distilled water have been performed in the presence and absence of crude Ekofisk oil, methylene blue and dibenzothiophene. With the exception of 2,3-DMN which was very insensitive to the reaction conditions, the course of reaction was, generally, influenced by the structure of the substrate, the salinity of the water, the oil and the presence of sulfur-containing compounds. In the absence of oil the photooxidation was fairly inefficient and took place exclusively in benzylic positions. In the presence of oil oxidation of the naphthalene moiety predominated due to abundant formation of singlet oxygen.     

Educational issues, school settings, and environmental psychology

This paper reviews selected research on classroom and school environments, using a framework that views schools from three perspectives—as places for learning, as places for socialization and as places for psychological development. Studies are included that deal with the impact of noise and classroom design on learning; the relationship between seating position, achievement and status; spatial cognition; the classroom environment and sex role stereotyping; privacy; and density. The need for classrooms to enhance children's feelings of competence, security and self-esteem is also stressed. The goal of the paper is to point out ways in which environmental psychologists can contribute to the improvement of the educational system and to the quality of life in schools.     

The effect of complex formation on the adsorption characteristics of heavy metals

In most aqueous environmental systems, inorganic and organic metal complexes represent a significant contribution to the total soluble metal. Metal adsorption is often a highly pH-dependent phenomena. Such behavior can generally be attributed to changes in metal speciation with solution acidity as well as variation in the extent of surface protonation. Thus, because adsorbability may vary drastically between different metal species, (e.g. Cu²⁺ (aq) compared to CuOH⁺) a knowledge of metal species distribution is essential to understanding and interpreting metal adsorption behavior.Organic complexation has been reported to enhance, suppress and have no perceptible effect on trace metal adsorption. Such differences arise because adsorption depends on factors such as the ligand/metal ratio, adsorbability of the free ligand, and various solution parameters (e.g. pH). Most important in determining the effect of complexation on adsorption is the adsorbability of the resulting complexes. Thus, it is difficult to make generalizations about the influence of organic complexation on metal adsorption.Adsorption of metal complexes is frequently reported to be predominantly coulombic in nature; that is, binding of an anionic or cationic complex to an oppositely charged colloidal particle. However, electrostatic forces can often represent an insignificant contribution to the total free energy of adsorption and can be overshadowed by chemical reactions with the surface, hydrogen bonding, and hydrophobic effects.     

Household Demand for Waste Recycling Services

Municipalities everywhere are coping with increasing amounts of solid waste and need urgently to formulate efficient and sustainable solutions to the problem. This study examines the use of economic incentives in municipal waste management. Specifically, we address the issue of recycling, if and when this waste management option is—on social welfare grounds—a preferred solution.A number of studies have recently assessed the monetary value of the externalities of alternative solid waste management options. In the present context, these subsidies could be interpreted as the implicit value of the benefits from reducing environmental externalities associated with landfilling as perceived by local government authorities. We surmise that the difference between mean households willingness to pay (WTP) for recycling services, via the purchase of a subsidized waste disposal facility, and the above (proxy) value of externalities reflects the difference between private and public perception regarding the negative externality associated with landfilling. We believe that this information is useful in determining the level of subsidization needed (if at all) to sustain any recycling program.The study is unique in the sense that its conclusions are based on revealed household behavior when faced with increased disposal costs, as well as information on WTP responses in hypothetical but related (and, therefore, familiar) scenarios. The article also explores the influence of the subsidization schemes on recycling rates. It was found that with low levels of effort needed to participate in a curbside recycling program, households participation rates are mainly influenced by economic variables and age, and households are willing to pay a higher price for the recycling scheme. When the required effort level is relatively high, however, households would pay a lower price, and the rate is influenced mainly by their environmental commitment and by economic considerations. We found that in both cases a subsidy would be required in order to achieve an efficient level of recycling. The median price that households are willing to pay for recycling devices is found to be about NIS 370 (New Israeli Shekel, approximately $90).     

Using revealed preferences to estimate the Value of Travel Time to recreation sites

The opportunity Value of Travel Time (VTT) is one of the most important elements of the total cost of recreation day-trips and arguably the most difficult to estimate. Most studies build upon the theoretical framework proposed by Becker (1965) by using a combination of revealed and stated preference data to estimate a value of time which is uniform in all activities and under all circumstances. This restriction is relaxed by DeSerpa's (1971) model which allows the value of saving time to be activity-specific. We present the first analysis which uses actual driving choices between open access and toll roads to estimate a VTT specific for recreation trips, thereby providing a value which conforms to both Becker's and DeSerpa's theoretical models. Using these findings we conduct a Monte Carlo simulation to identify generalizable results for subsequent valuation studies. Our results indicate that 3/4 of the wage rate provides a reasonable approximation of the average VTT for recreation trips, while the commonly implemented assumption of 1/3 of the wage rate generates downward biased results.     

Estimating willingness to pay for a hypothetical earthquake early warning systems

The development of reliable, accessible, and transparent earthquake early warning systems (EEWSs) for disaster reduction have been given increased priority at local, national, and international levels. Accurately quantifying the social and economic benefits accrued to households and businesses from EEWSs are a challenging and difficult task. In this paper, the Contingent Valuation Method (CVM) is used to evaluate the benefits of a hypothetical EEWS to the citizens of Tehran Metropolitan. This study clarifies public willingness to pay (WTP) for EEWS in Tehran, and the dominant factors involved in WTP through a CVM analysis. The survey, completed by more than 504 households, showed that on average households are willing to pay 367,471 Rials (~38 US$) per month for the hypothetical EEWS. Those willing to pay the most for EEWS are households, which currently possess a fire alarm. Also the more educated the respondents and the more children the respondents have, the more willing they are to pay for EEWS. These results could be used by policy makers and technology firms in order to determine the optimal investments in early warning systems for earthquake disaster reduction.