极端冰雪条件下的顺层岩质边坡滑移稳定性分析

推导了典型岩石边坡在极端冰雪条件下的滑移稳定系数的表达式;通过计算分析,揭示了岩石边坡滑移稳定系数随裂隙内水深、坡高、坡角、滑面倾角等因素变化的规律及与冻深的关系,并绘制岩石边坡滑移稳定系数与边坡几何要素之间的关系图.研究表明,当考虑极端冰雪灾害影响时,岩石边坡滑移稳定系数发生较为明显的变化:随裂隙饱水程度、坡面角、主...     

简易垃圾填埋场的安全分析

以福建省晋江市铜锣山垃圾填埋场为例,采用系统的安全分析方法--事故树分析法对该简易垃圾填埋场进行安全分析,发现铜锣山垃圾填埋场存在发生火灾、爆炸、垃圾堆体崩塌及因发生火灾或爆炸事故对邻近建筑物造成破坏的可能性,确定了影响该垃圾填埋场安全的主要因素,提出了有效的安全防范措施.     

破碎带对地下坑道动力响应影响的数值分析

为了研究破碎带的耗能作用及其对坑道结构动力响应的影响,根据某工程实例,建立了地冲击波作用下类岩体中坑道结构响应的计算模型,利用LS-DYNA3D有限元软件,分别计算了无破碎带和存在破碎带情况下坑道结构的动力响应。计算结果的对比分析表明,顶部破碎带使结构的加速度和位移等运动参数有不同程度的降低,但对结构所受到的应力影响不大;与之相反,侧部破碎带的存在使结构的加速度和位移等运动参数明显地增大。与顶部存在破碎带情况相比,侧部存在破碎带情况下坑道结构运动参数的峰值更大,对坑道结构安全更为不利。     

瑞士土壤环境监测网络构建与运行对中国的启示

“十三五”期间,中国初步构建了国家土壤环境监测网并开展了监测工作。当前,国家层面土壤环境监测网络的构建和运行还处于起步阶段,笔者选取土壤环境监测开展较为成熟的瑞士土壤环境监测网(NABO)作为研究对象,综述了NABO的技术体系及多年来的土壤环境监测结果,并结合中国土壤环境监测工作现状进行讨论,认为NABO在监测网络建立、指标选取、数据分析等方面建立了较为成熟的技术体系,未来中国国家土壤环境监测网可在此方面借鉴瑞士经验。     

北京地区PM10与秸秆燃烧排放单颗粒对比分析

采用场发射带能谱扫描电镜(FESEM/EDS)法分析北京怀柔地区PM10与秸秆燃烧排放颗粒的形貌特征和成分差异.结果显示:秸秆燃烧后排放颗粒物多为大粒径颗粒,成分上都含S、Cl和K元素.含有生物质燃烧标志元素K的PM10颗粒物多为含Si、Al和Na元素的燃煤飞灰和矿物颗粒,与秸秆燃烧排放颗粒组成化学元素差异明显.据此推...     

基于FA-BAS-ELM的海洋油气管道外腐蚀速率预测

为提高海洋油气管道外腐蚀速率预测的精度和效率,建立基于因子分析(FA)和天牛须搜索算法(BAS)的极限学习机(ELM)腐蚀速率预测模型。利用FA对影响因素数据集进行降维处理,确定预测模型的输入变量;建立ELM预测模型,并采用BAS对ELM模型的参数进行优化,避免参数取值随机性对模型预测性能的影响;以实海挂片试验为例,通过建模仿真评价模型的预测性能,并与其他模型进行对比分析。结果表明：FA-BAS-ELM预测模型的平均绝对误差(MAPE)仅为1.92%,决定系数R²高达0.994 9,相比于其他模型,该模型具有更优的预测性能。     

有机酸性腐蚀品生产危险性分析

目前我国化工生产中涉及大量有机酸性腐蚀品,通过对某市化工行业调查及分析,发现有机酸性腐蚀品生产普遍,而且生产原料易燃易爆,生产过程存在火灾爆炸危险,结合具体生产工艺,采用预先危险性分析法和作业条件的危险性评价法分析生产过程危险性,从而揭示并概括有机酸性腐蚀品生产危险性.为更好地促进我国安全生产,在此基础上探讨了一些针对性的安全措施.     

Heavy metals' content of automotive shredder residues (ASR): evaluation of environmental risk

Every year between 8 and 9 millions of vehicles in the European Union arrive to their end of life. Car wastes can have a very high metal content, falling into hazardous waste class. A preliminary evaluation of these wastes could be made by metals' leaching test runs which is the main objective of the present study. Evaluation of the total metal content was carried out by X-ray fluorescence and the mobility of these metals using two simple standardized extractions such as the TCLP (Toxicity Characterisation Leaching Procedure) of the US EPA and the German leaching test DIN 38414-S4. Additionally, an extraction test with acetone was performed in order to recognise metals bounded to organic matter. The results show that the total metal content of the ASR can overpass the established values for inert residues. Lead and zinc contents are fairly well correlated with grain-size, whilst other metals' contents do not exhibit clear grain-size dependence.     

U and Th in some brown coals of Serbia and Montenegro and their environmental impact

GOAL, SCOPE AND BACKGROUND: The objective of this paper is to determine and compare the concentrations of U and Th in soft to hard brown (lignite to sub-bituminous) coals of Serbia and Montenegro. It also presents comparison of the obtained data on U and Th concentrations with the published data on coals located in some other countries of the world. Almost the whole coal production of Serbia and Montenegro is used as feed coals for combustion in thermal power plants. METHODS: Channel samples from open pit and underground mines and core samples were collected for hard and soft brown coals. For the analysis the samples were decomposed using microwave technique. Obtained solutions containing U and Th were analyzed by inductively coupled plasma mass spectroscopy (ICP-MS) using NIST standards. RESULTS: Concentration of U from the investigated basins and the corresponding mine fields ranges within 0.60-70.10 mg/kg, 0.65-3.20 mg/kg, 0.95-6.59 mg/kg, 1.20-6.05 mg/kg, 0.80-6.66 mg/kg, 0.18-89.90 mg/kg, 0.19-4.14 mg/kg, and 0.28-3.52 mg/kg for the Kostolac, Kolubara, Krepoljin, Sjenica, Soko Banja, Bogovina East field, Senje-Resavica and Pljevlja basins, respectively. Concentration of Th ranges within 0.20-2.60 mg/kg, 0.84-6.57 mg/kg, 1.48-6.48 mg/kg, 0.12-2.71 mg/kg, 0.13-4.95 mg/kg, 0.14-3.48 mg/kg, 0.29-3.56 mg/kg, and 0.17-1.89 mg/kg for the Kostolac, Kolubara, Krepoljin, Sjenica, Soko Banja, Bogovina East field, Senje-Resavica and Pljevlja basins, respectively. DISCUSSION: Brown coal from Senje-Resavica, Kolubara, Kostolac and Pljevlja is characterized by low U concentration. Coals form the Krepoljin, Soko Banja and Sjenica basins have slightly higher U concentrations than the mentioned group. The highest concentration of U is characteristic for the coal from the Bogovina East field. Concentration of Th in coals from Serbia and Montenegro has proved to be low. Out of all investigated coal basins, only the coal from the Krepoljin and Kolubara basins has high concentration of Th. The hydrothermally altered rocks of the Timok dacite-andesite complex, representing the basement of the Bogovina basin, could be a potential source of U, especially at the bottom part of the Lower seam of the Bogovina East field. CONCLUSIONS: This study shows that brown coals in Serbia and Montenegro (soft to hard brown coals or lignite to sub-bituminous) contain low levels of U (5.30 mg/kg, average value and 2.10 mg/kg geometric mean value) and Th (1.80 mg/kg, average value and 1.12 mg/kg geometric mean value). There are some obvious differences in concentration of U and Th in coals from different basins in Serbia and Montenegro. The approximate value for U and Th release mainly from power plants was 644.33 t and 983.46 t, respectively within the period 1965-2000 for the studied mines in Serbia, and 23.76 t and 15.05 t for the Potrlica mine (Montenegro) within the period 1965-1997. RECOMMENDATIONS: The coals in Serbia and Montenegro show no identifiable unfavourable impact on the surrounding environment, due to low natural radioactive concentration of U and Th, but further investigations concerning human health should be performed. PERSPECTIVES: Preliminary research revealed that in some Serbian coals (and, particularly, parts of the coal seam) U and Th content are rather high. Such coals should be carefully studied, as well as U and Th concentrations in ash, fly ash, waste disposals, nearby soil and ground water. Further studies should include determination of the radioactivity of all these products, and estimation of possible health impact.     

亚超临界水技术在废旧尼龙6解聚中的应用

研究了尼龙6在亚超临界水中的解聚反应,以期为废旧尼龙6的回收利用提供技术参数.实验分别利用气质联用仪和紫外分光光度计对解聚后的液相产物进行定性和定量分析,并考察了不同的反应温度、反应压力和反应时间对液相产物收率的影响.结果表明,液相产物绝大部分为己内酰胺;解聚的最佳条件为370 ℃、25 MPa、60 min;己内酰胺最大收率为96%.通过动力学分析和Arrhenius关系计算,得出尼龙6亚超临界水解聚的活化能为64.4 kJ/mol.