模拟医疗废物在TG-DTA-FTIR上的热失重特性研究

在热重-差热分析仪上对模拟医疗废物分别在氮气和空气气氛中不同升温速率下加热的热失重行为进行了研究,并对升温速率和不同气氛对其热失重行为的影响进行了探讨.结果表明,随升温速率的提高,模拟医疗废物在2种气氛下热失重时挥发分初析出温度（T_s）向高温方向偏移、失重速率峰值（DTG_max）显著增大;在氮气气氛下,物料热失重时有2个失重峰,前后2个峰的失重率分别为31%和59%左右,在空气气氛下,有3个失重峰,前2个峰失重率分别在44%～59%和31%～46%之间.同时,结合同步傅立叶变换红外光谱仪对各个条件下的气体产物进行了定性分析,并对其中的CO、CO₂、H₂O和CH₄进行了定量分析.实验发现,模拟医疗废物在2种气氛下热失重主要阶段的产物种类相似,都检测到了CO₂、CO、烷烃类、醛类、羧酸、醇类和烯烃的特征吸收峰.并且,结果显示升温速率和气氛条件对CO、CO₂、H₂O和CH₄的生成量都有影响.在热失重的主要阶段,水分含量随加热时间变化曲线上显示1个向下的峰,说明载气中原有水分参与了反应.     

长三角典型区土壤重金属有效态的协同区域化分析、空间相关分析与空间主成分分析

以昆山市为典型区,采集了126个表层土壤样品,通过多元统计学、地统计学与GIS技术相结合,采用基于协同区域化理论的因子克立格法探讨了长三角多个土壤重金属有效态的区域分异,并在剖析不同空间尺度有效态重金属的空间结构特征基础上,应用空间相关分析和空间主成分分析来揭示引起这种分布格局的成因和污染来源,结果表明,昆山土壤有效态重金属服从正态或对数正态分布,变异系数较大,有效态Cd污染最重.重金属有效态在空间上可划分为块金尺度、小空间尺度（15 km左右）和大空间尺度（40 km左右）,它可用3个尺度的实验（交叉）变异函数的协同区域化模型线性拟合.空间相关分析中,Cd和Zn在3个尺度中的相关性均极显著,且元素在小尺度和大尺度的相关性比块金尺度更强,大尺度的负相关特征较其它尺度明显.空间主成分分析表明,不同尺度的空间污染来源不同.重金属有效态第一、二主成分的空间分布格局结果表明重金属有效态含量与工业活动、污水灌溉和土壤性质密切相关.     

不同墩高下连续刚构桥抗震性能分析

以某大跨连续高墩刚构桥为依托,采用Midas/civil软件建立仿真模型,通过时程分析方法研究双肢薄壁墩参数在地震响应下对高墩连续刚构桥抗震性能的影响.以桥墩高度为主要参数,以模型阵型频率、桥墩墩顶、墩底位移及内力变化三个方面对其抗震性能进行评价.研究结果表明,随着其中一个桥墩高度的增加,桥梁频率不断减小,矮墩墩底及矮...     

Investigation of PM2.5 pollution during COVID-19 pandemic in Guangzhou, China

The COVID-19 pandemic has raised awareness about various environmental issues,including PM_2.5 pollution.Here,PM_2.5 pollution during the COVID-19 lockdown was traced and analyzed to clarify the sources and factors influencing PM_2.5 in Guangzhou,with an emphasis on heavy pollution.The lockdown led to large reductions in industrial and traffic emissions,which significantly reduced PM_2.5 concentrations in Guangzhou.Interestingly,the trend of PM_2.5     

高铁扣件弹条疲劳断裂原因分析

通过对WJ-7型扣件中60Si2MnA弹条在拉伸-扭转试验过程发生断裂的原因进行分析和数值模拟研究,得出弹条断裂的原因.对60Si2MnA弹条承受的荷载进行分析可知,WJ-7型扣件在铁垫板与弹条后端接触区域内弯处应力集中最大,是造成弹条断裂破坏的主要原因之一,而弹条断裂的根本原因是弹条长期处于极限强度下工作,使弹条最终...     

多元回归在大气环境污染事故预测中的应用

运用多元回归法,通过预测模型的选择、数学模型的建立、基础数据的整理和回归效果的检验,建立环境污染范围与诸条件的关系,达到快速估算的目的,从而形成一种有效的大气环境污染事故范围预测的方法.     

桥式起重机典型事故分析及安全管理

分析了桥式起重机典型事故发生机理,运用事故树分析法对桥式起重机事故发生进行了分析,从而为能够找出安全隐患,制定出最优的控制措施提供了理论上的依据.最后根据分析结果,系统地提出了控制危害,降低事故发生率的安全管理措施,提出一些具有可行性的建议.     

运用QSPR预测有机磷农药的色谱保留值

通过计算43种有机磷农药的各种结构参数,运用多元线性回归分析方法比较了适用于有机磷农药色谱保留值的定量关系表达式,建立了有机磷农药结构参数对色谱保留值的QSPR模型.模型分析表明:磷酸酯与硫逐磷酸酯两类有机磷农药的模型非交叉验证相关系数R2分别为0.991和0.998,标准误差SE分别为0.0539和0.2874,交叉验证相关系数Q2分别为0.976和0.990,标准偏差Scv分别为0.086和0.610.在已知磷酸酯与硫逐磷酸酯两类有机磷农药结构参数的情况下,此模型可有助于有机磷农药的色谱分析.     

Synergistic Techniques for Better Understanding and Classifying the Environmental Structure of Landscapes

The desire to capture natural regions in the landscape has been a goal of geographic and environmental classification and ecological land classification (ELC) for decades. Since the increased adoption of data-centric, multivariate, computational methods, the search for natural regions has become the search for the best classification that optimally trades off classification complexity for class homogeneity. In this study, three techniques are investigated for their ability to find the best classification of the physical environments of the Mt. Lofty Ranges in South Australia: AutoClass-C (a Bayesian classifier), a Kohonen Self-Organising Map neural network, and a k-means classifier with homogeneity analysis. AutoClass-C is specifically designed to find the classification that optimally trades off classification complexity for class homogeneity. However, AutoClass analysis was not found to be assumption-free because it was very sensitive to the user-specified level of relative error of input data. The AutoClass results suggest that there may be no way of finding the best classification without making critical assumptions as to the level of class heterogeneity acceptable in the classification when using continuous environmental data. Therefore, rather than relying on adjusting abstract parameters to arrive at a classification of suitable complexity, it is better to quantify and visualize the data structure and the relationship between classification complexity and class homogeneity. Individually and when integrated, the Self-Organizing Map and k-means classification with homogeneity analysis techniques also used in this study facilitate this and provide information upon which the decision of the scale of classification can be made. It is argued that instead of searching for the elusive classification of natural regions in the landscape, it is much better to understand and visualize the environmental structure of the landscape and to use this knowledge to select the best ELC at the required scale of analysis.     

TUGAI: An Integrated Simulation Tool for Ecological Assessment of Alternative Water Management Strategies in a Degraded River Delta

The development of ecologically sound water allocation strategies that account for the needs of riverine ecosystems is a pressing issue, especially in semiarid river basins. In the Aral Sea Basin, a search for strategies to mitigate ecological and socioeconomic deterioration has been in process since the early 1990s. The Geographic Information System–based simulation tool TUGAI has been developed to support the policy determination process by providing a simple, problem-oriented method to assess ecological effects of alternative water management strategies for the Amudarya River. It combines a multiobjective water allocation model with simple, spatially explicit statistical and rule-based models of landscape dynamics. Changes in environmental conditions are evaluated by a fuzzy habitat suitability index for Populus euphratica, which is the dominant species of the characteristic riverine Tugai forests. Water management scenarios can be developed by altering spatiotemporal water distribution in the delta area or the amount of water inflow into the delta. Outcomes of scenario analysis are qualitative comparisons of the ecological effects of different options for a time period of up to 28 years. The given approach utilizes different types of knowledge, from quantitative hydrological data to qualitative local expert knowledge. The main purpose of the tool is to integrate the knowledge in a comprehensive way to make it available for discussions on alternative policies in moderated workshops with stakeholders. In this article, the modules of the tool, their integration, and three hypothetical scenarios are presented. Based on the experience gained when developing the TUGAI tool, we propose that the general framework can be transferred to other areas where tradeoffs in water allocation between the environment and other water users are of major concern. The potential for a simulation tool to structure and inform a complex resource management situation by involving local experts and stakeholders in the development of possible future scenarios will become increasingly valuable for transparent and participatory resource management.