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991.
西北太平洋是全球热带气旋(TC)发生次数最多、强度最大的区域之一,其TC研究受到该区域学者的广泛关注。基于日本气象厅(JMA)东京台风中心西北太平洋TC最佳路径数据资料,分析了该区域1951-2006年的TC频数和强度时空分布特征。首先,统计和分析了56年间(1951-2006年)TC的年际和年内变化,并通过建立1°×1°网格计算了落在每个网格内的TC次数,分析了多年TC的空间分布格局;其次,根据国际气象组织按照风速划分TC等级的标准,统计和分析了56年间不同强度TC的年际和年内特征,通过风速强度指数计算,获取了1°×1°网格单元区域内遭受TC影响的强度等级。结果显示,区域频数和强度时空分布规律较好地反映了该区域的TC影响特征,进而为区域台风灾害预报以及台风灾害风险评估提供了支持。 相似文献
992.
Valérie Guillet Céline Fave Michel Montury 《Journal of environmental science and health. Part. B》2013,48(5):415-422
A new analytical method using focused microwave-assisted extraction (FMAE), coupled with solid phase micro-extraction (SPME), has been elaborated to determine 25 pesticides used in tomato cultivation. Microwave energy was used for a fast and controlled heating of solvent to selectively extract compounds. Calibration curves were plotted from blank tomato samples spiked at different concentrations with standards. A linear response was obtained between 10 and 1000 μ g/Kg for pyrethroids and between 0.1 and 5000 μ g/Kg for other compounds. For all studied substances, the resulting correlation coefficient (r2) was greater than 0.99. Limits of detection (LOD) and quantification (LOQ) were measured lower than 8 and 25 μ g/Kg, respectively. The relative standard deviation (RSD) was determined below 15% for all pesticides. Field incurred tomato samples were used to validate the new FMAE/SPME method. Observed analysis results by using this technique were in good agreement compared to those obtained by two accredited trading laboratories using traditional methods. Four tomato samples, bought in a local market, were also tested with the FMAE/SPME method. 相似文献
993.
Yi Q. Wan Xue J. Mao Ai P. Yan 《Journal of environmental science and health. Part. B》2013,48(4):315-324
Gas chromatography with nitrogen phosphorus detector (GC-NPD) was applied to the simultaneous determination of 15 organophosphorus and 6 organonitrogen pesticides residues in Angelica sinensis. The pesticides were extracted by microwave-assisted extraction (MAE) and ultrasound-assisted extraction (UAE) techniques, respectively. The experimental variables were optimized through orthogonal array experimental design. Cleanup of extracts was performed with column chromatography using florisil and neutral aluminum as the sorbents. The determination of pesticides in the final extracts was carried out by GC-NPD. Under optimized conditions, the average recoveries obtained from MAE and UAE are in the range of 75.1–129% and 70.6–129%, respectively, and the relative standard deviations of MAE and UAE were 3.1–10.6% and 1.0–17.8%, respectively. 相似文献
994.
Somrutai Poothong Suwanna Kitpati Boontanon Narin Boontanon 《Journal of environmental science and health. Part. B》2013,48(10):830-835
This research aimed to optimize the extraction method parameters for sample pretreatment and determine the levels of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) contamination in food packaging made of paper. Techniques used were pressurized liquid extraction (PLE) followed by liquid chromatography coupled with tandem mass spectrometry (LC-MS/MS). Influence parameters of PLE were carefully evaluated for extracted concentration of samples in low level (ng g?1). The study found that the optimal conditions for PLE were 30 min static extraction time with a flush volume of 100% cell volume and one extraction cycle at 80°C and 1,000 psi. The extraction technique validated the absolute recovery from PFOS and PFOA fortified control samples at three different levels (5, 50, and 200 ng g?1), with seven repeats at each fortification level. The average recoveries were 79% or higher, with relative standard deviation (RSD) less than 11%. Optimization of the PLE method was established based on recovery data, accuracy, precision, and repeatability of the method. Using optimal PLE technique, PFOS and PFOA were extracted from 34 food-packaging samples collected in Thailand. PFOS and PFOA were detected in all kinds of collected samples, with average concentrations of 4.89 and 2.87 ng g?1, respectively. The concentrations of PFOS and PFOA were highest in fast-food container samples: 36.99 and 9.99 ng g?1, respectively. 相似文献
995.
以浮萍优势品种青萍(Lemna minor)为研究对象,开展受污染河水修复。分析了青萍在不同营养盐浓度条件下的生长特征,探讨了青萍对受污染河水的修复效果。在表面积为0.0095 m2的限制空间条件下,青萍在1、2和5 mg总氮(TN)/L营养液中的生长特征都能较好地服从Logistic生长模型,受制约的临界鲜重(FW)分别为1.20、1.36和1.36 g;青萍对受污染河水中氮磷污染物具有较好的去除效果,氨氮(NH+4-N)的平均去除率、平均去除量和平均去除速率分别为56.87%、1.22 mg/d和0.0466 mg/(g FW·h),正磷酸盐(PO3-4-P)的平均去除率、平均去除量和平均去除速率分别为66.95%、0.25 mg/d和0.0088 mg/(g FW·h)。根据相关性分析,进水NH+4-N和PO3-4-P浓度与其对应去除量之间极显著相关;青萍FW与NH+4-N去除速率之间显著负相关,但与PO3-4-P去除速率之间不存在显著相关性;NH+4-N进水浓度与去除速率相关性不显著,但PO3-4-P进水浓度与去除速率显著正相关。 相似文献
996.
为处置和利用一种玻璃抛光废渣,用XRF、ICP、XRD、SEM、灰熔点炉、粒度分析和浸出毒性等实验手段对其化学成分、浸出毒性、颗粒径和比表面积等理化性质进行了系统研究。结果表明,玻璃抛光废渣虽然主体是Si、Al、Fe、K、Na、Ca和Mg的硅酸盐,但含一定量的Pb、Ba、Cr、Mn、Zn、V、Cu和As等重金属元素,80%的粒径小于15μm,平均粒径为6.31μm,比表面积为480 m2/g,是一种细粉状浸出毒性较高的有害固废;烧结能有效地固封和固溶其中的重金属,可作为控制其污染和处置利用的有效措施。 相似文献
997.
Lumbricus terrestris L. activity increases the availability of metals and their accumulation in maize and barley 总被引:1,自引:0,他引:1
Ruiz E Alonso-Azcárate J Rodríguez L 《Environmental pollution (Barking, Essex : 1987)》2011,159(3):722-728
The effect of the earthworm Lumbricus terrestris L. on metal availability in two mining soils was assessed by means of chemical extraction methods and a pot experiment using crop plants. Results from single and sequential extractions showed that L. terrestris had a slight effect on metal fractionation in the studied soils: only metals bound to the soil organic matter were significantly increased in some cases. However, we found that L. terrestris significantly increased root, shoot and total Pb and Zn concentrations in maize and barley for the soil with the highest concentrations of total and available metals. Specifically, shoot Pb concentration was increased by a factor of 7.5 and 3.9 for maize and barley, respectively, while shoot Zn concentration was increased by a factor of 3.7 and 1.7 for maize and barley, respectively. Our results demonstrated that earthworm activity increases the bioavailability of metals in soils. 相似文献
998.
Kumpiene J Mench M Bes CM Fitts JP 《Environmental pollution (Barking, Essex : 1987)》2011,159(6):1536-1542
Field plots were established at a timber treatment site to evaluate remediation of Cu contaminated topsoils with aided phytostabilization. Soil containing 2600 mg kg−1 Cu was amended with a combination of 5 wt% compost and 2 wt% iron grit, and vegetated. Sequential extraction was combined with extended X-ray absorption fine structure (EXAFS) spectroscopy to correlate changes in Cu distribution across five fractions with changes in the predominant Cu compounds two years after treatment in parallel treated and untreated field plots. Exchangeable Cu dominated untreated soil, most likely as Cu(II) species non-specifically bound to natural organic matter. The EXAFS spectroscopic results are consistent with the sequential extraction results, which show a major shift in Cu distribution as a result of soil treatment to the fraction bound to poorly crystalline Fe oxyhydroxides forming binuclear inner-sphere complexes. 相似文献
999.
Distribution, speciation and availability of antimony (Sb) in soils and terrestrial plants from an active Sb mining area 总被引:1,自引:0,他引:1
Gudny Okkenhaug Yong-Guan ZhuLei Luo Ming LeiXi Li Jan Mulder 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2427-2434
Here, we present one of the first studies investigating the mobility, solubility and the speciation-dependent in-situ bioaccumulation of antimony (Sb) in an active Sb mining area (Xikuangshan, China). Total Sb concentrations in soils are high (527-11,798 mg kg−1), and all soils, including those taken from a paddy field and a vegetable garden, show a high bioavailable Sb fraction (6.3-748 mg kg−1), dominated by Sb(V). Elevated concentrations in native plant species (109-4029 mg kg−1) underpin this. Both chemical equilibrium studies and XANES data suggest the presence of Ca[Sb(OH)6]2, controlling Sb solubility. A very close relationship was found between the citric acid extractable Sb in plants and water or sulfate extractable Sb in soil, indicating that citric acid extractable Sb content in plants may be a better predictor for bioavailable Sb in soil than total acid digestible Sb plant content. 相似文献
1000.